83,272 research outputs found

    Identification of the dimethylamine-trimethylamine complex in the gas phase

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    We have identified the dimethylamine-trimethylamine complex (DMA-TMA) at room temperature in the gas phase. The Fourier transform infrared (FTIR) spectrum of DMA-TMA in the NH-stretching fundamental region was obtained by spectral subtraction of spectra of each monomer. Explicitly correlated coupled cluster calculations were used to determine the minimum energy structure and interaction energy of DMA-TMA. Frequencies and intensities of NH-stretching transitions were also calculated at this level of theory with an anharmonic oscillator local mode model. The fundamental NH-stretching intensity in DMA-TMA is calculated to be approximately 700 times larger than that of the DMA monomer. The measured and calculated intensity is used to determine a room temperature equilibrium constant of DMA-TMA of 1.7 × 10⁻³ atm⁻¹ at 298 K

    Quantitative comparisons of type 3 radio burst intensity and fast electron flux at 1 AU

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    The flux of fast solar electrons and the intensity of the type 111 radio emission generated by these particles were compared at one AU. Two regimes were found in the generation of type 111 radiation: one where the radio intensity is linearly proportional to the electron flux, and another, which occurs above a threshold electron flux, where the radio intensity is approximately proportional to the 2.4 power of the electron flux. This threshold appears to reflect a transition to a different emission mechanism

    Scattering by a contact potential in three and lower dimensions

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    We consider the scattering of nonrelativistic particles in three dimensions by a contact potential Ω2δ(r)/2μrα\Omega\hbar^2\delta(r)/ 2\mu r^\alpha which is defined as the a0a\to 0 limit of Ω2δ(ra)/2μrα\Omega\hbar^2\delta(r-a)/2\mu r^\alpha. It is surprising that it gives a nonvanishing cross section when α=1\alpha=1 and Ω=1\Omega=-1. When the contact potential is approached by a spherical square well potential instead of the above spherical shell one, one obtains basically the same result except that the parameter Ω\Omega that gives a nonvanishing cross section is different. Similar problems in two and one dimensions are studied and results of the same nature are obtained.Comment: REVTeX, 9 pages, no figur

    Determination of the Joint Confidence Region of Optimal Operating Conditions in Robust Design by Bootstrap Technique

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    Robust design has been widely recognized as a leading method in reducing variability and improving quality. Most of the engineering statistics literature mainly focuses on finding "point estimates" of the optimum operating conditions for robust design. Various procedures for calculating point estimates of the optimum operating conditions are considered. Although this point estimation procedure is important for continuous quality improvement, the immediate question is "how accurate are these optimum operating conditions?" The answer for this is to consider interval estimation for a single variable or joint confidence regions for multiple variables. In this paper, with the help of the bootstrap technique, we develop procedures for obtaining joint "confidence regions" for the optimum operating conditions. Two different procedures using Bonferroni and multivariate normal approximation are introduced. The proposed methods are illustrated and substantiated using a numerical example.Comment: Two tables, Three figure

    Spectrophotovoltaic orbital power generation

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    A system with 1000 : 1 concentration ratio is defined, using a cassegrain telescope as the first stage concentration (270 x) and compound parabolic concentrators (CPC) for the second stage concentration of 4.7 x for each spectral band. Using reported state of the art (S.O.A.) solar cells device parameters and considering structural losses due to optics and beamsplitters, the efficiencies of one to four cell systems were calculated with efficiencies varying from approximately 22% to 30%. Taking into account cost of the optics, beamsplitter, radiator, and the cost of developing new cells the most cost effective system is the GaAs/Si system

    Classification of GHZ-type, W-type and GHZ-W-type multiqubit entanglements

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    We propose the concept of SLOCC-equivalent basis (SEB) in the multiqubit space. In particular, two special SEBs, the GHZ-type and the W-type basis are introduced. They can make up a more general family of multiqubit states, the GHZ-W-type states, which is a useful kind of entanglement for quantum teleporatation and error correction. We completely characterize the property of this type of states, and mainly classify the GHZ-type states and the W-type states in a regular way, which is related to the enumerative combinatorics. Many concrete examples are given to exhibit how our method is used for the classification of these entangled states.Comment: 16 pages, Revte
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