13 research outputs found
Self-trapped electrons and holes in PbBr crystals
We have directly observed self-trapped electrons and holes in PbBr
crystals with electron-spin-resonance (ESR) technique. The self-trapped states
are induced below 8 K by two-photon interband excitation with pulsed
120-fs-width laser light at 3.10 eV. Spin-Hamiltonian analyses of the ESR
signals have revealed that the self-trapping electron centers are the dimer
molecules of Pb along the crystallographic a axis and the
self-trapping hole centers are those of Br with two possible
configurations in the unit cell of the crystal. Thermal stability of the
self-trapped electrons and holes suggests that both of them are related to the
blue-green luminescence band at 2.55 eV coming from recombination of spatially
separated electron-hole pairs.Comment: 8 pages (7 figures, 2 tables), ReVTEX; revised the text and figures
1, 4, and
Self-trapped states and the related luminescence in PbCl crystals
We have comprehensively investigated localized states of photoinduced
electron-hole pairs with electron-spin-resonance technique and
photoluminescence (PL) in a wide temperature range of 5-200 K. At low
temperatures below 70 K, holes localize on Pb ions and form
self-trapping hole centers of Pb. The holes transfer to other trapping
centers above 70 K. On the other hand, electrons localize on two Pb ions
at higher than 50 K and form self-trapping electron centers of Pb.
From the thermal stability of the localized states and PL, we clarify that
blue-green PL band at 2.50 eV is closely related to the self-trapped holes.Comment: 8 pages (10 figures), ReVTEX; removal of one figure, Fig. 3 in the
version
Electron Paramagnetic Resonance of Human Tooth Enamel at High Gamma Ray Doses.
Powdered human tooth enamel was exposed to Co-60 gamma rays up to a dose of 100 kGy. The electron paramagnetic resonance (EPR) signal intensity (1) of the radiation-generated carbon dioxide radicals was measured for dependence on absorbed dose (D). The EPR dose response can be fitted with an exponential saturation function I I-M[1 - exp(-D/D-37)] with the saturated signal intensity (I-M) and the dose saturation value (D-37). The obtained value D-37 = 9.64 (+/- 0.96) kGy (measured at least one month after irradiation) exceeds those given in the literature. The saturated concentration of orthorhombic CO2- radicals was estimated at 6.5 X 10(17) per gram of enamel by comparing the integrated EPR spectra of enamel and a standard MgO:Cr probe. For enamel samples, which were heated before irradiation for one hour at +405degreesC, the value of D-37T = 3.89 (+/- 0.44) kGy and the saturated value of CO2- radicals 3.4 X 10(17) per gram of enamel were lower than for unheated samples. The initial rise of the signal with the dose was slightly higher (8.8 X 10(13) radicals/g X Gy) for heated compared with unheated samples (6.8 X 10(13) radicals/g X Gy)