1 research outputs found
Impregnation of Polyethylenimine in Mesoporous Multilamellar Silica Vesicles for CO<sub>2</sub> Capture: A Kinetic Study
Amine-impregnated
solid sorbents have been approved as one of the
promising sorbents for CO<sub>2</sub> capture. However, the low adsorption
rate seriously limits their real application. Herein, we synthesized
the mesoporous multilamellar silica vesicle (MMSV) and used them as
a novel support for the impregnation of polyethylenimine (PEI). The
mesoporous multilamellar structure, as well as the presence of surfactant
templates, significantly improved the dispersion of PEI in sorbents
and hence improved both adsorption capacity and adsorption rate simultaneously.
Among various MMSV-PEIs samples, MMSVÂ(a)-PEI-60% showed the best CO<sub>2</sub> adsorption capacity, up to 4.73 mmol/g in pure and dry CO<sub>2</sub> flow at 90 °C, and even exhibited a 22% enhancement
in humid CO<sub>2</sub> flow at 75 °C. Moreover, it also presented
good adsorption/desorption cyclic performance. The kinetic study showed
that the second-order kinetic model fitted quite well for dynamic
CO<sub>2</sub> adsorption, and the adsorption rate constants revealed
its faster adsorption rate and higher amine efficiency compared with
most reported amine-impregnated sorbents