Effect of refining variables on the properties and composition of JP-5

Potential future problem areas that could arise from changes in the composition, properties, and potential availability of JP-5 produced in the near future are identified. Potential fuel problems concerning thermal stability, lubricity, low temperature flow, combustion, and the effect of the use of specific additives on fuel properties and performance are discussed. An assessment of available crudes and refinery capabilities is given

High performance, high density hydrocarbon fuels

The fuels were selected from 77 original candidates on the basis of estimated merit index and cost effectiveness. The ten candidates consisted of 3 pure compounds, 4 chemical plant streams and 3 refinery streams. Critical physical and chemical properties of the candidate fuels were measured including heat of combustion, density, and viscosity as a function of temperature, freezing points, vapor pressure, boiling point, thermal stability. The best all around candidate was found to be a chemical plant olefin stream rich in dicyclopentadiene. This material has a high merit index and is available at low cost. Possible problem areas were identified as low temperature flow properties and thermal stability. An economic analysis was carried out to determine the production costs of top candidates. The chemical plant and refinery streams were all less than 44 cent/kg while the pure compounds were greater than 44 cent/kg. A literature survey was conducted on the state of the art of advanced hydrocarbon fuel technology as applied to high energy propellents. Several areas for additional research were identified

Energy balance in a low pressure capacitive discharge driven by a double-saddle antenna

A radio frequency (rf) plasma is created at low pressure (∼1 mTorr) in the source tube of a “helicon” excited diffusion system in the absence of a dc magnetic field. The coupling is capacitive for the low source power of 160 W at 13.56 MHz considered here. Temperature measurements of the glass source tube yield a plasma power deposition of ∼35 W. The plasma parameters (density, potential, electron temperature) were measured using a retarding field energy analyzer. An analytical model based on the measuredplasma parameters and on additional external parameters measured in the matching box (rf voltages and phase, rf current) is developed. The model takes into account the geometry of the double saddle rf antenna. It is found that the inside of the glass wall adjacent to the antenna wire charges negatively. Ion acceleration into the glass along the antenna and fast electrons escaping the plasma account for most of the power deposition to the walls (∼16.8 W). Secondary electrons liberated by ions impinging onto the glass along the antenna contribute a power of ∼4.6 W. Adding the power of 3.7 W deposited to the part of the tube not affected by the antenna, the total power deposition responsible for the temperature rise of the tube is found to be about 25 W. The model shows that the power deposition is strongly nonuniform along the tube as a result of the antenna geometry. An estimate of the power deposited into the electrons by stochastic heating yields ∼1.4 W, compared to an estimate of 5.8 W for the measured power loss from electrons

Xenon ion beam characterization in a helicon double layer thruster

A current-free electric double layer is created in a helicon double layer thruster operating with xenon and compared to a recently developed theory. The Xe⁺ion beam formed by acceleration through the potential drop of the double layer is characterized radially using an electrostatic ion energy analyzer. For operating conditions of 500W rf power, 0.07mTorr gas pressure, and a maximum magnetic field of 125G, the measuredbeamvelocity is about 6kms⁻¹, the beam area is about 150cm², and the measuredbeam divergence is less than 6°

Grounded radio-frequency electrodes in contact with high density plasmas

An analytical model is developed of an asymmetric electrode system immersed in a plasma, consisting of two dc-grounded electrodes, where the smaller one is biased at 13.56MHz. The model is compared with a set of experiments performed in a high density low pressure plasma source (an electron cyclotron resonance source) where a second electrode is immersed into the plasma and powered by radio frequency. Excellent agreement is obtained between the analytical model and the experimental results. It is found that the time average plasma potential and the direct current(dc) flowing in the system during steady state are strongly dependent on both the rf voltage (or power) and the area ratio between the larger and smaller electrodes. For area ratios larger than 80, the dc current is large and the plasma potential is constant with respect to the applied rf voltage. For area ratios smaller than 80 but larger than unity, the plasma potential increases linearly with the applied rf voltage, and the dc current is reduced compared to the large area ratio case

Experiments and theory of an upstream ionization instability excited by an accelerated electron beam through a current-free double layer

A low-frequency instability varying from 10 to 20kHz has been discovered in the presence of a current-free double layer (DL) in a low-pressure expanding helicon plasma. The instability is observed using various electrostatic probes, such as Langmuir probes floating or biased to ion saturation and emissive probes measuring the plasma potential. A retarding field energy analyzer measuring the ion energy distribution function downstream of the double layer is used together with the LP to simultaneously observe the DL and the instability, confirming their coexistence. The frequency of the instability decreases with increasing neutral pressure, increases with increasing magnetic field in the source and increases with increasing rf power. A theory for an upstream ionizationinstability has been developed, in which electrons accelerated through the DL increase the ionization upstream and are responsible for the observed instability. The theory is in good agreement with the experimental results and shows that the frequency increases with the potential drop of the double layer and with decreasing chamber radius

Auger de-excitation of metastable molecules at metallic surfaces

We study secondary electron emission from metallic surfaces due to Auger de-excitation of diatomic metastable molecules. Our approach is based on an effective model for the two active electrons involved in the process -- a molecular electron described by a linear combination of atomic orbitals when it is bound and a two-center Coulomb wave when it is not and a metal electron described by the eigenfunctions of a step potential -- and employs Keldysh Green's functions. Solving the Dyson equation for the retarded Green's function by exponential resummation we are able to treat time-nonlocal self-energies and to avoid the wide-band approximation.Results are presented for the de-excitation of \NitrogenDominantMetastableState\ on aluminum and tungsten and discussed in view of previous experimental and theoretical investigations. We find quantitative agreement with experimental data for tungsten indicating that the effective model captures the physics of the process quite well. For aluminum we predict secondary electron emission due to Auger de-excitation to be one to two orders of magnitude smaller than the one found for resonant charge-transfer and subsequent auto-detachment.Comment: 15 pages, 9 figures, revised version using an improved single-electron basi