Standardized procedures important for improving single-component ceramic fuel cell technology

Standardized procedures important for improving single-component ceramic fuel cell technolog

Superionic Conductivity of Sm³⁺, Pr³⁺, and Nd³⁺ Triple-Doped Ceria through Bulk and Surface Two-Step Doping Approach

Sufficiently high oxygen ion conductivity of electrolyte is critical for good performance of low-temperature solid oxide fuel cells (LT-SOFCs). Notably, material conductivity, reliability, and manufacturing cost are the major barriers hindering LT-SOFC commercialization. Generally, surface properties control the physical and chemical functionalities of materials. Hereby, we report a Sm³⁺, Pr³⁺, and Nd³⁺ triple-doped ceria, exhibiting the highest ionic conductivity among reported doped-ceria oxides, 0.125 S cm^–1 at 600 °C. It was designed using a two-step wet-chemical coprecipitation method to realize a desired doping for Sm³⁺ at the bulk and Pr³⁺/Nd³⁺ at surface domains (abbreviated as PNSDC). The redox couple Pr³⁺/Pr⁴⁺ contributes to the extraordinary ionic conductivity. Moreover, the mechanism for ionic conductivity enhancement is demonstrated. The above findings reveal that a joint bulk and surface doping methodology for ceria is a feasible approach to develop new oxide-ion conductors with high impacts on advanced LT-SOFCs

Ni/NiO Exsolved Perovskite La_0.2Sr_0.7Ti_0.9Ni_0.1O_3−δ for Semiconductor-Ionic Fuel Cells: Roles of Electrocatalytic Activity and Physical Junctions

A semiconductor-ionic fuel cell (SIFC) is recognized as a promising technology and an alternative approach to reduce the operating temperature of solid oxide fuel cells. The development of alternative semiconductors substituting easily reduced transition metal oxide is a great challenge as high activity and durability should be satisfied simultaneously. In this study, the B-site Ni-doped La0.2Sr0.7Ti0.9Ni0.1O3−δ (LSTN) perovskite is synthesized and used as a potential semiconductor for SIFC. The in situ exsolution and A-site deficiency strategy enable the homogeneous decoration of Ni/NiO nanoparticles as reactive sites to improve the electrode reaction kinetics. It also supports the formation of basic ingredient of the Schottky junction to improve the charge separation efficiency. Furthermore, additional symmetric Ni0.8Co0.15Al0.05LiO2−δ (NCAL) electrocatalytic electrode layers significantly enhance the electrode reaction activity and cells’ charge separation efficiency, as confirmed by the superior open circuit voltage of 1.13 V (close to Nernst’s theoretical value) and peak power density of 650 mW cm–2 at 550 °C, where the latter is one order of magnitude higher than NCAL electrode-free SIFC. Additionally, a bulk heterojunction effect is proposed to illustrate the electron-blocking and ion-promoting processes of the semiconductor-ionic composite electrolyte in SIFCs, based on the energy band values of the applied materials. Overall, we found that the energy conversion efficiency of novel SIFC can be remarkably improved through in situ exsolution and intentional introduction of the catalytic functionality

Junction and energy band on novel semiconductor-based fuel cells

Fuel cells are highly efficient and green power sources. The typical membrane electrode assembly is necessary for common electrochemical devices. Recent research and development in solid oxide fuel cells have opened up many new opportunities based on the semiconductor or its heterostructure materials. Semiconductor-based fuel cells (SBFCs) realize the fuel cell functionality in a much more straightforward way. This work aims to discuss new strategies and scientific principles of SBFCs by reviewing various novel junction-types/interfaces, i.e., bulk and planar p-n junction, Schottky junction and n-i type interface contact. New designing methodologies of SBFCs from energy band/alignment and built-in electric field (BIEF) which block the internal electronic transport while assisting interfacial superionic transport, and subsequently enhance device performance, are comprehensively reviewed. This work highlights the recent advances of SBFCs and provides new methodology and understanding with significant importance for both fundamental and applied R&D on new-generation fuel cell materials and technologies

Semiconductor electrochemistry for clean energy conversion and storage

Semiconductors and the associated methodologies applied to electrochemistry have recently grown as an emerging field in energy materials and technologies. For example, semiconductor membranes and heterostructure fuel cells are new technological trend, which differ from the traditional fuel cell electrochemistry principle employing three basic functional components: anode, electrolyte, and cathode. The electrolyte is key to the device performance by providing an ionic charge flow pathway between the anode and cathode while preventing electron passage. In contrast, semiconductors and derived heterostructures with electron (hole) conducting materials have demonstrated to be much better ionic conductors than the conventional ionic electrolytes. The energy band structure and alignment, band bending and built-in electric field are all important elements in this context to realize the necessary fuel cell functionalities. This review further extends to semiconductor- based electrochemical energy conversion and storage, describing their fundamentals and working principles, with the intention of advancing the understanding of the roles of semiconductors and energy bands in electrochemical devices for energy conversion and storage, as well as applications to meet emerging demands widely involved in energy applications, such as photocatalysis/water splitting devices, batteries and solar cells. This review provides new ideas and new solutions to problems beyond the conventional electrochemistry and presents new interdisciplinary approaches to develop clean energy conversion and storage technologies