In Situ Structure Characterization in Slot-Die-Printed All-Polymer Solar Cells with Efficiency Over 9%

Herein, high-performance printed all-polymer solar cells (all-PSCs) based on a bulk-heterojunction (BHJ) blend film are demonstrated using PTzBI as the donor and N2200 as the acceptor. A slot-die process is used to prepare the BHJ blend, which is a cost-effective, high-throughput approach to achieve large-area photovoltaic devices. The real-time crystallization of polymers in the film drying process is investigated by in situ grazing incidence wide-angle X-ray scattering characterization. Printing is found to significantly improve the crystallinity of the polymer blend in comparison with spin coating. Moreover, printing with 1,8-diiodooctane as the solvent additive enhances the polymer aggregation and crystallization during solvent evaporation, eventually leading to multi-length-scale phase separation, with PTzBI-rich domains in-between the N2200 crystalline fibers. This unique morphology achieved by printing fabrication results in an impressively high power conversion efficiency of 9.10%, which is the highest efficiency reported for printed all-PSCs. These findings provide important guidelines for controlling film drying dynamics for processing all-PSCs

Branching ratio and CP asymmetry of Bs→π+π−B_s \to \pi^+ \pi^- decays in the perturbative QCD approach

In this paper, we calculate the decay rate and CP asymmetry of the $B_s \to \pi^+\pi^-$ decay in perturbative QCD approach with Sudakov resummation. Since none of the quarks in final states is the same as those of the initial $B_s$ meson, this decay can occur only via annihilation diagrams in the standard model. Besides the current-current operators, the contributions from the QCD and electroweak penguin operators are also taken into account. We find that (a) the branching ratio is about $4 \times 10^{-7}$; (b) the penguin diagrams dominate the total contribution; and (c) the direct CP asymmetry is small in size: no more than $3$; but the mixing-induced CP asymmetry can be as large as ten percent testable in the near future LHC-b experiments.Comment: 12 pages, 4 figures included, RevTe

Trapped interacting two-component bosons

In this paper we solve one dimensional trapped SU(2) bosons with repulsive $\delta$-function interaction by means of Bethe-ansatz method. The features of ground state and low-lying excited states are studied by numerical and analytic methods. We show that the ground state is an isospin "ferromagnetic" state which differs from spin-1/2 fermions system. There exist three quasi-particles in the excitation spectra, and both holon-antiholon and holon-isospinon excitations are gapless for large systems. The thermodynamics equilibrium of the system at finite temperature is studied by thermodynamic Bethe ansatz. The thermodynamic quantities, such as specific heat etc. are obtained for the case of strong coupling limit.Comment: 15 pages, 9 figure