Outstanding supercapacitive properties of Mn-doped TiO2 micro/nanostructure porous film prepared by anodization method.

Mn-doped TiO2 micro/nanostructure porous film was prepared by anodizing a Ti-Mn alloy. The film annealed at 300 °C yields the highest areal capacitance of 1451.3 mF/cm(2) at a current density of 3 mA/cm(2) when used as a high-performance supercapacitor electrode. Areal capacitance retention is 63.7% when the current density increases from 3 to 20 mA/cm(2), and the capacitance retention is 88.1% after 5,000 cycles. The superior areal capacitance of the porous film is derived from the brush-like metal substrate, which could greatly increase the contact area, improve the charge transport ability at the oxide layer/metal substrate interface, and thereby significantly enhance the electrochemical activities toward high performance energy storage. Additionally, the effects of manganese content and specific surface area of the porous film on the supercapacitive performance were also investigated in this work

An Effective Strategy to Build Up a Balanced Test Suite for Spectrum-Based Fault Localization

During past decades, many automated software faults diagnosis techniques including Spectrum-Based Fault Localization (SBFL) have been proposed to improve the efficiency of software debugging activity. In the field of SBFL, suspiciousness calculation is closely related to the number of failed and passed test cases. Studies have shown that the ratio of the number of failed and passed test case has more significant impact on the accuracy of SBFL than the total number of test cases, and a balanced test suite is more beneficial to improving the accuracy of SBFL. Based on theoretical analysis, we proposed an PNF (Passed test cases, Not execute Faulty statement) strategy to reduce test suite and build up a more balanced one for SBFL, which can be used in regression testing. We evaluated the strategy making experiments using the Siemens program and Space program. Experiments indicated that our PNF strategy can be used to construct a new test suite effectively. Compared with the original test suite, the new one has smaller size (average 90% test case was reduced in experiments) and more balanced ratio of failed test cases to passed test cases, while it has the same statement coverage and fault localization accuracy

μ-Benzene-1,2,4,5-tetra­carboxyl­ato-κ4 O 1,O 2:O 4,O 5-bis­[diaqua(phen­an­thro­line-κ2 N,N′)nickel(II)] 0.67-hydrate

The asymmetric unit of the title compound, [Ni2(C10H2O8)(C12H8N2)2(H2O)4]·0.67H2O, contains one complete binuclear complex and one half-mol­ecule, the latter being completed by crystallographic inversion symmetry, and 0.67 of a solvent water molecule. Each Ni2+ cation is coordinated by a 1,10-phenanthroline ligand, a bidentate benzene-1,2,4,5-tetra­carboxyl­ate (btec) tetra-anion and two water mol­ecules to generate a distorted cis-NiN2O4 octa­hedral coordination geometry. The btec species bridges the metal ions. In the crystal, the clusters and uncoordinated water mol­ecules are linked by O—H⋯O hydrogen bonds and π–π inter­actions [shortest centroid–centroid separation = 3.596 (2) Å] to form a three-dimensional network