107 research outputs found

    Improving multi-objective reservoir operation optimization with sensitivity-informed dimension reduction

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    There is another ORE record for this article: http://hdl.handle.net/10871/21284This study investigates the effectiveness of a sensitivity-informed method for multi-objective operation of reservoir systems, which uses global sensitivity analysis as a screening tool to reduce computational demands. Sobol's method is used to screen insensitive decision variables and guide the formulation of the optimization problems with a significantly reduced number of decision variables. This sensitivity-informed method dramatically reduces the computational demands required for attaining high-quality approximations of optimal trade-off relationships between conflicting design objectives. The search results obtained from the reduced complexity multi-objective reservoir operation problems are then used to pre-condition the full search of the original optimization problem. In two case studies, the Dahuofang reservoir and the inter-basin multi-reservoir system in Liaoning province, China, sensitivity analysis results show that reservoir performance is strongly controlled by a small proportion of decision variables. Sensitivity-informed dimension reduction and pre-conditioning are evaluated in their ability to improve the efficiency and effectiveness of multi-objective evolutionary optimization. Overall, this study illustrates the efficiency and effectiveness of the sensitivity-informed method and the use of global sensitivity analysis to inform dimension reduction of optimization problems when solving complex multi-objective reservoir operation problems.China Postdoctoral Science FoundationNatural Science Foundation of Chin

    Fast wide-field quantum sensor based on solid-state spins integrated with a SPAD array

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    Achieving fast, sensitive, and parallel measurement of a large number of quantum particles is an essential task in building large-scale quantum platforms for different quantum information processing applications such as sensing, computation, simulation, and communication. Current quantum platforms in experimental atomic and optical physics based on CMOS sensors and CCD cameras are limited by either low sensitivity or slow operational speed. Here we integrate an array of single-photon avalanche diodes with solid-state spin defects in diamond to build a fast wide-field quantum sensor, achieving a frame rate up to 100~kHz. We present the design of the experimental setup to perform spatially resolved imaging of quantum systems. A few exemplary applications, including sensing DC and AC magnetic fields, temperature, strain, local spin density, and charge dynamics, are experimentally demonstrated using an NV ensemble diamond sample. The developed photon detection array is broadly applicable to other platforms such as atom arrays trapped in optical tweezers, optical lattices, donors in silicon, and rare earth ions in solids

    Effect of Lifestyle Changes after Percutaneous Coronary Intervention on Revascularization

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    Objective. Whether optimal cardiovascular health metrics may reduce the risk of cardiovascular events in secondary prevention is uncertain. The study was conducted to evaluate the influence of lifestyle changes on clinical outcomes among the subjects underwent percutaneous coronary intervention (PCI). Methods. The study group consists of 17,099 consecutive PCI patients. We recorded data on subject lifestyle behavior changes after their procedure. Patients were categorized as ideal, intermediate, or poor CV health according to a modified Life’s Simple 7 score (on body mass, smoking, physical activity, diet, cholesterol, blood pressure, and glucose). Multivariable COX regression was used to evaluate the association between CV health and revascularization event. We also tested the impact of cumulative cardiovascular health score on reoccurrence of cardiovascular event. Results. During a 3-year median follow-up, 1,583 revascularization events were identified. The observed revascularization rate was 8.0%, 9.3%, and 10.6% in the group of patients with optimal (a modified Life’s Simple 7 score of 11–14), average (score = 9 or 10), or inadequate (less or equal than 8) CV health, respectively. After multivariable analysis, the adjusted hazard ratios were 0.83 (95% CI: 0.73–0.94) and 0.89 (95% CI: 0.79–0.99) for patients with optimal and average lifestyle changes comparing with the inadequate tertile ( for trend = 0.003). In addition, each unit increase in above metrics was associated with a decrease risk of revascularization (HR, 0.96; 95% confidence interval, 0.93–0.98; ). Conclusion. Ideal CV health related to lower incidence of cardiovascular events, even after the percutaneous coronary intervention. Revascularization can be reduced by lifestyle changes. The cardiovascular health metrics could be extrapolated to secondary prevention and need for further validation

    In situ spectroelectrochemical probing of CO redox landscape on copper single-crystal surfaces

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    Electrochemical reduction of CO(2)_{(2)}to value-added chemicals and fuels is a promising strategy to sustain pressing renewable energy demands and to address climate change issues. Direct observation of reaction intermediates during the CO(2)_{(2)}reduction reaction will contribute to mechanistic understandings and thus promote the design of catalysts with the desired activity, selectivity, and stability. Herein, we combined in situ electrochemical shell-isolated nanoparticle-enhanced Raman spectroscopy and ab initio molecular dynamics calculations to investigate the CORR process on Cu single-crystal surfaces in various electrolytes. Competing redox pathways and coexistent intermediates of CO adsorption (*COatop_{atop}and *CObridge_{bridge}), dimerization (protonated dimer *HOCCOH and its dehydrated *CCO), oxidation (*CO2_{2}^{−}and *CO3_{3}2^{2−}), and hydrogenation (*CHO), as well as Cu-Oad_{ad}/Cu-OHad_{ad}species at Cu-electrolyte interfaces, were simultaneously identified using in situ spectroscopy and further confirmed with isotope-labeling experiments. With AIMD simulations, we report accurate vibrational frequency assignments of these intermediates based on the calculated vibrational density of states and reveal the corresponding species in the electrochemical CO redox landscape on Cu surfaces. Our findings provide direct insights into key intermediates during the CO(2)_{(2)}RR and offer a full-spectroscopic tool (40–4,000 cm1^{−1}) for future mechanistic studies

    Experimental comparison of Yb/Al/Ce and Yb/Al/P co-doped fibers on the suppression of transverse mode instability

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    We presented an experimental comparison of the core-composition difference on the suppression of the photodarkening and transverse mode instability effects. Two core-composition fibers, entailing Yb/Al/Ce and Yb/Al/P co-doped fibers, were fabricated by MCVD process combined with solution doping technique. The parameters of two fibers were almost the same. The PD-induced loss at equilibrium was 3.94 dB/m at 702 nm in Yb/Al/Ce fiber, while it was 0.99 dB/m in Yb/Al/P fiber. To obtain a deeper understanding of the impact of PD on laser performance, a bidirectional pumping fiber amplifier was constructed. Compared with Yb/Al/Ce co-doped fiber, the TMI thresholds of Yb/Al/P co-doped fiber were enhanced in co-pumped and counter-pumped schemes. Meanwhile, the slope efficiency in bidirectional scheme was promoted by 4%. Moreover, the transmittance at 638 nm confirmed the superior PD resistance of Yb/Al/P co-doped fiber. These experimental results pave the way for the further development of high-power fiber lasers

    Research on mechanical properties of high-performance cable-in-conduit conductors with different design

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    The China Fusion Engineering Test Reactor (CFETR) is a new tokamak fusion reactor under preliminary design, where the toroidal field (TF) coil has been designed to create a magnetic field of over 14.3 T. The TF conductors need to operate stably at 14.3 T, requiring the exclusion of conductor performance degradation from thermal and electromagnetic loading as much as possible. The maximum Lorentz force will reach about 1200 kN m-1, which is much higher than that of ITER conductors. In previous research, performance degradation was found during electromagnetic cycles and warm-up-cool-down cycles. A correlation was found between a conductor's degradation and its mechanical properties. According to the analysis, a conductor with a short twist pitch (STP) scheme or a copper wound superconducting strand (CWS) design has large stiffness, which enables significant performance improvement in terms of the electromagnetic and thermal load cycling. The cable stiffness is closely related to the number of inter-strand contact points inside the conductor. Based on this concept, four types of prototype cable-in-conduit conductor samples with STP and CWS design were manufactured. The number of inter-strand contact points was analyzed, and mechanical transverse load testing was performed at 77 K. The results show that the conductors with more contact points per unit length exhibit a higher stiffness. However, the cable designed with high cable stiffness caused strand indentation, which was also investigated. In this paper, the conductor design and experimental results are discussed and compared with ITER TF and central solenoid conductors.</p

    Dynamics and control of active sites in hierarchically nanostructured cobalt phosphide/chalcogenide-based electrocatalysts for water splitting

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    The rational design of efficient electrocatalysts for industrial water splitting is essential to generate sustainable hydrogen fuel. However, a comprehensive understanding of the complex catalytic mechanisms under harsh reaction conditions remains a major challenge. We apply a self-templated strategy to introduce hierarchically nanostructured “all-surface” Fe-doped cobalt phosphide nanoboxes (Co@CoFe–P NBs) as alternative electrocatalysts for industrial-scale applications. Operando Raman spectroscopy and X-ray absorption spectroscopy (XAS) experiments were carried out to track the dynamics of their structural reconstruction and the real catalytically active intermediates during water splitting. Our operando analyses reveal that partial Fe substitution in cobalt phosphides promotes a structural reconstruction into P–Co–O–Fe–P configurations with low-valence metal centers (M0/M+) during the hydrogen evolution reaction (HER). Results from density functional theory (DFT) demonstrate that these in situ reconstructed configurations significantly enhance the HER performance by lowering the energy barrier for water dissociation and by facilitating the adsorption/desorption of HER intermediates (H*). The competitive activity in the oxygen evolution reaction (OER) arises from the transformation of the reconstructed P–Co–O–Fe–P configurations into oxygen-bridged, high-valence CoIV–O–FeIV moieties as true active intermediates. In sharp contrast, the formation of such CoIII/IV–O–FeIII/IV moieties in Co–FeOOH is hindered under the same conditions, which outlines the key advantages of phosphide-based electrocatalysts. Ex situ studies of the as-synthesized reference cobalt sulfides (Co–S), Fe doped cobalt selenides (Co@CoFe–Se), and Fe doped cobalt tellurides (Co@CoFe–Te) further corroborate the observed structural transformations. These insights are vital to systematically exploit the intrinsic catalytic mechanisms of non-oxide, low-cost, and robust overall water splitting electrocatalysts for future energy conversion and storage

    Performance of first insert coil with REBCO CICC sub-size cable exceeding 6 kA at 21 T magnetic field

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    The Institute of Plasma Physics at the Chinese Academy of Sciences is developing the REBCO cable in conduit conductor (CICC) technology for applications in next-generation nuclear fusion devices. The aim is to develop a CICC comprised of six REBCO sub-cables to satisfy the requirements of operation with a current of around 40 kA and a peak field of up to 20 T. To qualify the performance of the sub-size REBCO cable to be used in the CICC, two 25-turn insert solenoids have been designed, manufactured and tested at a current exceeding 6 kA subjected in a background field supplied by a water-cooled resistive magnet. The insert solenoid, wound from a 11.5 m long REBCO CORC®^{®} cable, was designed to investigate its current carrying capacity under high field and electromagnetic (EM) load at 4.2 K. Tests were performed under a background magnetic field up to 18.5 T, resulting in a peak magnetic field on the innermost layer turns of around 21.1 T at an operating current of 6.3 kA. The effects of operation with cyclic EM loads were tested by repeated current ramps to around 95% of the critical current. Moreover, the V–I characteristics were measured at 77 K and the self-field, to check the effects from warm-up and cool-down (WUCD) cycles between room temperature and 77 K with liquid nitrogen. The results show no obvious degradation after dozens of high-current test cycles in background fields ranging from 10 T to 18.5 T. The insert solenoid demonstrates the stable operation of the REBCO sub-size cable for CICC with EM loads of about 90 kN m1^{−1} and WUCD cycles between room temperature and 77 K. These promising results indicate the potential of this technology for further applicationsin particular, for full-size CICC for high-performance fusion magnets

    Source rupture process of the 2015 Gorkha, Nepal Mw7.9 earthquake and its tectonic implications

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    On 25 April, 2015, an Mw7.9 earthquake occurred in Nepal, which caused great economic loss and casualties. However, almost no surface ruptures were observed. Therefore, in order to interpret the phenomenon, we study the rupture process of the earthquake to seek answers. Inversion of teleseismic body-wave data is applied to estimate the rupture process of the 2015 Nepal earthquake. To obtain stable solutions, smoothing and non-negative constraints are introduced. 48 teleseismic stations with good coverage are chosen. Finite fault model is established with length and width of 195 km and 150 km, and we set the initial seismic source parameters referring to CMT solutions. Inversion results indicate that the focal mechanism of this earthquake is a thrust fault type, and the strike, dip and rake angle are in accordance with CMT results. The seismic moment is 0.9195 × 1021 Nm (Mw7.9), and source duration is about 70 s. The rupture nucleated near the hypocenter and then propagated along the dip direction to the southeast, and the maximum slip amounts to 5.2 m. Uncertainties on the amount of slip retrieved by different inversion methods still exist, the overall characteristics are inconsistent. The lack of shallow slip during the 2015 Gorkha earthquake implies future seismic hazard and this region should be paid more attention to
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