Template epitaxial growth of thermoelectric Bi/BiSb superlattice nanowires by charge-controlled pulse electrodeposition

© The Electrochemical Society, Inc. 2009. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in The Journal of The Electrochemical Society, 156(9), 2009.Bi/BiSb superlattice nanowires (SLNWs) with a controllable and very small bilayer thickness and a sharp segment interface were grown by adopting a charge-controlled pulse electrodeposition. The deposition parameters were optimized to ensure an epitaxial growth of the SLNWs with a preferential orientation. The segment length and bilayer thickness of the SLNWs can be controlled simply by changing the modulating time, and the consistency of the segment length can be well maintained by our approach. The Bravais law in the electrodeposited nanowires is verified by the SLNW structure. The current–voltage measurement shows that the SLNWs have good electrical conductance, particularly those with a smaller bilayer thickness. The Bi/BiSb SLNWs might have excellent thermoelectric performances.National Natural Science Foundation of China and the National Major Project of Fundamental Research for Nanomaterials and Nanostructures

Thermodynamics of the Mg-B system: Implications for the deposition of MgB2 thin films

We have studied thermodynamics of the Mg-B system with the modeling technique CALPHAD using a computerized optimization procedure. Temperature-composition, pressure-composition, and pressure-temperature phase diagrams under different conditions are obtained. The results provide helpful insights into appropriate processing conditions for thin films of the superconducting phase, MgB2, including the identification of the pressure/temperature region for adsorption-controlled growth. Due to the high volatility of Mg, MgB2 is thermodynamically stable only under fairly high Mg overpressures for likely growth temperatures. This constraint places severe temperature constraints on deposition techniques employing high vacuum conditions

Insulator-metal transition shift related to magnetic polarons in La0.67-xYxCa0.33MnO3

The magnetic transport properties have been measured for La0.67-xYxCa0.33MnO3 (0 <= x <= 0.14) system. It was found that the transition temperature Tp almost linearly moves to higher temperature as H increases. Electron spin resonance confirms that above Tp, there exist ferromagnetic clusters. From the magnetic polaron point of view, the shift of Tp vs. H was understood, and it was estimated that the size of the magnetic polaron is of 9.7~15.4 angstrom which is consistent with the magnetic correlation length revealed by the small-angle neutron-scattering technique. The transport properties at temperatures higher than Tp conform to the variable-range hopping mechanism.Comment: 22 pages, 6 figures, pdf, to be published in Euro. Phys. J.

Effect factors of part-load performance for various Organic Rankine cycles using in engine waste heat recovery

The Organic Rankine Cycle (ORC) is regarded as one of the most promising waste heat recovery technologies for electricity generation engines. Since the engine usually operates under different working conditions, it is important to research the part-load performance of the ORC. In order to reveal the effect factors of part-load performance, four different forms of ORCs are compared in the study with dynamic math models established in SIMULINK. They are the ORC applying low temperature working fluid R245fa with a medium heat transfer cycle, the ORCs with high temperature working fluid toluene heated directly by exhaust condensing at low pressure and high pressure, and the double-stage ORC. It is regarded that the more slowly the system output power decreases, the better part-load performance it has. Based on a comparison among the four systems, the effects of evaporating pressure, condensing condition, working fluid, and system structure on part-load performance are revealed in the work. Further, it is found that the system which best matches with the heat source not only performs well under the design conditions, but also has excellent part-load performance