Di-μ-thio­cyanato-bis­({2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II))

The title compound, [Cu2(NCS)2(C13H17Cl2N2O)2], was obtained by the reaction of 3,5-dichloro­salicylaldehyde, N,N-diethyl­ethane-1,2-diamine, sodium thio­cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl­amino­ethyl­imino)meth­yl]phenol, one N atom of a thio­cyanate group, and one S atom of a symmetry-related thio­cyanate group, forming a slightly distorted square-pyramidal geometry

Study of the cytological features of bone marrow mesenchymal stem cells from patients with neuromyelitis optica.

Neuromyelitis optica (NMO) is a refractory autoimmune inflammatory disease of the central nervous system without an effective cure. Autologous bone marrow‑derived mesenchymal stem cells (BM‑MSCs) are considered to be promising therapeutic agents for this disease due to their potential regenerative, immune regulatory and neurotrophic effects. However, little is known about the cytological features of BM‑MSCs from patients with NMO, which may influence any therapeutic effects. The present study aimed to compare the proliferation, differentiation and senescence of BM‑MSCs from patients with NMO with that of age‑ and sex‑matched healthy subjects. It was revealed that there were no significant differences in terms of cell morphology or differentiation capacities in the BM‑MSCs from the patients with NMO. However, in comparison with healthy controls, BM‑MSCs derived from the Patients with NMO exhibited a decreased proliferation rate, in addition to a decreased expression of several cell cycle‑promoting and proliferation‑associated genes. Furthermore, the cell death rate increased in BM‑MSCs from patients under normal culture conditions and an assessment of the gene expression profile further confirmed that the BM‑MSCs from patients with NMO were more vulnerable to senescence. Platelet‑derived growth factor (PDGF), as a major mitotic stimulatory factor for MSCs and a potent therapeutic cytokine in demyelinating disease, was able to overcome the decreased proliferation rate and increased senescence defects in BM‑MSCs from the patients with NMO. Taken together, the results from the present study have enabled the proposition of the possibility of combining the application of autologous BM‑MSCs and PDGF for refractory and severe patients with NMO in order to elicit improved therapeutic effects, or, at the least, to include PDGF as a necessary and standard growth factor in the current in vitro formula for the culture of NMO patient‑derived BM‑MSCs

Quantity and quality of China's water from demand perspectives

China is confronted with an unprecedented water crisis regarding its quantity and quality. In this study, we quantified the dynamics of China's embodied water use and chemical oxygen demand (COD) discharge from 2010 to 2015. The analysis was conducted with the latest available water use data across sectors in primary, secondary and tertiary industries and input-output models. The results showed that (1) China's water crisis was alleviated under urbanisation. Urban consumption occupied the largest percentages (over 30%) of embodied water use and COD discharge, but embodied water intensities in urban consumption were far lower than those in rural consumption. (2) The 'new normal' phase witnessed the optimisation of China's water use structures. Embodied water use in light-manufacturing and tertiary sectors increased while those in heavy-manufacturing sectors (except chemicals and transport equipment) dropped. (3) Transformation of China's international market brought positive effects on its domestic water use. China's water use (116-80 billion tonnes (Bts))9 and COD discharge (3.95-2.22 million tonnes (Mts)) embodied in export tremendously decreased while its total export values (11-25 trillion CNY) soared. Furthermore, embodied water use and COD discharge in relatively low-end sectors, such as textile, started to transfer from international to domestic markets when a part of China's production activities had been relocated to other developing countries

Transport Coefficients for Holographic Hydrodynamics at Finite Energy Scale

We investigate the relations between black hole thermodynamics and holographic transport coefficients in this paper. The formulae for DC conductivity and diffusion coefficient are verified for electrically single-charged black holes. We examine the correctness of the proposed expressions by taking charged dilatonic and single-charged STU black holes as two concrete examples, and compute the flows of conductivity and diffusion coefficient by solving the linear order perturbation equations. We then check the consistence by evaluating the Brown-York tensor at a finite radial position. Finally, we find that the retarded Green functions for the shear modes can be expressed easily in terms of black hole thermodynamic quantities and transport coefficients.Comment: 33 pages,4 figures,to appear in Advances in High Energy Physic

A Descriptive Model of Robot Team and the Dynamic Evolution of Robot Team Cooperation

At present, the research on robot team cooperation is still in qualitative analysis phase and lacks the description model that can quantitatively describe the dynamical evolution of team cooperative relationships with constantly changeable task demand in Multi-robot field. First this paper whole and static describes organization model HWROM of robot team, then uses Markov course and Bayesian theorem for reference, dynamical describes the team cooperative relationships building. Finally from cooperative entity layer, ability layer and relative layer we research team formation and cooperative mechanism, and discuss how to optimize relative action sets during the evolution. The dynamic evolution model of robot team and cooperative relationships between robot teams proposed and described in this paper can not only generalize the robot team as a whole, but also depict the dynamic evolving process quantitatively. Users can also make the prediction of the cooperative relationship and the action of the robot team encountering new demands based on this model. Journal web page & a lot of robotic related papers www.ars-journal.co

Ballistic Thermal Rectification in Asymmetric Three-Terminal Mesoscopic Dielectric Systems

By coupling the asymmetric three-terminal mesoscopic dielectric system with a temperature probe, at low temperature, the ballistic heat flux flow through the other two asymmetric terminals in the nonlinear response regime is studied based on the Landauer formulation of transport theory. The thermal rectification is attained at the quantum regime. It is a purely quantum effect and is determined by the dependence of the ratio $\tau_{RC}(\omega)/\tau_{RL}(\omega)$ on $\omega$, the phonon's frequency. Where $\tau_{RC}(\omega)$ and $\tau_{RL}(\omega)$ are respectively the transmission coefficients from two asymmetric terminals to the temperature probe, which are determined by the inelastic scattering of ballistic phonons in the temperature probe. Our results are confirmed by extensive numerical simulations.Comment: 10 pages, 4 figure