A Comparison of Electrical Breakdown Characteristics of Composite Materials Prepared With Unmodified Micro and Nano Scale Barium Titanate

High permittivity polymer matrix composites (PMCs) have been widely researched, especially in the field of microelectronics. For this study, high permittivity materials were investigated for their potential to form part of a multi-layer electric field detector. The two main requirements for such composites were high permittivity and a dielectric strength comparable to most standard polymers used as dielectric materials. Polystyrene was selected as a host polymer due to its high dielectric strength and amorphous structure. Barium titanate, a ferroelectric ceramic from the perovskite family, was selected as a high permittivity filler. Polymer permittivity in PMCs is usually orders of magnitude lower compared to the filler permittivity, although the resultant permittivity of the composite is generally markedly lower than the permittivity of the filler may suggest. This is because very little energy is stored in the ceramic filler, such that any increase in composite permittivity is due to an increase in the average field with the polymer matrix.[1]Micro and nano scale barium titanate was blended into polystyrene in an effort to discern the initial differences between composites prepared with the two different filler types. It was found that the micro scale barium titanate was well dispersed and from studying SEM micrographs, appeared to have a good particle size distribution. The nanoscale barium titanate was found to be very poorly dispersed in polystyrene, with a wide particle size distributions formed of weakly bound aggregations and some seemingly chemically bonded agglomerations which were regular in shape with a surface texture which was indicative of tightly bound primary particles. Consistent with the differences in particle dispersion within the micro and nano composites, there was a marked difference in AC breakdown strength between the different materials. All electrical breakdown data was analysed using a 2 parameter Weibull distribution. Figure 1 compares the ? values for the micro and nano composites at different filler loadings.<br/

A Comparison between Electroluminescence Models and Experimental Results

Electrical insulation ages and degrades until its eventual failure under electrical stress. One cause of this relates to the movement and accumulation of charge within the insulation. The emission of a low level of light from polymeric materials while under electrical stressing occurs before the onset of currently detectable material degradation. This light is known as electroluminescence (EL) and under an ac electric field is thought to relate to the interaction of charge in close proximity to the electrode-polymer interface. Understanding the cause of this light emission gives a very high-resolution method of monitoring charge interaction and its influence on material ageing. A possible cause of this light emission is the bipolar charge recombination theory. This theory involves the injection, trapping and recombination of charge carriers during each half cycle of the applied field [1]. This work compares two models that to simulate the EL emission according to this bipolar charge recombination theory. Model 1 assumes a fixed space charge region and all injected charge is uniformly distributed in this region with charges able to either become trapped or to recombine with opposite polarity charge carriers [2]. This recombination relates directly the excitation needed for the emission of a photon of light as measured in experiments. Model 2 develops on this by accounting for the transport and extraction of charge with an exponential distribution of trap levels rather than a uniform distribution [3]. Figure 1 shows a good correlation between the two models and experimental data. The full paper will describe the models in more detail and present results comparing the simulated and experimental results under various applied waveforms. Model 1 and model 2 both provide a good correlation with experimental data but model 2 allows a greater understanding of the space charge profile in the region close to the electrodes as well as the shape of the conduction current. Further work involves developing these models to support changes in the charge trapping profiles due to material ageing and supporting simulated results with measured conduction current

Recurrence Formulas for Fully Exponentially Correlated Four-Body Wavefunctions

Formulas are presented for the recursive generation of four-body integrals in which the integrand consists of arbitrary integer powers (>= -1) of all the interparticle distances r_ij, multiplied by an exponential containing an arbitrary linear combination of all the r_ij. These integrals are generalizations of those encountered using Hylleraas basis functions, and include all that are needed to make energy computations on the Li atom and other four-body systems with a fully exponentially correlated Slater-type basis of arbitrary quantum numbers. The only quantities needed to start the recursion are the basic four-body integral first evaluated by Fromm and Hill, plus some easily evaluated three-body "boundary" integrals. The computational labor in constructing integral sets for practical computations is less than when the integrals are generated using explicit formulas obtained by differentiating the basic integral with respect to its parameters. Computations are facilitated by using a symbolic algebra program (MAPLE) to compute array index pointers and present syntactically correct FORTRAN source code as output; in this way it is possible to obtain error-free high-speed evaluations with minimal effort. The work can be checked by verifying sum rules the integrals must satisfy.Comment: 10 pages, no figures, accepted by Phys. Rev. A (January 2009

Electromagnetic field application to underground power cable detection

Before commencing excavation or other work where power or other cables may be buried, it is important to determine the location of cables to ensure that they are not damaged. This paper describes a method of power-cable detection and location that uses measurements of the magnetic field produced by the currents in the cable, and presents the results of tests performed to evaluate the method. The cable detection and location program works by comparing the measured magnetic field signal with values predicted using a simple numerical model of the cable. Search coils are used as magnetic field sensors, and a measurement system is setup to measure the magnetic field of an underground power cable at a number of points above the ground so that it can detect the presence of an underground power cable and estimate its position. Experimental investigations were carried out using a model and under real site test conditions. The results show that the measurement system and cable location method give a reasonable prediction for the position of the target cable

Detection and Location of Underground Power Cable using Magnetic Field Technologies

The location of buried underground electricity cables is becoming a major engineering and social issue worldwide. Records of utility locations are relatively scant, and even when records are available, they almost always refer to positions relative to ground-level physical features that may no longer exist or that may have been moved or altered. The lack of accurate positioning records of existing services can cause engineering and construction delays and safety hazards when new construction, repairs, or upgrades are necessary. Hitting unknown underground obstructions has the potential to cause property damage, injuries and, even deaths. Thus, before commencing excavation or other work where power or other cables may be buried, it is important to determine the location of the cables to ensure that they are not damaged during the work. This paper describes the use of an array of passive magnetic sensors (induction coils) together with signal processing techniques to detect and locate underground power cables. The array consists of seven identical coils mounted on a support frame; one of these coils was previously tested under laboratory conditions, and relevant results have been published in [1]. A measurement system was constructed that uses a battery powered data acquisition system with two NI 9239 modules connected to the coil array, and controlled by a laptop. The system is designed to measure the magnetic field of an underground power cable at a number of points above the ground. A 3 by 3 m test area was chosen in one of our campus car parks. This area was chosen because the university’s utility map shows an isolated power cable there. Measurements were taken with the array in 16 different test positions, and compared with the values predicted for a long straight horizontal cable at various positions. Finally, error maps were plotted for different Z-coordinate values, showing the minimum fitting error for each position in this plane. One such map is shown in Figure 1; the low error values of 4-5% give a high degree of confidence that most of the measured signal is due to a cable near to these positions. This view is supported by the fact that the university’s utility map shows the cable at X = 1.4 m, and by amplitude measurements taken with a hand-held magnetic field meter

Non-perturbative embedding of local defects in crystalline materials

We present a new variational model for computing the electronic first-order density matrix of a crystalline material in presence of a local defect. A natural way to obtain variational discretizations of this model is to expand the difference Q between the density matrix of the defective crystal and the density matrix of the perfect crystal, in a basis of precomputed maximally localized Wannier functions of the reference perfect crystal. This approach can be used within any semi-empirical or Density Functional Theory framework.Comment: 13 pages, 4 figure

A search for X-ray pulsations from the galactic center

Data from the SAS-3 satellite were used in a search for X-ray pulsations from the direction of the galactic center. No periodic X-ray behavior was detected in the frequency interval 0.6 Hz to 0.0006 Hz and energy range 2.5 - 35 keV. For periods less than 60 sec, the upper limit to the amplitude of any pulsation in the 2.5 - 10 keV band is approximately .0017 cts/sq cm/s. This corresponds to a pulsed fraction of approximately 1.3 percent of the total GCX flux. Somewhat higher limits apply for longer periods and for energies greater than 10 keV

Smart Materials as Intelligent Insulation

In order to provide a robust infrastructure for the transmission and distribution of electrical power, understanding and monitoring equipment ageing and failure is of paramount importance. Commonly, failure is associated with degradation of the dielectric material; therefore the introduction of a smart moiety into the material is a potentially attractive means of continual condition monitoring. It is important that any introduction of smart groups into the dielectric does not have any detrimental effect on the desirable electrical and mechanical properties of the bulk material. Initial work focussed on the introduction of fluorophores into a model dielectric system. Fluorescence is known to be a visible effect even at very low concentrations of active fluorophores and therefore was thought well suited to such an application. It was necessary both to optimise the active fluorophore itself and to determine the most appropriate manner in which to introduce the fluorophores into the insulating system. This presentation will describe the effect of introducing fluorophores into polymeric systems on the dielectric properties of the material and the findings thus far [1]. Alternative smart material systems will also be discussed along with the benefits and limitations of smart materials as electric field sensors

The Nature of the Giant Outbursts in the Bursting Pulsar GRO J 1744-28

We investigate the possible role of an accretion disk instability in producing the giant outbursts seen in GRO J1744-28. Specifically, we study the global, time dependent evolution of the Lightman-Eardley instability which can develop near the inner edge of an accretion disk when the radiation pressure becomes comparable to the gas pressure. Broadly speaking, our results are compatible with earlier works by Taam \& Lin and by Lasota \& Pelat. The uniqueness of GRO J1744-28 appears to be associated with the constraint that, in order for outbursts to occur, the rate of accretion at the inner edge must be within a narrow range just above the critical accretion rate at which radiation pressure is beginning to become significant.Comment: 11 pages in .tex file, 4 Postscript figures, .tex file uses aasms.sty; Ap. J. L. 1996, in pres

Modeling of Isotropic Backward-Wave Materials Composed of Resonant Spheres

A possibility to realize isotropic artificial backward-wave materials is theoretically analyzed. An improved mixing rule for the effective permittivity of a composite material consisting of two sets of resonant dielectric spheres in a homogeneous background is presented. The equations are validated using the Mie theory and numerical simulations. The effect of a statistical distribution of sphere sizes on the increasing of losses in the operating frequency band is discussed and some examples are shown.Comment: 15 pages, 7 figure