68 research outputs found
Berechnung der Aktivierungsenergien fĆ¼r die thermische cis-trans-Isomerisierung substituierter Stilbene, Stilbazole und Stilbazolium-Salze
Die Aktivierungsenergien der thermischen cis-trans-Isome- risierung substituierter Stilbene, Stilbazole und Stilbazolium-Salze werden mittels der HMO-Methode berechnet und mit den expe- rimentellen Werten verglichen. Die Ergebnisse werden im Zusam- menhang mit dem Mechanismus der thermischen cis-trans-Isomerisierung diskutiert
Dietrich Schulte-Frohlinde (1924 ā 2015)
Professor Dietrich Schulte-Frohlinde, a distinguished German chemist with long-time relationships to Croatian scientists (e.g. S. AÅ”perger, M. RandiÄ, J. N. Herak, A. Graovac, I. KraljiÄ), and this Journal, passed away on Oct 1st, 2015 in Chevy Chase MD, USA. He was born on Dec 17th, 1924 in Munich ...
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Foreword
This issue of Croatica Chemica Acta is dedicated to Chemical Kinetics
and Reaction Mechanisms on the occasion of the 80th birthday of Smiljko AŔperger
Atmosphere/soil exchange processes of importance for molecular soil sciences
Globally the atmosphere/soil exchange can be interpreted as part of the biogeochemical cycles describing the transport of main chemical elements and their gaseous compounds between the compartments of the geosphere. Approaches to monitor and analyze these transport processes are described. The paramount role of Earthās life, the biosphere, in these processes is emphasized
Snježana PauÅ”ek-Baždar: Hrvatski alkemiÄari tijekom stoljeÄa (Äitana recenzija na predstavljanju knjige, Zagreb, HAZU, 13. lipnja 2017.)
Snježana PauÅ”ek-Baždar: Hrvatski alkemiÄari tijekom stoljeÄa (Äitana recenzija na predstavljanju knjige, Zagreb, HAZU, 13. lipnja 2017.)
Photoelectron Spectroscopy of Some trans-2,2-Disubstituted Stilbenes
The He I photoelectron (PE) spectra of stilbene (1), 2,2\u27-dichlorostilbene
(2) 2-amino-2\u27-chlorostilbene (3), 2,2\u27-diaminostilbene
(4) ,and 2,2\u27-dinitrostilbene (5), all in their trans configuration are
recorded and discussed. The electronic structure of 1-5 can well
be described on the basis of the composite molecule method and
simple Hiickel molecular orbital (HMO) calculations. Results indicate
the importance of substituent effects causing characteristic
shifts of low energy electronic band systems in the PE spectra
Deuterium Labeling Study of the Gas-phase Reaction of Fe+/Cr+ with Pyrene by FTMS
A ~ 10 :1 mixture of deuterated with undeuterated pyrene was used to study the product composition in the reaction with various ratios of Fe+ and Cr+ (10 :1 to 1: 10) ions in a Fourier-transform mass spectrometer. None of the products FePy+, CrPy+, Py+, FePy2+, CrPy2+ and Py2+ showed deviation from the statistically expected composition
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