Longitudinal magnon in the tetrahedral spin system Cu2Te2O5Br2 near quantum criticality

We present a comprehensive study of the coupled tetrahedra-compound Cu2Te2O5Br2 by theory and experiments in external magnetic fields. We report the observation of a longitudinal magnon in Raman scattering in the ordered state close to quantum criticality. We show that the excited tetrahedral-singlet sets the energy scale for the magnetic ordering temperature T_N. This energy is determined experimentally. The ordering temperature T_N has an inverse-log dependence on the coupling parameters near quantum criticality

TiOCl, an orbital-ordered system?

We present first principles density functional calculations and downfolding studies of the electronic and magnetic properties of the layered quantum spin system TiOCl. We discuss explicitely the nature of the exchange pathes and attempt to clarify the concept of orbital ordering in this material. An analysis of the electronic structure of slightly distorted structures according to the phononic modes allowed in this material suggests that this system is subject to large orbital fluctuations driven by the electron-phonon coupling. Based on these results, we propose a microscopic explanation of the behavior of TiOCl near the phase transition to a spin-gapped system.Comment: Some figures are compressed, for higher quality please contact the author

Bulk antiferromagnetism in Na0.82CoO2\bf Na_{0.82}CoO_2 single crystals

Susceptibility, specific heat, and muon spin rotation measurements on high-quality single crystals of $\rm Na_{0.82}CoO_2$ have revealed bulk antiferromagnetism with N\'{e}el temperature $\rm T_N = 19.8 \pm 0.1$ K and an ordered moment perpendicular to the $\rm CoO_2$ layers. The magnetic order encompasses nearly 100% of the crystal volume. The susceptibility exhibits a broad peak around 30 K, characteristic of two-dimensional antiferromagnetic fluctuations. The in-plane resistivity is metallic at high temperatures and exhibits a minimum at $\rm T_N$.Comment: published versio

Low-Lying Magnetic Excitation of the Shastry-Sutherland Model

By using perturbation calculation and numerical diagonalization, low-energy spin dynamics of the Shastry-Sutherland model is investigated paying particular attention to the two-particle coherent motion. In addition to spin-singlet- and triplet bound states, we find novel branches of coherent motion of a bound quintet pair, which are usually unstable because of repulsion. Unusual dispersion observed in neutron-scattering measurements are explained by the present theory. The importance of the effects of phonon is also pointed out.Comment: 4 pages, 6 figures combined into 1 PSfile. Final version to appear in Phys.Rev.Lett. (Jan. 2000

Anomalous electronic Raman scattering in Na_xCoO_2 H_2O

Raman scattering experiments on Na_{x}CoO_2 yH_2O single crystals show a broad electronic continuum with a pronounced peak around 100 cm-1 and a cutoff at approximately 560 cm-1over a wide range of doping levels. The electronic Raman spectra in superconducting and non-superconducting samples are similar at room temperature, but evolve in markedly different ways with decreasing temperature. For superconducting samples, the low-energy spectral weight is depleted upon cooling below T* sim 150K, indicating a opening of a pseudogap that is not present in non-superconducting materials. Weak additional phonon modes observed below T* suggest that the pseudogap is associated with charge ordering.Comment: 5 pages, 4 figures, for further information see www.peter-lemmens.d

Comparative investigation of the coupled-tetrahedra quantum spin systems Cu2Te2O5X2, X=Cl, Br and Cu4Te5O12Cl4

We present a comparative study of the coupled-tetrahedra quantum spin systems Cu2Te2O5X2, X=Cl, Br (Cu-2252(X)) and the newly synthesized Cu4Te5O12Cl4 (Cu-45124(Cl)) based on ab initio Density Functional Theory calculations. The magnetic behavior of Cu-45124(Cl) with a phase transition to an ordered state at a lower critical temperature T$_c$=13.6K than in Cu-2252(Cl) (T$_c$=18K) can be well understood in terms of the modified interaction paths. We identify the relevant structural changes between the two systems and discuss the hypothetical behavior of the not yet synthesized Cu-45124(Br) with an ab initio relaxed structure using Car-Parrinello Molecular Dynamics.Comment: 2 pages, 1 figure; submitted to Proceedings of M2S-HTSC VIII, Dresden 200

Momentum distribution of confined bosons: temperature dependence

The momentum distribution function of a parabolically confined gas of bosons with harmonic interparticle interactions is derived. In the Bose-Einstein condensation region, this momentum distribution substantially deviates from a Maxwell-Boltzmann distribution. It is argued that the determination of the temperature of the boson gas from the Bose-Einstein momentum distribution function is more appropriate than the currently used fitting to the high momentum tail of the Maxwell-Boltzmann distribution.Comment: 5 REVTEX pages + 2 postscript figures. Accepted in Phys. Rev.

Optical phonons, spin correlations, and spin-phonon coupling in the frustrated pyrochlore magnets CdCr2O4 and ZnCr2O4

We report on infrared, Raman, magnetic susceptibility, and specific heat measurements on CdCr2O4 and ZnCr2O4 single crystals. We estimate the nearest-neighbor and next-nearest neighbor exchange constants from the magnetic susceptibility and extract the spin-spin correlation functions obtained from the magnetic susceptibility and the magnetic contribution to the specific heat. By comparing with the frequency shift of the infrared optical phonons above TN , we derive estimates for the spin-phonon coupling constants in these systems. The observation of phonon modes which are both Raman and infrared active suggest the loss of inversion symmetry below the Neel temperature in CdCr2O4 in agreement with theoretical predictions by Chern and coworkers [Phys. Rev. B 74, 060405 (2006)]. In ZnCr2O4 several new modes appear below TN, but no phonon modes could be detected which are both Raman and infrared active indicating the conservation of inversion symmetry in the low temperature phase.Comment: 11 pages, 13 figure

Magnetism of a tetrahedral cluster spin-chain

We discuss the magnetic properties of a dimerized and completely frustrated tetrahedral spin-1/2 chain. Using a combination of exact diagonalization and bond-operator theory the quantum phase diagram is shown to incorporate a singlet-product, a dimer, and a Haldane phase. In addition we consider one-, and two-triplet excitations in the dimer phase and evaluate the magnetic Raman cross section which is found to be strongly renormalized by the presence of a two-triplet bound state. The link to a novel tellurate materials is clarified.Comment: 8 pages, 8 figure

The Pairing Mechanism in HTSC investigated by Electronic Raman Scattering

By means of electronic Raman scattering we investigated the symmetry of the energy gap Delta(k), its temperature dependence and its variation with doping of well characterized Bi2Sr2CaCu2O8+delta single crystals. The oxygen content delta was varied between the under- and the overdoped regime by subsequently annealing the same single crystal in Ar and O2, respectively. The symmetry analysis of the polarized electronic Raman scattering is consistent with a d_x^2-y^2-wave symmetry of the energy gap in both regimes. The gap ratio 2Delta_max/k_BT_c and its temperature dependence changes with doping similar to predictions of theories based on paramagnon coupling.Comment: 3 pages, LaTeX, 2 ps figures available on request to [email protected]