8 research outputs found
Superconductivity in SrFe_(2-x)Co_xAs_2: Internal Doping of the Iron Arsenide Layers
In the electron doped compounds SrFe_(2-x)Co_xAs_2 superconductivity with T_c
up to 20 K is observed for 0.2 < x < 0.4. Results of structure determination,
magnetic susceptibility, electrical resistivity, and specific heat are
reported. The observation of bulk superconductivity in all thermodynamic
properties -- despite strong disorder in the Fe-As layer -- favors an itinerant
picture in contrast to the cuprates and renders a p- or d-wave scenario
unlikely. DFT calculations find that the substitution of Fe by Co (x > 0.3)
leads to the suppression of the magnetic ordering present in SrFe_2As_2 due to
a rigid down-shift of the Fe-3d_(x^2-y^2) related band edge in the density of
states.Comment: 5 pages, 3 figure
Pressure effects on the electron-doped high Tc superconductor BaFe(2-x)Co(x)As(2)
Application of pressures or electron-doping through Co substitution into Fe
sites transforms the itinerant antiferromagnet BaFe(2)As(2) into a
superconductor with the Tc exceeding 20K. We carried out systematic transport
measurements of BaFe(2-x)Co(x)As(2) superconductors in pressures up to 2.5GPa,
and elucidate the interplay between the effects of electron-doping and
pressures. For the underdoped sample with nominal composition x = 0.08,
application of pressure strongly suppresses a magnetic instability while
enhancing Tc by nearly a factor of two from 11K to 21K. In contrast, the
optimally doped x=0.20 sample shows very little enhancement of Tc=22K under
applied pressure. Our results strongly suggest that the proximity to a magnetic
instability is the key to the mechanism of superconductivity in iron-pnictides.Comment: 5 figure
Superconductivity induced by Ni doping in BaFeAs
A series of 122 phase BaFeNiAs ( = 0, 0.055, 0.096, 0.18,
0.23) single crystals were grown by self flux method and a dome-like Ni doping
dependence of superconducting transition temperature is discovered. The
transition temperature reaches a maximum of 20.5 K at = 0.096,
and it drops to below 4 K as 0.23. The negative thermopower in the
normal state indicates that electron-like charge carrier indeed dominates in
this system. This Ni-doped system provides another example of superconductivity
induced by electron doping in the 122 phase.Comment: 7 pages, 5 figures, revised version, added EDX result, accepted for
special issue of NJ
Growth and characterization of A_{1-x}K_xFe_2As_2 (A = Ba, Sr) single crystals with x=0 - 0.4
Single crystals of AKFeAs (A=Ba, Sr) with high quality
have been grown successfully by FeAs self-flux method. The samples have sizes
up to 4 mm with flat and shiny surfaces. The X-ray diffraction patterns suggest
that they have high crystalline quality and c-axis orientation. The
non-superconducting crystals show a spin-density-wave (SDW) instability at
about 173 K and 135 K for Sr-based and Ba-based compound, respectively. After
doping K as the hole dopant into the BaFeAs system, the SDW transition
is smeared, and superconducting samples with the compound of
BaKFeAs (0 0.4) are obtained. The
superconductors characterized by AC susceptibility and resistivity measurements
exhibit very sharp superconducting transition at about 36 K, 32 K, 27 K and 23
K for x= 0.40,0.28,0.25 and 0.23, respectively.Comment: 9 pages, 6 figures, 1 table. This paper together with new data are
modified into a new pape
Superconductivity in Co-doped SmFeAsO
Here we report the synthesis and basic characterization of SmFe1-xCoxAsO
(x=0.10, 0.15). The parent compound SmFeAsO itself is not superconducting but
shows an antiferromagnetic order near 150 K, which must be suppressed by doping
before superconductivity emerges. With Co-doping in the FeAs planes,
antiferromagnetic order is destroyed and superconductivity occurs at 15 K.
Similar to LaFe1-xCoxAsO, the SmFe1-xCoxAsO system appears to tolerate
considerable disorder in the FeAs planes. This result is important, which
indicates difference between cuprare superconductors and the iron-based
arsenide ones.Comment: 11 pages, 3 figure
AFe2As2 (A = Ca, Sr, Ba, Eu) and SrFe_(2-x)TM_(x)As2 (TM = Mn, Co, Ni): crystal structure, charge doping, magnetism and superconductivity
The electronic structure and physical properties of the pnictide compound
families OFeAs ( = La, Ce, Pr, Nd, Sm), FeAs ( = Ca,
Sr, Ba, Eu), LiFeAs and FeSe are quite similar. Here, we focus on the members
of the FeAs family whose sample composition, quality and single
crystal growth are better controllable compared to the other systems. Using
first principles band structure calculations we focus on understanding the
relationship between the crystal structure, charge doping and magnetism in
FeAs systems. We will elaborate on the tetragonal to
orthorhombic structural distortion along with the associated magnetic order and
anisotropy, influence of doping on the site as well as on the Fe site, and
the changes in the electronic structure as a function of pressure.
Experimentally, we investigate the substitution of Fe in
SrFeAs by other 3 transition metals, = Mn, Co, Ni.
In contrast to a partial substitution of Fe by Co or Ni (electron doping) a
corresponding Mn partial substitution does not lead to the supression of the
antiferromagnetic order or the appearance of superconductivity. Most calculated
properties agree well with the measured properties, but several of them are
sensitive to the As position. For a microscopic understanding of the
electronic structure of this new family of superconductors this structural
feature related to the Fe-As interplay is crucial, but its correct ab initio
treatment still remains an open question.Comment: 27 pages, single colum