106 research outputs found
Thermoelastic study of nanolayered structures using time-resolved x-ray diffraction at high repetition rate
We investigate the thermoelastic response of a nanolayered sample composed of
a metallic SrRuO3 (SRO) electrode sandwiched between a ferroelectric
Pb(Zr0.2Ti0.8)O3 (PZT) film with negative thermal expansion and a SrTiO3
substrate. SRO is rapidly heated by fs-laser pulses with 208 kHz repetition
rate. Diffraction of x-ray pulses derived from a synchrotron measures the
transient out-of-plane lattice constant c of all three materials simultaneously
from 120 ps to 5 mus with a relative accuracy up to Delta c/c = 10^-6. The
in-plane propagation of sound is essential for understanding the delayed out of
plane expansion.Comment: 5 pages, 3 figure
Simultaneous dynamic characterization of charge and structural motion during ferroelectric switching
Monitoring structural changes in ferroelectric thin films during electric
field-induced polarization switching is important for a full microscopic
understanding of the coupled motion of charges, atoms and domain walls. We
combine standard ferroelectric test-cycles with time-resolved x-ray diffraction
to investigate the response of a nanoscale ferroelectric oxide capacitor upon
charging, discharging and switching. Piezoelectric strain develops during the
electronic RC time constant and additionally during structural domain-wall
creep. The complex atomic motion during ferroelectric polarization reversal
starts with a negative piezoelectric response to the charge flow triggered by
voltage pulses. Incomplete screening limits the compressive strain. The
piezoelectric modulation of the unit cell tweaks the energy barrier between the
two polarization states. Domain wall motion is evidenced by a broadening of the
in-plane components of Bragg reflections. Such simultaneous measurements on a
working device elucidate and visualize the complex interplay of charge flow and
structural motion and challenges theoretical modelling
Hybrid simulations of lateral diffusion in fluctuating membranes
In this paper we introduce a novel method to simulate lateral diffusion of
inclusions in a fluctuating membrane. The regarded systems are governed by two
dynamic processes: the height fluctuations of the membrane and the diffusion of
the inclusion along the membrane. While membrane fluctuations can be expressed
in terms of a dynamic equation which follows from the Helfrich Hamiltonian, the
dynamics of the diffusing particle is described by a Langevin or Smoluchowski
equation. In the latter equations, the curvature of the surface needs to be
accounted for, which makes particle diffusion a function of membrane
fluctuations. In our scheme these coupled dynamic equations, the membrane
equation and the Langevin equation for the particle, are numerically integrated
to simulate diffusion in a membrane. The simulations are used to study the
ratio of the diffusion coefficient projected on a flat plane and the
intramembrane diffusion coefficient for the case of free diffusion. We compare
our results with recent analytical results that employ a preaveraging
approximation and analyze the validity of this approximation. A detailed
simulation study of the relevant correlation functions reveals a surprisingly
large range where the approximation is applicable.Comment: 12 pages, 9 figures, accepted for publication in Phys. Rev.
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Reciprocal space slicing: A time-efficient approach to femtosecond x-ray diffraction
An experimental technique that allows faster assessment of out-of-plane strain dynamics of thin film heterostructures via x-ray diffraction is presented. In contrast to conventional high-speed reciprocal space-mapping setups, our approach reduces the measurement time drastically due to a fixed measurement geometry with a position-sensitive detector. This means that neither the incident (ω) nor the exit ( 2θ ) diffraction angle is scanned during the strain assessment via x-ray diffraction. Shifts of diffraction peaks on the fixed x-ray area detector originate from an out-of-plane strain within the sample. Quantitative strain assessment requires the determination of a factor relating the observed shift to the change in the reciprocal lattice vector. The factor depends only on the widths of the peak along certain directions in reciprocal space, the diffraction angle of the studied reflection, and the resolution of the instrumental setup. We provide a full theoretical explanation and exemplify the concept with picosecond strain dynamics of a thin layer of NbO2
Observation of sagittal X ray diffraction by surface acoustic waves in Bragg geometry
X-ray Bragg diffraction in sagittal geometry on a Y-cut langasite crystal (La(3)Ga(5)SiO(14)) modulated by Λ = 3 µm Rayleigh surface acoustic waves was studied at the BESSY II synchrotron radiation facility. Owing to the crystal lattice modulation by the surface acoustic wave diffraction, satellites appear. Their intensity and angular separation depend on the amplitude and wavelength of the ultrasonic superlattice. Experimental results are compared with the corresponding theoretical model that exploits the kinematical diffraction theory. This experiment shows that the propagation of the surface acoustic waves creates a dynamical diffraction grating on the crystal surface, and this can be used for space–time modulation of an X-ray beam
Principles for developing and adapting clinical practice guidelines and guidance for pandemics, wars, shortages, and other crises and emergencies: the PAGE criteria
Development of international clinical practice guidelines: benefits, limitations, and alternative forms of international collaboration
PERSPECTIVAS DEL PROCESO DE GLOBALIZACIÓN Y SU INFLUENCIA SOBRE LOS DERECHOS HUMANOS ECONÓMICOS, SOCIALES Y CULTURALES
El escenario internacional se encuentra en constante transformación debido a lo que se ha denominado el proceso de “globalización”. Este afecta las relaciones internaciones interestatales e influye en la vida cotidiana de los individuos. El Derecho Internacional y más específicamente el Derecho Internacional de los Derechos Humanos no es ajeno a este proceso. La investigación afirma que nos encontramos frente a una etapa de transnacionalización de los Derechos Humanos, que permite que los individuos cuenten con mayor protección en ámbitos supranacionales. También hace especial mención a los derechos Económicos Sociales y Culturales, analiza el debate sobre el pluralismo jurídico y la eficacia diferencial. En la metodología empleada se revisan fuentes documentales y se realiza un análisis de algunos derechos particulares previstos en el Pacto de Derechos Económicos, Sociales y Culturales. Los planteamientos permiten afirmar que el proceso de globalización ha determinado la transnacionalización de los Derechos Humanos, surgiendo de dicho fenómeno consecuencias positivas y negativas en cuanto a su cumplimiento
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