2 research outputs found
Metal–Organic Framework Based on Isonicotinate <i>N</i>‑Oxide for Fast and Highly Efficient Aqueous Phase Cr(VI) Adsorption
Synthesis
of new porous materials has been developed for efficient capture of
pollutants in environmental sciences. Here, the application of a new
metal–organic framework (TMU-30) has been reported based on
isonicotinate <i>N</i>-oxide as an adsorptive site for fast
and highly efficient aqueous phase adsorption of CrÂ(VI). The adsorption
process showed no remarkable effect over a pH range of 2–9.
The maximum capacity of the adsorption was reached in just less than
10 min and followed the pseudo-second-order kinetics. The maximum
capacity of 2.86 mol mol<sup>–1</sup> (145 mg/g) was obtained
according to Langmuir model at 298 K. The spontaneous adsorption and
an endothermic process were controlled by positive entropy changes.
XPS analysis revealed electrostatic interactions between <i>N</i>-oxide groups of TMU-30 and CrÂ(VI) species, which were responsible
for the adsorption process
Metal–Organic Framework Based on Isonicotinate <i>N</i>‑Oxide for Fast and Highly Efficient Aqueous Phase Cr(VI) Adsorption
Synthesis
of new porous materials has been developed for efficient capture of
pollutants in environmental sciences. Here, the application of a new
metal–organic framework (TMU-30) has been reported based on
isonicotinate <i>N</i>-oxide as an adsorptive site for fast
and highly efficient aqueous phase adsorption of CrÂ(VI). The adsorption
process showed no remarkable effect over a pH range of 2–9.
The maximum capacity of the adsorption was reached in just less than
10 min and followed the pseudo-second-order kinetics. The maximum
capacity of 2.86 mol mol<sup>–1</sup> (145 mg/g) was obtained
according to Langmuir model at 298 K. The spontaneous adsorption and
an endothermic process were controlled by positive entropy changes.
XPS analysis revealed electrostatic interactions between <i>N</i>-oxide groups of TMU-30 and CrÂ(VI) species, which were responsible
for the adsorption process