155 research outputs found
Bearing capacity degradation curves of JL-2–JL-4.
<p>Bearing capacity degradation curves of JL-2–JL-4.</p
Experimental stiffness results (<i>MN</i> â‹… <i>m</i><sup>2</sup>).
<p>Experimental stiffness results (<i>MN</i> â‹… <i>m</i><sup>2</sup>).</p
Quantum Mode Selectivity of Plasmon-Induced Water Splitting on Gold Nanoparticles
Plasmon induced water splitting is
a promising research area with
the potential for efficient conversion of solar to chemical energy,
yet its atomic mechanism is not well understood. Here, ultrafast electron–nuclear
dynamics of water splitting on gold nanoparticles upon exposure to
femtosecond laser pulses was directly simulated using real time time-dependent
density functional theory (TDDFT). Strong correlation between laser
intensity, hot electron transfer, and reaction rates has been identified.
The rate of water splitting is dependent not only on respective optical
absorption strength, but also on the quantum oscillation mode of plasmonic
excitation. Odd modes are more efficient than even modes, owing to
faster decaying into hot electrons whose energy matches well the antibonding
orbital of water. This finding suggests photocatalytic activity can
be manipulated by adjusting the energy level of plasmon-induced hot
carriers, through altering the cluster size and laser parameter, to
better overlap adsorbate unoccupied level in plasmon-assisted photochemistry
Load–deflection curve after 50000 cycles.
<p>Load–deflection curve after 50000 cycles.</p
Relative bearing capacity degradation curve of JL-4 beam.
<p>Relative bearing capacity degradation curve of JL-4 beam.</p
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