Synergistic multi-doping effects on the Li7La3Zr2O12 solid electrolyte for fast lithium ion conduction.

Here, we investigate the doping effects on the lithium ion transport behavior in garnet Li7La3Zr2O12 (LLZO) from the combined experimental and theoretical approach. The concentration of Li ion vacancy generated by the inclusion of aliovalent dopants such as Al(3+) plays a key role in stabilizing the cubic LLZO. However, it is found that the site preference of Al in 24d position hinders the three dimensionally connected Li ion movement when heavily doped according to the structural refinement and the DFT calculations. In this report, we demonstrate that the multi-doping using additional Ta dopants into the Al-doped LLZO shifts the most energetically favorable sites of Al in the crystal structure from 24d to 96 h Li site, thereby providing more open space for Li ion transport. As a result of these synergistic effects, the multi-doped LLZO shows about three times higher ionic conductivity of 6.14 × 10(-4) S cm(-1) than that of the singly-doped LLZO with a much less efforts in stabilizing cubic phases in the synthetic condition

Chemodynamical Analysis of Metal-rich High-eccentricity Stars in the Milky Way's Disk

We present a chemodynamical analysis of 11,562 metal-rich, high-eccentricity halo-like main-sequence (MS) stars, which has been referred to as the Splash or Splashed Disk, selected from Sloan Digital Sky Survey (SDSS) and Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST). When divided into two groups, a low-[$\alpha$/Fe] population (LAP) and a high-[$\alpha$/Fe] population (HAP), based on kinematics and chemistry, we find that they exhibit very distinct properties, indicative of different origins. From a detailed analysis of their orbital inclinations, we suggest that the HAP arises from a large fraction (~ 90%) of heated disk stars and a small fraction (~ 10%) of in situ stars from a starburst population, likely induced by interaction of the Milky Way with Gaia Sausage/Enceladus (GSE) or other early merger. The LAP comprises about half accreted stars from the GSE and half formed by the GSE-induced starburst. Our findings further imply that the Splash stars in our sample originated from at least three different mechanisms - accretion, disk heating, and a merger induced starburst

Effect of Long-Term Dietary Arginyl-Fructose (AF) on Hyperglycemia and HbA1c in Diabetic db/db Mice

We have previously reported that Amadori compounds exert anti-diabetic effects by lowering sucrose-induced hyperglycemia in normal Sprague-Dawley rats. In the present study we extended our recent findings to evaluate whether α-glucosidase inhibitor arginyl-fructose (AF) lowers blood glucose level in diabetic db/db mice, a genetic model for type 2 diabetes. The db/db mice were randomly assigned to high-carbohydrate diets (66.1% corn starch) with and without AF (4% in the diet) for 6 weeks. Changes in body weight, blood glucose level, and food intake were measured daily for 42 days. Dietary supplementation of AF resulted in a significant decrease of blood glucose level (p \u3c 0.001) and body weight (p \u3c 0.001). The level of HbA1c, a better indicator of plasma glucose concentration over prolonged periods of time, was also significantly decreased for 6-week period (p \u3c 0.001). Dietary treatment of acarbose® (0.04% in diet), a positive control, also significantly alleviated the level of blood glucose, HbA1c, and body weight. These results indicate that AF Maillard reaction product improves postprandial hyperglycemia by suppressing glucose absorption as well as decreasing HbA1c level