168 research outputs found
Characterization and biological studies of organotin (IV) complexes with tris[hydroxymethyl)aminomethane] ligands
Dichlorido{μ3-6,6′-diethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}octamethyldi-μ3-oxido-tetratin(IV)
In the title tetranuclear tin(IV) complex, [Sn4(CH3)8(C20H22N2O4)Cl2O2], there are three completely different tin-atom coordinations. One metal atom (site symmetry 2) adopts a distorted pentagonal-bipyramidal SnC2N2O3 coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, two methyl groups in the axial sites and a μ3-O atom that also bonds to two further Sn atoms. Two symmetry-equivalent Sn atoms adopt very distorted SnC2O4 arrangements that could be described as pentagonal-bipyramidal with one equatorial vertex missing and the C atoms in the axial site. The final Sn atom (site symmetry 2) adopts an SnC2Cl2O trigonal-bipyramidal arrangement, with Cl atoms in the axial sites. As well as the two Sn atoms, one O atom lies on a twofold rotation rotation axis, and another is disordered about the axis. The terminal ethoxy group is disordered over two sets of sites with equal occupancy
Crystal structure of chlorido-diphenyl-(isopropyl(propyl)carbamodithioato-κ2S,S′)tin(IV), C19H24ClNS2Sn
Crystal structure of octa(4-chlorobenzyl)-dichlorido-bis(μ2-methanolato)-bis(μ3-oxo)-tetratin(IV), C58H54Cl10O4Sn4
Crystal structure of catena-poly[dibenzyl-dichlorido-(μ2-[4,4′-bipyridine]1,1′-dioxide-κ2O:O′)tin(IV)], C24H22Cl2N2O2Sn
Low temperature redetermination of the crystal structure of catena-poly[[tri-4-fluorobenzyltin(IV)]μ2-pyridine-4-carboxylato-κ2N:O], {C27H22F3NO2Sn}n
Crystal structure of bis(ammonium) diaqua-tetrakis(4-hydroxybenzoato)-manganese(II) tetrahydrate, [NH4]2[C28H24MnO14] ⋅ 4(H2O)
Crystal structure of (dimethyl sulfoxide)-dioxido-[2-hydroxy-N′-(4-oxo-4-phenylbutan-2-ylidene)benzohydrazidato κ3N,O,O′]molybdenum(VI), C19H20MoN2O6S
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