26 research outputs found
Stereochemistry of seven-membered heterocycles. 2. IR spectra, dipole moments, and inductive effect of the alkyl groups in 2-alkylbenz[e]-1,3-dioxepanes
Effect of Different PCI Practice on the Texture Obtained during Reduction of Iron Oxide Pellets
Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes
(xylyl-phanephos)Pt(2+) in combination with XeF(2) mediates the consecutive diastereoselective cation-olefin cyclization/fluorination of polyene substrates. Isolated yields were typically in the 60s while enantioselectivies reached as high as 87%. The data are consistent with a stereoretentive fluorination of a P(2)Pt-alkyl cation intermediate
