6,153 research outputs found

    An experimental and theoretical study of Ni impurity centers in Ba0.8_{0.8}Sr0.2_{0.2}TiO3_3

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    The local environment and the charge state of a nickel impurity in cubic Ba0.8_{0.8}Sr0.2_{0.2}TiO3_3 are studied by XAFS spectroscopy. According to the XANES data, the mean Ni charge state is \sim2.5+. An analysis of the EXAFS spectra and their comparison with the results of first-principle calculations of the defect geometry suggest that Ni2+^{2+} ions are in a high-spin state at the BB sites of the perovskite structure and the difference of the Ni2+^{2+} and Ti4+^{4+} charges is mainly compensated by distant oxygen vacancies. In addition, a considerable amount of nickel in the sample is in a second phase BaNiO3δ_{3-\delta}. The measurements of the lattice parameter show a decrease in the unit cell volume upon doping, which can indicate the existence of a small amount of Ni4+^{4+} ions at the BB sites.Comment: 8 pages, 3 figures, 3 table

    When a C*-algebra is a coefficient algebra for a given endomorphism

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    The paper presents a criterion for a C*-algebra to be a coefficient algebra associated with a given endomorphis

    Shape transformations in rotating ferrofluid drops

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    Floating drops of magnetic fluid can be brought into rotation by applying a rotating magnetic field. We report theoretical and experimental results on the transition from a spheroid equilibrium shape to non-axissymmetrical three-axes ellipsoids at certain values of the external field strength. The transitions are continuous for small values of the magnetic susceptibility and show hysteresis for larger ones. In the non-axissymmetric shape the rotational motion of the drop consists of a vortical flow inside the drop combined with a slow rotation of the shape. Nonlinear magnetization laws are crucial to obtain quantitative agreement between theory and experiment.Comment: 4 pages, 3 figure

    The effect of electron surface scattering on fine metal particle electromagnetic radiation absorption

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    The magnetic dipole absorption cross section of a spherically shaped metal particle was calculated in terms of kinetic approach. The particle considered was placed in the field of a plane electromagnetic wave. The model of boundary conditions was investigated taking into account the dependence of the reflectivity coefficient both on the surface roughness parameter and on the electron incidence angle. The results obtained were compared with theoretical computation results for a model of combined diffusion-specular boundary conditions of Fuchs.Comment: 9 pages, 5 figure
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