Visible-light promoted atom transfer radical addition-elimination (ATRE) reaction for the synthesis of fluoroalkylated alkenes using DMA as electron-donor

Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor-acceptor (EDA) complex between DMA and fluoroalkyl iodides. The significant advantages of this photochemical transformation are high efficiency, excellent functional group tolerance, and synthetic simplicity, thus providing a facile route for further application in pharmaceuticals and life sciences

Parametric cooling of a degenerate Fermi gas in an optical trap

We demonstrate a novel technique for cooling a degenerate Fermi gas in a crossed-beam optical dipole trap, where high-energy atoms can be selectively removed from the trap by modulating the stiffness of the trapping potential with anharmonic trapping frequencies. We measure the dependence of the cooling effect on the frequency and amplitude of the parametric modulations. It is found that the large anharmonicity along the axial trapping potential allows to generate a degenerate Fermi gas with anisotropic energy distribution, in which the cloud energy in the axial direction can be reduced to the ground state value