1 research outputs found
Nonlinear Optical Thin Film Device from a Chiral Octopolar Phenylacetylene Liquid Crystal
A set of chiral discotic phenylacetylenes have been synthesized
by 3-fold Sonogashira coupling between different ethynylbenzenes and
triiodobenzenes. The resultant bulk materials are fully characterized
by polarized optical microscopy (POM), differential scanning calorimetry
(DSC), and X-ray diffraction. The octopolar nature of the target compounds
is studied by UVāvis absorption spectroscopy and hyper-Raleigh
scattering in solution. Optimization of the donorāacceptor
substitution yields both high hyperpolarizability values and appreciable
mesomorphic properties. A simple thin film device for second harmonic
generation has been prepared from the nitro-substituted liquid crystalline
derivative