The 42nd Symposium Chromatographic Methods of Investigating Organic Compounds : Book of abstracts

The 42nd Symposium Chromatographic Methods of Investigating Organic Compounds : Book of abstracts. June 4-7, 2019, Szczyrk, Polan

Odour emission from primary settling tanks after air-tightening

The purpose of the present article was to determine odour emission rate from primary settling tanks after hermetisation. The paper presents the results of the research on odour emission from four settling tanks, covered with self-supporting aluminium domes with a diameter of 52 meters, located on urban wastewater treatment plants, with the planned flow capacity equal to 200 000 m3/day. Altogether, the olfactometry analysis of 189 samples of polluted air pulled from the domes with the use of an air blower which has efficiency of 12 000 m3/h was conducted. The results of odour concentration measurements were in a range of approximately 10 800 to 763 600 ouE/m3. Average odour emission rate was equal to 102 ouE/(s · m2). The obtained value is much higher than the literature data, available for non-hermetised settlers only. This rate enables better estimation of the odour stream that has to be deodorised after sealing the settling tanks

Odour emission from primary settling tanks after air-tightening

The purpose of the present article was to determine odour emission rate from primary settling tanks after hermetisation. The paper presents the results of the research on odour emission from four settling tanks, covered with self-supporting aluminium domes with a diameter of 52 meters, located on urban wastewater treatment plants, with the planned flow capacity equal to 200 000 m3/day. Altogether, the olfactometry analysis of 189 samples of polluted air pulled from the domes with the use of an air blower which has efficiency of 12 000 m3/h was conducted. The results of odour concentration measurements were in a range of approximately 10 800 to 763 600 ouE/m3. Average odour emission rate was equal to 102 ouE/(s · m2). The obtained value is much higher than the literature data, available for non-hermetised settlers only. This rate enables better estimation of the odour stream that has to be deodorised after sealing the settling tanks

CO₂ Sorbents Based on Spherical Carbon and Photoactive Metal Oxides: Insight into Adsorption Capacity, Selectivity and Regenerability

This work aimed to obtain hybrid composites based on photoactive metal oxide and carbon having adsorption properties. The materials, composed of titanium dioxide or zinc oxide and spherical carbon, were obtained from resorcinol-formaldehyde resin, treated in a solvothermal reactor heated with microwaves and then subjected to carbonization, were received. The functional groups of pure carbon spheres (unsaturated stretching C=C, stretching C−OH and C−H bending vibrations), CS/ZnO and CS/TiO2 samples were determined by FT-IR analysis. The characteristic bands for ZnO and TiO2 were observed below 1000 cm−1. The thermal oxidative properties are similar for TiO2- and ZnO-modified carbon spheres. We have observed that the increased carbon sphere content in nanocomposites results in starting the decomposition process at a lower temperature, therefore, nanocomposites have a broader combustion temperature range. The effect of the oxides’ addition to carbon spheres on their adsorption properties was evaluated in detail by examining CO2 adsorption from the gas phase. The selectivity of CO2 over N2 at a temperature of 25 °C and pressure of 1 bar (a novelty in testing CS-based sorbents) calculated for 3.00 CS/TiO2 and 4.00 CS/ZnO was 15.09 and 16.95, respectively. These nanocomposites exhibit excellent cyclic stability checked over 10 consecutive adsorption–desorption cycles