Simultaneous spectrophotometric determination of chromium(VI) and iron (III) by H-point standard addition method

In this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagent (diphenylcarbazide and 1,10-phenanthroline) is studied. We have applied Н-point standard addition method to determine concentrations of chromium (VI) and iron (III) from the mixture. The pure signals of complexes of chromium (VI) with diphenylcarbazide and iron (III) with the 1,10-phenanthroline and their calibration plots are previously carried out. We established the possibility of simultaneous determination of chromium (VI) and iron (III) in the different concentration ranges by Н-point standard addition method. Correctness of determination of concentration by means of the offered technique is proved by "added-found" method for a series of mixtures with different ratios of concentration of chromium (VI) and iron (III). It is founded that the error of determination of concentration doesn't exceed 33 %.

Analysis of negative magnetoresistance. Statistics of closed paths. I. Theory

Statistics of closed paths in two-dimensional (2D) systems, which just determines the interference quantum correction to conductivity and anomalous magnetoconductance, has been studied by computer simulation of a particle motion over the plane with randomly distributed scatterers. Both ballistic and diffusion regimes have been considered. The results of simulation have been analyzed in the framework of diffusion approximation. They are used for calculation of the magnetic field dependence of magnetoconductance in the model 2D system. It is shown that the anomalous magnetoconductance can be in principle described by the well known expression, obtained in the diffusion approximation, but with the prefactor less than unity and phase breaking length which differs from true value.Comment: 10 pages, 12 figures, to be published in Phys.Rev.

The Outburst of the Blazar AO 0235+164 in 2006 December: Shock-in-Jet Interpretation

We present the results of polarimetric ($R$ band) and multicolor photometric ($BVRIJHK$) observations of the blazar AO 0235+16 during an outburst in 2006 December. The data reveal a short timescale of variability (several hours), which increases from optical to near-IR wavelengths; even shorter variations are detected in polarization. The flux density correlates with the degree of polarization, and at maximum degree of polarization the electric vector tends to align with the parsec-scale jet direction. We find that a variable component with a steady power-law spectral energy distribution and very high optical polarization (30-50%) is responsible for the variability. We interpret these properties of the blazar withina model of a transverse shock propagating down the jet. In this case a small change in the viewing angle of the jet, by $\lesssim 1^o$, and a decrease in the shocked plasma compression by a factor of $\sim$1.5 are sufficient to account for the variability.Comment: 22 pages, 8 figures, accepted for Ap