Efficient hybrid solar cells based on solution processed mesoporous TiO2 / Tin (II) sulfide heterojunctions

Tin monosulfide (SnS) is emerging as a promising absorber material for the development of low-cost, solution-processable solar cells. Herein, we present a straightforward, solution-based route for the preparation of tin monosulfide (SnS) films employing a green solvent, namely, tetrahydrofuran (THF). We show that the surface coverage and the morphology of the SnS films can be tuned by modification of the precursor solution composition and film deposition conditions. Furthermore, we explore the effect of a PEDOT:PSS interlayer and fabricate solar cells based on the following architecture: FTO/planar-TiO2/mesoporous-TiO2/SnS/P3HT/PEDOT:PSS/Ag. Devices based on this architecture are shown to exhibit power conversion efficiencies (PCEs) of 3.0%, thus demonstrating the potential of our method for the development of low-cost and environmentally friendly solar cells

HI Fluctuations at Large Redshifts: II - the Signal Expected for GMRT

For the GMRT, we calculate the expected signal from redshifted HI emission at two frequency bands centered at 610 and 325 MHz. The study focuses on the visibility-visibility cross-correlations, proposed earlier as the optimal statistical estimator for detecting and analyzing this signal. These correlations directly probe the power spectrum of density fluctuations at the redshift where the radiation originated, and thereby provide a method for studying the large scale structures at large redshifts. We present detailed estimates of the correlations expected between the visibilities measured at different baselines and frequencies. Analytic fitting formulas representing the salient features of the expected signal are also provided. These will be useful in planning observations and deciding an optimal strategy for detecting this signal.Comment: 16 pages including 7 figures, published in JAp

New Improved Photometric Redshifts of Galaxies in the HDF

We report new improved photometric redshifts of 1048 galaxies in the Hubble Deep Field (HDF). A standard chi^2 minimizing method is applied to seven-color UBVIJHK photometry by Fernandez-Soto, Lanzetta, & Yahil (1999). We use 187 template SEDs representing a wide variety of morphology and age of observed galaxies based on a population synthesis model by Kodama & Arimoto (1997). We introduce two new recipes. First, the amount of the internal absorption is changed as a free parameter in the range of E(B-V)=0.0 to 0.5 with an interval of 0.1. Second, the absorption due to intergalactic HI clouds is also changed by a factor of 0.5, 1.0, and 1.5 around the opacity given by Madau (1995). The total number of template SEDs is thus 187x6x3=3,366, except for the redshift grid. The dispersion sigma_z of our photometric redshifts with respect to spectroscopic redshifts is sigma_z=0.08 and 0.24 for z2, respectively, which are smaller than the corresponding values (sigma_z=0.09 and 0.45) by Fernandez-Soto et al. Improvement is significant, especially in z>2. This is due to smaller systematic errors which are largely reduced mainly by including three opacities due to intergalactic HI clouds. We discuss redshift distribution N(z) and cosmic star formation rate based on our new photometric redshifts.Comment: 24 pages including 16 eps figures; accepted for publication in Ap

Hydrodynamic simulations of the KT Eridani nova super-remnant

A nova super-remnant (NSR) is an immense structure associated with a nova that forms when frequent and recurrent nova eruptions sweep up surrounding interstellar material (ISM) into a high density and distant shell. The prototypical NSR, measuring over 100 pc across, was discovered in 2014 around the annually erupting nova M31N 2008-12a. Hydrodynamical simulations demonstrated that the creation of a dynamic NSR by repeated eruptions transporting large quantities of ISM is not only feasible but that these structures should exist around all novae, whether the white dwarf (WD) is increasing or decreasing in mass. But it is only the recurrent nova (RNe) with the highest WD masses and accretion rates that should host observable NSRs. KT Eridani is, potentially, the eleventh RNe recorded in the Galaxy and is also surrounded by a recently unveiled H{\alpha} shell tens of parsecs across, consistent with a NSR. Through modelling the nova ejecta from KT Eri, we demonstrate that such an observable NSR could form in approximately 50,000 years, which fits with the proper motion history of the nova. We compute the expected H{\alpha} emission from the KT Eri NSR and predict that the structure might be accessible to wide-field X-ray facilities.Comment: 9 pages, 7 figures; Accepted for publication in Monthly Notices of the Royal Astronomical Societ

HI Fluctuations at Large Redshifts: I--Visibility correlation

We investigate the possibility of probing the large scale structure in the universe at large redshifts by studying fluctuations in the redshifted 1420 MHz emission from the neutral hydrogen (HI) at early epochs. The neutral hydrogen content of the universe is known from absorption studies for z<4.5. The HI distribution is expected to be inhomogeneous in the gravitational instability picture and this inhomogeneity leads to anisotropy in the redshifted HI emission. The best hope of detecting this anisotropy is by using a large low-frequency interferometric instrument like the Giant Meter-Wave Radio Telescope (GMRT). We calculate the visibility correlation function <V_nu(u) V_nu'(u)> at two frequencies nu and nu' of the redshifted HI emission for an interferometric observation. In particular we give numerical results for the two GMRT channels centered around nu =325 and 610 MHz from density inhomogeneity and peculiar velocity of the HI distribution. The visibility correlation is ~10^-9 to 10^-10 Jy^2. We calculate the signal-to-noise for detecting the correlation signal in the presence of system noise and show that the GMRT might detect the signal for integration times ~ 100 hrs. We argue that the measurement of visibility correlation allows optimal use of the uncorrelated nature of the system noise across baselines and frequency channels.Comment: 17 pages, 2 figures, Submitted to JA

Using HI to probe large scale structures at z ~ 3

The redshifted 1420 MHz emission from the HI in unresolved damped Lyman-\alpha clouds at high z will appear as a background radiation in low frequency radio observations. This holds the possibility of a new tool for studying the universe at high-z, using the mean brightness temperature to probe the HI content and its fluctuations to probe the power spectrum. Existing estimates of the HI density at z~3 imply a mean brightness temperature of 1 mK at 320 Mhz. The cross-correlation between the temperature fluctuations across different frequencies and sight lines is predicted to vary from 10^{-7} K^2 to 10^{-8} K^2 over intervals corresponding to spatial scales from 10 Mpc to 40 Mpc for some of the currently favoured cosmological models. Comparing this with the expected sensitivity of the GMRT, we find that this can be detected with \~10 hrs of integration, provided we can distinguish it from the galactic and extragalactic foregrounds which will swamp this signal. We discuss a strategy based on the very distinct spectral properties of the foregrounds as against the HI emission, possibly allowing the removal of the foregrounds from the observed maps.Comment: 16 pages, includes 6 figures, accepted in JAA (minor revisions, references added

Metallicities and dust content of proximate damped Lyman alpha systems in the Sloan Digital Sky Survey

Composite spectra of 85 proximate absorbers (log N(HI)>20 and velocity difference between the absorption and emission redshift, dv<10,000 km/s) in the SDSS are used to investigate the trends of metal line strengths with velocity separation from the QSO. We construct composites in 3 velocity bins: dv<3000 km/s, 30006000 km/s, with further sub-samples to investigate the metal line dependence on N(HI) and QSO luminosity. Low (e.g. SiII and FeII) and high ionization (e.g. SiIV and CIV) species alike have equivalent widths (EWs) that are larger by factors of 1.5 -- 3 in the dv<3000 km/s composite, compared to the dv>6000 km/s spectrum. The EWs show an even stronger dependence on dv if only the highest neutral hydrogen column density (log N(HI)>20.7) absorbers are considered. We conclude that PDLAs generally have higher metallicities than intervening absorbers, with the enhancement being a function of both dv and N(HI). It is also found that absorbers near QSOs with lower rest-frame UV luminosities have significantly stronger metal lines. We speculate that absorbers near to high luminosity QSOs may have had their star formation prematurely quenched. Finally, we search for the signature of dust reddening by the PDLAs, based on an analysis of the QSO continuum slopes relative to a control sample and determine a limit of E(B-V)<0.014 for an SMC extinction curve. This work provides an empirical motivation for distinguishing between proximate and intervening DLAs, and establishes a connection between the QSO environment and galaxy properties at high redshifts.Comment: Accepted for publication in MNRA

Proton Motive Force-Dependent Hoechst 33342 Transport by the ABC Transporter LmrA of Lactococcus lactis

The fluorescent compound Hoechst 33342 is a substrate for many multidrug resistance (MDR) transporters and is widely used to characterize their transport activity. We have constructed mutants of the adenosine triphosphate (ATP) binding cassette (ABC)-type MDR transporter LmrA of Lactococcus lactis that are defective in ATP hydrolysis. These mutants and wild-type LmrA exhibited an atypical behavior in the Hoechst 33342 transport assay. In membrane vesicles, Hoechst 33342 transport was shown to be independent of the ATPase activity of LmrA, and it was not inhibited by orthovanadate but sensitive to uncouplers that collapse the proton gradient and to N,N'-dicyclohexylcarbodiimide, an inhibitor of the F0F1-ATPase. In contrast, transport of Hoechst 33342 by the homologous, heterodimeric MDR transporter LmrCD showed a normal ATP dependence and was insensitive to uncouplers of the proton gradient. With intact cells, expression of LmrA resulted in an increased rate of Hoechst 33342 influx while LmrCD caused a decrease in the rate of Hoechst 33342 influx. Cellular toxicity assays using a triple knockout strain, i.e., L. lactis ΔlmrA ΔlmrCD, demonstrate that expression of LmrCD protects cells against the growth inhibitory effects of Hoechst 33342, while in the presence of LmrA, cells are more susceptible to Hoechst 33342. Our data demonstrate that the LmrA-mediated Hoechst 33342 transport in membrane vesicles is influenced by the transmembrane pH gradient due to a pH-dependent partitioning of Hoechst 33342 into the membrane.

Large-scale structure in the Lyman-alpha forest II: analysis of a group of ten QSOs

The spatial distribution of Ly-alpha forest absorption systems towards ten QSOs has been analysed to search for large-scale structure over the redshift range 2.2 < z < 3.4. The QSOs form a closely spaced group on the sky and are concentrated within a 1 deg^2 field. We have employed a technique based on the first and second moments of the transmission probability density function which is capable of identifying and assessing the significance of regions of over- or underdense Ly-alpha absorption. We find evidence for large-scale structure in the distribution of Ly-alpha forest absorption at the > 99 per cent confidence level. In individual spectra we find overdense Ly-alpha absorption on scales of up to 1200 km s^-1. There is also strong evidence for correlated absorption across line of sight pairs separated by < 3 h^-1 proper Mpc (q_0 = 0.5). For larger separations the cross-correlation signal becomes progressively less significant.Comment: 15 pages, LaTeX, 6 Postscript figures, accepted for publication in MNRA

HI Fluctuations at Large Redshifts: III - Simulating the Signal Expected at GMRT

We simulate the distribution of neutral hydrogen (HI) at the redshifts z=1.3 and 3.4 using a cosmological N-body simulation along with a prescription for assigning HI masses to the particles. The HI is distributed in clouds whose properties are consistent with those of the damped Lyman-\alpha absorption systems (DLAs) seen in quasar spectra. The clustering properties of these clouds are identical to those of the dark matter. We use this to simulate the redshifted HI emission expected at 610 MHz and 325 MHz, two of the observing bands a the GMRT. These are used to predict the correlations expected between the complex visibilities measured at different baselines and frequencies in radio-interferometric observations with the GMRT. The visibility correlations directly probe the power spectrum of HI fluctuations at the epoch when the HI emission originated, and this holds the possibility of using HI observations to study large-scale structures at high z.Comment: Submitted to JApA, 12 Latex pages including 6 figure