15 research outputs found
Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes
Die strafrechtliche Verantwortlichkeit des Compliance Officers im deutsch-\uf6sterreichischen Rechtsvergleich
eingereicht von Sylvia LangenhahnSalzburg, Univ., Diss., 201
Obesity, age, sex, diagnosis, and fixation mode differently affect early cup failure in total hip arthroplasty: a matched case-control study of 4420 patients
Studies about the influence of patient characteristics on mechanical failure of cups in total hip replacement have applied different methodologies and revealed inconclusive results. The fixation mode has rarely been investigated. Therefore, we conducted a detailed analysis of the influence of patient characteristics and fixation mode on cup failure risks
Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst
Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst
The rational design and synthesis of mesoporous functional materials is of great significance to tackle fundamental challenges in materials science and to yield practical solutions for efficient energy utilization. Here, a novel p-toluenesulfonic acid-assisted mechanochemical approach is used to prepare a silica-templated bipyridine-containing covalent organic framework (COF), which can be further converted into an iron–nitrogen-doped mesoporous carbon (mC-TpBpy-Fe) upon carbonization and template removal. The resulting mC-TpBpy-Fe exhibits a large pore volume and surface area, which significantly promote the mass transfer efficiency and increase the accessibility of the active sites, yielding a high ORR activity with a competitive half-wave potential of 0.845 V and limiting current density of 5.92 mA/cm (vs 0.852 V and 5.57 mA/cm for Pt/C). Application of this COF derived mesoporous carbon within a Zn–air battery revealed that it can operate in ambient conditions with a competitive discharge performance, showing its potential for practical applications
