Size-resolved aerosol and cloud condensation nuclei (CCN) properties in the remote marine South China Sea - Part 1: Observations and source classification

Abstract. Ship-based measurements of aerosol and cloud condensation nuclei (CCN) properties are presented for 2 weeks of observations in remote marine regions of the South China Sea/East Sea during the southwestern monsoon (SWM) season. Smoke from extensive biomass burning throughout the Maritime Continent advected into this region during the SWM, where it was mixed with anthropogenic continental pollution and emissions from heavy shipping activities. Eight aerosol types were identified using a k-means cluster analysis with data from a size-resolved CCN characterization system. Interpretation of the clusters was supplemented by additional onboard aerosol and meteorological measurements, satellite, and model products for the region. A typical bimodal marine boundary layer background aerosol population was identified and observed mixing with accumulation mode aerosol from other sources, primarily smoke from fires in Borneo and Sumatra. Hygroscopicity was assessed using the κ parameter and was found to average 0.40 for samples dominated by aged accumulation mode smoke; 0.65 for accumulation mode marine aerosol; 0.60 in an anthropogenic aerosol plume; and 0.22 during a short period that was characterized by elevated levels of volatile organic compounds not associated with biomass burning impacts. As a special subset of the background marine aerosol, clean air masses substantially scrubbed of particles were observed following heavy precipitation or the passage of squall lines, with changes in observed aerosol properties occurring on the order of minutes. Average CN number concentrations, size distributions, and κ values are reported for each population type, along with CCN number concentrations for particles that activated at supersaturations between 0.14 and 0.85 %

Investigating size-segregated sources of elemental composition of particulate matter in the South China Sea during the 2011 Vasco cruise

The South China Sea (SCS) is a receptor of numerous natural and anthropogenic aerosol species from throughout greater Asia. A combination of several developing countries, archipelagic and peninsular terrain, a strong Asian monsoon climate, and a host of multi-scale meteorological phenomena make the SCS one of the most complex aerosol–meteorological systems in the world. However, aside from the well-known biomass burning emissions from Indonesia and Borneo, the current understanding of aerosol sources is limited, especially in remote marine environments. In September 2011, a 2-week research cruise was conducted near Palawan, Philippines, to sample the remote SCS environment. Size-segregated aerosol data were collected using a Davis Rotating Uniform size-cut Monitor (DRUM) sampler and analyzed for concentrations of 28 elements measured via X-ray fluorescence (XRF). Positive matrix factorization (PMF) was performed separately on the coarse, fine, and ultrafine size ranges to determine possible sources and their contributions to the total elemental particulate matter mass. The PMF analysis resolved six sources across the three size ranges: biomass burning, oil combustion, soil dust, a crustal–marine mixed source, sea spray, and fly ash. Additionally, size distribution plots, time series plots, back trajectories and satellite data were used in interpreting factors. The multi-technique source apportionment revealed the presence of biogenic sources such as soil dust, sea spray, and a crustal–marine mixed source. Anthropogenic sources were also identified: biomass burning, oil combustion, and fly ash. Mass size distributions showed elevated aerosol concentrations towards the end of the sampling period, which coincided with a shift of air mass back trajectories to southern Kalimantan. Covariance between coarse-mode soil dust and fine-mode biomass burning aerosols were observed. Agreement between the PMF and the linear regression analyses indicates that the PMF solution is robust. While biomass burning is indeed a key source of aerosol, this study shows the presence of other important sources in the SCS. Identifying these sources is not only key for characterizing the chemical profile of the SCS but, by improving our picture of aerosol sources in the region, also a step forward in developing our understanding of aerosol–meteorology feedbacks in this complex environment

Aerosol meteorology of Maritime Continent for the 2012 7SEAS southwest monsoon intensive study - Part 2: Philippine receptor observations of fine-scale aerosol behavior

Abstract. The largest 7 Southeast Asian Studies (7SEAS) operations period within the Maritime Continent (MC) occurred in the August–September 2012 biomass burning season. Data included were observations aboard the M/Y Vasco, dispatched to the Palawan Archipelago and Sulu Sea of the Philippines for September 2012. At these locations, the Vasco observed MC smoke and pollution entering the southwest monsoon (SWM) monsoonal trough. Here we describe the research cruise findings and the finer-scale aerosol meteorology of this convectively active region. This 2012 cruise complemented a 2-week cruise in 2011 and was generally consistent with previous findings in terms of how smoke emission and transport related to monsoonal flows, tropical cyclones (TC), and the covariance between smoke transport events and the atmosphere's thermodynamic structure. Biomass burning plumes were usually mixed with significant amounts of anthropogenic pollution. Also key to aerosol behavior were squall lines and cold pools propagating across the South China Sea (SCS) and scavenging aerosol particles in their path. However, the 2012 cruise showed much higher modulation in aerosol frequency than its 2011 counterpart. Whereas in 2011 large synoptic-scale aerosol events transported high concentrations of smoke into the Philippines over days, in 2012 measured aerosol events exhibited a much shorter-term variation, sometimes only 3–12 h. Strong monsoonal flow reversals were also experienced in 2012. Nucleation events in cleaner and polluted conditions, as well as in urban plumes, were observed. Perhaps most interestingly, several cases of squall lines preceding major aerosol events were observed, as opposed to 2011 observations where these lines largely scavenged aerosol particles from the marine boundary layer. Combined, these observations indicate pockets of high and low particle counts that are not uncommon in the region. These perturbations are difficult to observe by satellite and very difficult to model. Indeed, the Navy Aerosol Analysis and Prediction System (NAAPS) simulations captured longer period aerosol events quite well but largely failed to capture the timing of high-frequency phenomena. Ultimately, the research findings of these cruises demonstrate the real world challenges of satellite-based missions, significant aerosol life cycle questions such as those the future Aerosol/Clouds/Ecosystems (ACE) will investigate, and the importance of small-scale phenomena such as sea breezes, squall lines, and nucleation events embedded within SWM patterns in dominating aerosol life cycle and potential relationships to clouds

Aerosol Meteorology of the Maritime Continent for the 2012 7SEAS Southwest Monsoon Intensive Study - Part 2: Philippine Receptor Observations of Fine-Scale Aerosol Behavior

The largest 7 Southeast Asian Studies (7SEAS) operations period within the Maritime Continent (MC) occurred in the August–September 2012 biomass burning season. Data included were observations aboard the M/Y Vasco, dispatched to the Palawan Archipelago and Sulu Sea of the Philippines for September 2012. At these locations, the Vasco observed MC smoke and pollution entering the southwest monsoon (SWM) monsoonal trough. Here we describe the research cruise findings and the finer-scale aerosol meteorology of this convectively active region. This 2012 cruise complemented a 2-week cruise in 2011 and was generally consistent with previous findings in terms of how smoke emission and transport related to monsoonal flows, tropical cyclones (TC), and the covariance between smoke transport events and the atmosphere’s thermodynamic structure. Biomass burning plumes were usually mixed with significant amounts of anthropogenic pollution. Also key to aerosol behavior were squall lines and cold pools propagating across the South China Sea (SCS) and scavenging aerosol particles in their path. However, the 2012 cruise showed much higher modulation in aerosol frequency than its 2011 counterpart. Whereas in 2011 large synoptic-scale aerosol events transported high concentrations of smoke into the Philippines over days, in 2012 measured aerosol events exhibited a much shorter-term variation, sometimes only 3–12 h. Strong monsoonal flow reversals were also experienced in 2012. Nucleation events in cleaner and polluted conditions, as well as in urban plumes, were observed. Perhaps most interestingly, several cases of squall lines preceding major aerosol events were observed, as opposed to 2011 observations where these lines largely scavenged aerosol particles from the marine boundary layer. Combined, these observations indicate pockets of high and low particle counts that are not uncommon in the region. These perturbations are difficult to observe by satellite and very difficult to model. Indeed, the Navy Aerosol Analysis and Prediction System (NAAPS) simulations captured longer period aerosol events quite well but largely failed to capture the timing of high-frequency phenomena. Ultimately, the research findings of these cruises demonstrate the real world challenges of satellite-based missions, significant aerosol life cycle questions such as those the future Aerosol/Clouds/Ecosystems (ACE) will investigate, and the importance of small-scale phenomena such as sea breezes, squall lines, and nucleation events embedded within SWM patterns in dominating aerosol life cycle and potential relationships to clouds

Optical Properties Analysis of Scattering Media Base on GI-OCT Imaging

An optical coherence tomography (OCT) system based on the ghost imaging (GI) technique is developed for correctly imaging in scattering media. Usually, the scattering in the media leads to a decrease in the signal-to-noise ratio of the reconstructed image. This problem can be solved by using ghost imaging-OCT(GI-OCT), but the number of patterns required for GI reconstruction depends on the concentration of the scattering media. Therefore, studying the relationship between the intensity distribution in reconstructed images and the optical properties of scattering media is essential. In this study, image reconstruction is carried out in scattering media with a concentration of 0.0% to 1.4%, diluted from processed milk. Using the structural similarity index method (SSIM) to analyze the reconstruction condition, it is found that the target image can be reconstructed correctly when the SSIM value is more than 0.7. By analyzing the intensity distribution of the reconstructed image, the results show that the extinction coefficient of the scattering media is negatively correlated with the contrast of the reconstructed image and positively correlated with the scattering intensity. Their correlation coefficients are −0.94 and 0.99, respectively

Optical Properties Analysis of Scattering Media Based on GI-OCT Imaging

An optical coherence tomography (OCT) system based on the ghost imaging (GI) technique is developed for correctly imaging in scattering media. Usually, the scattering in the media leads to a decrease in the signal-to-noise ratio of the reconstructed image. This problem can be solved by using ghost imaging-OCT(GI-OCT), but the number of patterns required for GI reconstruction depends on the concentration of the scattering media. Therefore, studying the relationship between the intensity distribution in reconstructed images and the optical properties of scattering media is essential. In this study, image reconstruction is carried out in scattering media with a concentration of 0.0% to 1.4%, diluted from processed milk. Using the structural similarity index method (SSIM) to analyze the reconstruction condition, it is found that the target image can be reconstructed correctly when the SSIM value is more than 0.7. By analyzing the intensity distribution of the reconstructed image, the results show that the extinction coefficient of the scattering media is negatively correlated with the contrast of the reconstructed image and positively correlated with the scattering intensity. Their correlation coefficients are −0.94 and 0.99, respectively

Influence of Ambient Relative Humidity on Seasonal Trends of the Scattering Enhancement Factor for Aerosols in Chiba, Japan

In this study, we used ground instruments, namely, a visibility meter, an integrating nephelometer, an aethalometer, a lidar, and a weather monitor, to measure the scattering enhancement factor, f(RH), which quantifies the effect of ambient relative humidity (RH) on aerosol light-scattering, and to generate a model of its annual variation in the city of Chiba, Japan. First, the f(RH) values were calculated with chemical analysis data. Second, visibility-meter and aethalometer data were used to model the monthly trends of f(RH) at 550 nm. The f(RH) values were higher during summer than during the other three seasons, which can be attributed to the general pattern of the regional climatology as well as the loading of different particle types into the lower troposphere. Third, the f(RH) values at 532 nm were obtained from lidar and aethalometer measurements. Low and constant f(RH) values were observed during November, whereas higher and increasing f(RH) values were observed during May. Also, dust events during March 2015 showed decreasing f(RH) with increasing RH

Assessment of Nighttime Cloud Cover Products from MODIS and Himawari-8 Data with Ground-Based Camera Observations

Comparing cloud cover (CC) products from different satellites with the same ground-based CC dataset provides information on the similarities or differences of values among satellite products. For this reason, 42-month CC products from Moderate Resolution Imaging Spectrometer’s (MODIS) Collection 6.1 daily cloud cover products (MOD06_L2, MYD06_L2, MOD08_D3, and MYD08_D3) and Himawari-8 are compared with the ground-based camera datasets. The comparison shows that CC from MODIS differs from ground measurement CC by as much as 57% over Chiba, Japan, when low CC is observed by the camera. This indicates MODIS’s ability to capture high-level clouds that are not effectively seen from the ground. When the camera detects high CC, an indication of the presence of low-level clouds, CC from MODIS is relatively higher than the CC from the camera. In the case of Himawari-8 data, when the camera observes low CC, this difference is around 0.7%. This result indicates that high-level clouds are not effectively observed, but the Himawari-8 data correlates well with camera observations. When the camera observes high CC, Himawari-8-derived CC is lower by around 10% than CC from the camera. These results show the potential of continuous observations of nighttime clouds using the camera to provide a dataset that can be used for intercomparison among nighttime satellite CC products

Global Sources of Fine Particulate Matter: Interpretation of PM2.5 Chemical Composition Observed by SPARTAN using a Global Chemical Transport Model

Exposure to ambient fine particulate matter (PM2.5) is a leading risk factor for the global burden of disease. However, uncertainty remains about PM2.5 sources. We use a global chemical transport model (GEOS-Chem) simulation for 2014, constrained by satellite-based estimates of PM2.5 to interpret globally dispersed PM2.5 mass and composition measurements from the ground-based surface particulate matter network (SPARTAN). Measured site mean PM2.5 composition varies substantially for secondary inorganic aerosols (2.4–19.7 μg/m3), mineral dust (1.9–14.7 μg/m3), residual/organic matter (2.1–40.2 μg/m3), and black carbon (1.0–7.3 μg/m3). Interpretation of these measurements with the GEOS-Chem model yields insight into sources affecting each site. Globally, combustion sectors such as residential energy use (7.9 μg/m3), industry (6.5 μg/m3), and power generation (5.6 μg/m3) are leading sources of outdoor global population-weighted PM2.5 concentrations. Global population-weighted organic mass is driven by the residential energy sector (64%) whereas population-weighted secondary inorganic concentrations arise primarily from industry (33%) and power generation (32%). Simulation-measurement biases for ammonium nitrate and dust identify uncertainty in agricultural and crustal sources. Interpretation of initial PM2.5 mass and composition measurements from SPARTAN with the GEOS-Chem model constrained by satellite-based PM2.5 provides insight into sources and processes that influence the global spatial variation in PM2.5 composition

Eutrophication of Manila Region, Philippines

In the Philippines about 37% of the total water pollution originates from agricultural practices, which include use of animal waste, fertilizer and pesticide runoff. As a consequence, eutrophication is observed in the Manila coastal region in connection with the major drainage region around Manila. The PasigMarikina-Laguna de Bay Basin as a water drain to Manila Bay is unique because it represents an interconnection between several water bodies and is partly controlled by the Manggahan Floodway and the Napindan Hydraulic Control Structure. The high nutrient emission from Manila and the catchment area around the Manila Bay results in eutrophication of the bay and its adjacent coastal waters. Chlorophyll estimates with satellite measurements show elevated levels and it seems that eutrophication of Manila Bay is present throughout the year but is decoupled from the monsoon seasons