204 research outputs found
Telephone-cord instabilities in thin smectic capillaries
Telephone-cord patterns have been recently observed in smectic liquid crystal
capillaries. In this paper we analyse the effects that may induce them. As long
as the capillary keeps its linear shape, we show that a nonzero chiral
cholesteric pitch favors the SmA*-SmC* transition. However, neither the
cholesteric pitch nor the presence of an intrinsic bending stress are able to
give rise to a curved capillary shape.
The key ingredient for the telephone-cord instability is spontaneous
polarization. The free energy minimizer of a spontaneously polarized SmA* is
attained on a planar capillary, characterized by a nonzero curvature. More
interestingly, in the SmC* phase the combined effect of the molecular tilt and
the spontaneous polarization pushes towards a helicoidal capillary shape, with
nonzero curvature and torsion.Comment: Submitte
Influence of the flow on the anchoring of nematic liquid crystals on a Langmuir-Blodgett monolayer studied by optical second-harmonic generation
The influence of capillary flow on the alignment of the nematic liquid
crystal MBBA on fatty acid Langmuir-Blodgett monolayers was studied by optical
second-harmonic generation. The surface dipole sensitivity of the technique
allows probing the orientation of the first liquid crystal monolayer in the
presence of the liquid crystal bulk. It was found that capillary flow causes
the first monolayer of liquid crystal molecules in contact with the fatty acid
monolayer to be oriented in the flow direction with a large pretilt (78
degrees), resulting in a quasi-planar alignment with splay-bend deformation of
the nematic director in the bulk. itself is affected by the flow. The
quasi-planar flow-induced alignment was found to be metastable. Once the flow
ceases, circular domains of homeotropic orientation nucleate in the sample and
expand until the whole sample becomes homeotropic. This relaxation process from
flow-induced quasi-planar to surface-induced homeotropic alignment was also
monitored by SHG. It was found that in the homeotropic state the first nematic
layer presents a pretilt of 38 degrees almost isotropically distributed in the
plane of the cell, with a slight preference for the direction of the previous
flow.Comment: LaTeX2e article, 11 figures, 17 EPS files, submitte
Nonlinear optical properties of a channel waveguide produced with crosslinkable ferroelectric liquid crystals
A binary mixture of ferroelectric liquid crystals (FLCs) was used for the
design of a channel waveguide. The FLCs possess two important functionalities:
a chromophore with a high hyperpolarizability and photoreactive groups.
The smectic liquid crystal is aligned in layers parallel to the glass plates in
a sandwich geometry. This alignment offers several advantages, such as that
moderate electric fields are sufficient to achieve a high degree of polar
order. The arrangement was then permanently fixed by photopolymerization which
yielded a polar network possessing a high thermal and mechanical stability
which did not show any sign of degradation within the monitored period of
several months. The linear and nonlinear optical properties have been measured
and all four independent components of the nonlinear susceptibility tensor
have been determined. The off-resonant -coefficients are remarkably
high and comparable to those of the best known inorganic materials. The
alignment led to an inherent channel waveguide for p-polarized light without
additional preparation steps. The photopolymerization did not induce scattering
sites in the waveguide and the normalized losses were less than 2 dB/cm. The
material offers a great potential for the design of nonlinear optical devices
such as frequency doublers of low power laser diodes.Comment: LaTeX2e article, 15 pages, 10 figures, 11 EPS files, submitted to
Physical Review
Phase-matched second-harmonic generation in a ferroelectric liquid crystal waveguide
True phase-matched second-harmonic generation in a waveguide of crosslinkable
ferroelectric liquid crystals is demonstrated. These materials allow the
formation of macroscopically polar structures whose order can be frozen by
photopolymerization. Homeotropic alignment was chosen which offers decisive
advantages compared to other geometries. All parameters contributing to the
conversion efficiency are maximized by deliberately controlling the
supramolecular arrangement. The system has the potential to achieve practical
level of performances as a frequency doubler for low power laser diodes.Comment: 4 pages, LaTeX2e article, 3 figures, 4 EPS files, submitted to
Physical Review Letter
Effects of weak anchoring on C1 and C2 chevron structures
We present a theoretical study of the effect of weak anchoring on the transition between C1 and C2 chevron structures in smectic C liquid crystals. We employ a continuum theory which allows for variable cone, azimuthal and layer tilt angles. Equilibrium profiles for the director cone and azimuthal angles in the C1 and C2 states are calculated from the standard Euler-Lagrange minimisation of the total energy of the system. By comparing the total energies of the C1 and C2 states we can determine the globally stable chevron profile and calculate the critical temperature for the C1-C2 transition, which depends on anchoring strength and pretilt angle variations
Induced Anticlinic Ordering and Nanophase Segregation of Bow-Shaped Molecules in a Smectic Solvent
Recent experiments indicate that doping low concentrations of bent-core
molecules into calamitic smectic solvents can induce anticlinic and biaxial
smectic phases. We have carried out Monte Carlo (MC) simulations of mixtures of
rodlike molecules (hard spherocylinders with length/breadth ratio ) and bow- or banana-shaped molecules (hard spherocylinder dimers
with length/breadth ratio or 2.5 and opening angle ) to
probe the molecular-scale organization and phase behavior of rod/banana
mixtures. We find that a low concentration (3%) of dimers
induces anticlinic (SmC) ordering in an untilted smectic (SmA) phase for
. For smaller , half of each bow-shaped
molecule is nanophase segregated between smectic layers, and the smectic layers
are untilted. For , no tilted phases are induced. However,
with decreasing we observe a sharp transition from {\sl intralamellar}
nanophase segregation (bow-shaped molecules segregated within smectic layers)
to {\sl interlamellar} nanophase segregation (bow-shaped molecules concentrated
between smectic layers) near . These results demonstrate that
purely entropic effects can lead to surprisingly complex behavior in rod/banana
mixtures.Comment: 5 pages Revtex, 7 postscript figure
Responsive Photonic Liquid Marbles
Liquid marbles have potential to serve as mini-reactors for fabricating new materials, but this has been exploited little and mostly for conventional chemical reactions. Here, we uncover the unparalleled capability of liquid marbles to act as platforms for controlling the self-assembly of a bio-derived polymer, hydroxypropyl cellulose, into a cholesteric liquid crystalline phase showing structural coloration by Bragg reflection. By adjusting the cholesteric pitch via quantitative water extraction, we achieve liquid marbles that we can tailor for structural color anywhere in the visible range. Liquid marbles respond with color change that can be detected by eye, to changes in temperature, exposure to toxic chemicals and mechanical deformation. Our concept demonstrates the advantages of using liquid marbles as a miniature platform for controlling the liquid crystal self-assembly of bio-derived polymers, and their exploitation to fabricate sustainable, responsive soft photonic objects
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