Controlling the crystal polymorph by exploiting the time dependence of nucleation rates

Most substances can crystallise into two or more different crystal lattices, called polymorphs. Despite this, there are no systems in which we can quantitatively predict the probability of one competing polymorph forming, instead of the other. We address this problem using large scale (hundreds of events) studies of the competing nucleation of the alpha and gamma polymorphs of glycine. In situ Raman spectroscopy is used to identify the polymorph of each crystal. We find that the nucleation kinetics of the two polymorphs is very different. Nucleation of the alpha polymorph starts off slowly but accelerates, while nucleation of the gamma polymorph starts off fast but then slows. We exploit this difference to increase the purity with which we obtain the gamma polymorph by a factor of ten. The statistics of the nucleation of crystals is analogous to that of human mortality, and using a result from medical statistics we show that conventional nucleation data can say nothing about what, if any, are the correlations between competing nucleation processes. Thus we can show that, with data of our form, it is impossible to disentangle the competing nucleation processes. We also find that the growth rate and the shape of a crystal depends on when it nucleated. This is new evidence that nucleation and growth are linked.Comment: 8 pages, plus 17 pages of supplementary materia

C18O (3-2) observations of the Cometary Globule CG 12: a cold core and a C18O hot spot

The feasibility of observing the C18O (3-2) spectral line in cold clouds with the APEX telescope has been tested. As the line at 329.330 GHz lies in the wing of a strong atmospheric H2O absorption it can be observed only at high altitude observatories. Using the three lowest rotational levels instead of only two helps to narrow down the physical properties of dark clouds and globules. The centres of two C18O maxima in the high latitude low mass star forming region CG 12 were mapped in C18O (3-2) and the data were analyzed together with spectral line data from the SEST. The T_MB(3-2)/T_MB(2-1) ratio in the northern C18O maximum, CG 12 N, is 0.8, and in the southern maximum, CG 12 S, ~2. CG 12 N is modelled as a 120'' diameter (0.4pc) cold core with a mass of 27 Msun. A small size maximum with a narrow, 0.8 kms-1, C18O (3-2) spectral line with a peak temperature of T_MB ~11 K was detected in CG 12 S. This maximum is modelled as a 60'' to 80'' diameter (~0.2pc) hot (80 K < Tex < 200 K) ~1.6 Msun clump. The source lies on the axis of a highly collimated bipolar molecular outflow near its driving source. This is the first detection of such a compact, warm object in a low mass star forming region.Comment: APEX A&A special issue, accepte

Isotopically Light Cd in Sediments Underlying Oxygen Deficient Zones

Cadmium is a trace metal of interest in the ocean partly because its concentration mimics that of phosphate. However, deviations from the global mean dissolved Cd/PO4 relationship are present in oxygen deficient zones, where Cd is depleted relative to phosphate. This decoupling has been suggested to result from cadmium sulphide (CdS) precipitation in reducing microenvironments within sinking organic matter. We present Cd concentrations and Cd isotope compositions in organic-rich sediments deposited at several upwelling sites along the northeast Pacific continental margin. These sediments all have enriched Cd concentrations relative to crustal material. We calculate a net accumulation rate of Cd in margin settings of between 2.6 to 12.0 × 107 mol/yr, higher than previous estimates, but at the low end of a recently published estimate for the magnitude of the marine sink due to water column CdS precipitation. Cadmium in organic-rich sediments is isotopically light (δ114/110CdNIST-3108 = +0.02 ± 0.14‰, n = 26; 2 SD) compared to deep seawater (+0.3 ± 0.1‰). However, isotope fractionation during diagenesis in continental margin settings appears to be small. Therefore, the light Cd isotope composition of organic-rich sediments is likely to reflect an isotopically light source of Cd. Non-quantitative biological uptake of light Cd by phytoplankton is one possible means of supplying light Cd to the sediment, which would imply that Cd isotopes could be used as a tracer of past ocean productivity. However, water column CdS precipitation is also predicted to preferentially sequester light Cd isotopes from the water column, which could obfuscate Cd as a tracer. We also observe notably light Cd isotope compositions associated with elevated solid phase Fe concentrations, suggesting that scavenging of Cd by Fe oxide phases may contribute to the light Cd isotope composition of sediments. These multiple possible sources of isotopically light Cd to sediments, along with evidence for complex particle cycling of Cd in the water column, bring into question the straightforward application of Cd isotopes as a paleoproductivity proxy

Strong Enhancement of Superconducting Correlation in a Two-Component Fermion Gas

We study high-density electron-hole (e-h) systems with the electron density slightly larger than the hole density. We find a new superconducting phase, in which the excess electrons form Cooper pairs moving in an e-h BCS phase. The coexistence of the e-h and e-e orders is possible because e and h have opposite charges, whereas analogous phases are impossible in the case of two fermion species that have the same charge or are neutral. Most strikingly, the e-h order enhances the superconducting e-h order parameter by more than one order of magnitude as compared with that given by the BCS formula, for the same value of the effective e-e attractive potential \lambda^{ee}. This new phase should be observable in an e-h system created by photoexcitation in doped semiconductors at low temperatures.Comment: 5 pages including 5 PostScript figure

Business Value Is not only Dollars - Results from Case Study Research on Agile Software Projects

Business value is a key concept in agile software development. This paper presents results of a case study on how business value and its creation is perceived in the context of agile projects. Our overall conclusion is that the project participants almost never use an explicit and structured approach to guide the value creation throughout the project. Still, the application of agile methods in the studied cases leads to satisfied clients. An interesting result of the study represents the fact that the agile process of many projects differs significantly from what is described in the agile practitioners’ books as best practices. The key implication for research and practice is that we have an incentive to pursue the study of value creation in agile projects and to complement it by providing guidelines for better client’s involvement, as well as by developing structured methods that will enhance the value-creation in a project

Lyman-alpha Forest Constraints on the Mass of Warm Dark Matter and the Shape of the Linear Power Spectrum

High resolution N-body simulations of cold dark matter (CDM) models predict that galaxies and clusters have cuspy halos with excessive substructure. Observations reveal smooth halos with central density cores. One possible resolution of this conflict is that the dark matter is warm (WDM); this will suppress the power spectrum on small scales. The Lyman-alpha forest is a powerful probe of the linear power spectrum on these scales. We use collisionless N-body simulations to follow the evolution of structure in WDM models, and analyze artificial Lyman-alpha forest spectra extracted from them. By requiring that there is enough small-scale power in the linear power spectrum to reproduce the observed properties of the Lyman-alpha forest in quasar spectra, we derive a lower limit to the mass of the WDM particle of 750 eV. This limit is robust to reasonable uncertainties in our assumption about the temperature of the mean density gas (T0) at z=3. We argue that any model that suppresses the CDM linear theory power spectrum more severely than a 750 eV WDM particle cannot produce the Lyman-alpha forest.Comment: 13 pages including 4 color Figures and 1 Table, submitted to ApJ Letter