Structure and magnetic properties of nanocrystalline PrCo3

The structure and magnetic properties of nanocrystalline PrCo$_3$ prepared by high-energy milling technique have been investigated by means of X-ray diffraction using the Rietveld method coupled to Curie temperature and magnetic measurements. The as-milled samples were subsequently annealed in temperature range from 750 to 1050 {\deg}C for 30 min to optimize the extrinsic properties. From x-ray studies of magnetic aligned samples, the magnetic anisotropy of this compounds is found uniaxial. The Curie temperature is 349 {\deg}K and no saturation reached at room temperature for applied field of 90 kOe. The coercive field of 55 kOe and 12 kOe measured at 10 and 293 K respectively is obtained after annealing at 750 {\deg}C for 30 min suggests that nanocrystalline PrCo$_3$ are interesting candidates in the field of permanent magnets. We have completed this experimental study by simulations in the micromagnetic framework in order to get a qualitative picture of the microstructure effect on the macroscopic magnetization curve. From this simple model calculation, we can suggest that the after annealing the system behaves as magnetically hard crystallites embedded in a weakly magnetized amorphous matrix. PACS : 75.50.Bb, 75.50.Tt, 76.80.+yComment: Published in Journal of Applied Physics, 107, 083916 (2010). To be found at: http://jap.aip.or

Magnetic and structural properties of nanocrystalline PrCo3_3

The structure and magnetic properties of nanocrystalline PrCo$_3$ obtained from high energy milling technique are investigated by X-ray diffraction, Curie temperature determination and magnetic properties measurements are reported. The as-milled samples have been annealed in a temperature range of 1023 K to 1273 K for 30 mn to optimize the extrinsic properties. The Curie temperature is 349\,K and coercive fields of 55\,kOe at 10\,K and 12\,kOe at 293\,K are obtained on the samples annealed at 1023\,K. A simulation of the magnetic properties in the framework of micromagnetism has been performed in order to investigate the influence of the nanoscale structure. A composite model with hard crystallites embedded in an amorphous matrix, corresponding to the as-milled material, leads to satisfying agreement with the experimental magnetization curve. [ K. Younsi, V. Russier and L. Bessais, J. Appl. Phys. {\bf 107}, 083916 (2010)]. The microscopic scale will also be considered from DFT based calculations of the electronic structure of $R$Co$_x$ compounds, where $R$ = (Y, Pr) and $x$ = 2,3 and 5.Comment: To be published in J. Phys.: Conference Series in the JEMS 2010 special issue. To be found once published at http://iopscience.iop.org/1742-659

DC-conductivity of a suspension of insulating particles with internal rotation

We analyse the consequences of Quincke rotation on the conductivity of a suspension. Quincke rotation refers to the spontaneous rotation of insulating particles dispersed in a slightly conducting liquid and subject to a high DC electric field: above a critical field, each particle rotates continuously around itself with an axis pointing in any direction perpendicular to the DC field. When the suspension is subject to an electric field lower than the threshold one, the presence of insulating particles in the host liquid decreases the bulk conductivity since the particles form obstacles to ion migration. But for electric fields higher than the critical one, the particles rotate and facilitate ion migration: the effective conductivity of the suspension is increased. We provide a theoretical analysis of the impact of Quincke rotation on the apparent conductivity of a suspension and we present experimental results obtained with a suspension of PMMA particles dispersed in weakly conducting liquids

Room temperature soft ferromagnetism in the nanocrystalline form of YCo2 - a well-known bulk Pauli paramagnet

The Laves phase compound, YCo2, is a well-known exchange-enahnced Pauli paramagnet. We report here that, in the nanocrystalline form, this compound interestingly is an itinerant ferromagnet at room temperature with a low coercive-field. The magnitude of the saturation moment (about 1 Bohr-magneton per formula unit) is large enough to infer that the ferromagnetism is not a surface phenomenon in these nanocrystallites. Since these ferromagnetic nanocrystallines are easy to synthesize with a stable form in air, one can explore applications, particularly where hysteresis is a disadvantage

Cu(I)-Catalyzed Alkynylation of Quinolones

[Image: see text] Herein we report the first alkynylation of quinolones with terminal alkynes under mild reaction conditions. The reaction is catalyzed by Cu(I) salts in the presence of a Lewis acid, which is essential for the reactivity of the system. The enantioselective version of this transformation has also been explored, and the methodology has been applied in the synthesis of the enantioenriched tetrahydroquinoline alkaloid cuspareine

Change in Grassland Science: Implications for Training, Research and Grassland Societies

In most of the world the priority for production-oriented research has been succeeded by the need for grassland research to focus on systems which satisfy requirements relating to the stability and protection of land, water and atmospheric resources and to biodiversity, in addition to production efficiency. This dictates not only a new approach to research, but also new approaches for the organisation of research, the training and development of research scientists and the activities of Grassland Societies and associated organisations

Distribution of phytoplankton pigments in nine European estuaries and implications for an estuarine typology

Phytoplankton pigments were studied by LiquidChromatography (HPLC) in nine West Europeanestuaries. Three estuaries, i.e. the Rhine,Scheldt and the Gironde were sampled four timesto cover the different seasons, whereas theother six estuaries were sampled once. Pigmentdistributions in estuaries reflect bothriverine inputs as well as autochthonousblooms. Fucoxanthin was the most commonaccessory photosynthetic pigment showing thatDiatoms were the most common group in thestudied estuaries and were particularlydominant during autumn and winter. In the veryturbid Gironde estuary, degradation processeswere predominant between salinities 1 and 20,while Diatoms, Dinoflagellates and Cryptophytesbloomed above 20 salinity during spring andsummer. This contrasted with the highlyeutrophic but less turbid Scheldt, wherephytoplanktonic blooms occurred at lowsalinities close to the city of Antwerp. In theScheldt, we observed both a tenfold fluctuationof phytoplankton biomass and a fluctuatingpigment diversity index. In contrast,chlorophyll a was always low in theGironde, but we observed large variations ofpigment diversity among samplings duringdifferent seasons. Distribution of pheopigmentsshowed that the maximum turbidity zone (MTZ)was a highly reactive region for heterotrophicphytoplankton degradation. The Scheldt and theThames were the most anthropogenic influencedestuaries contrasting with the Gironde estuarythat has a less urbanised watershed. Anestuarine typology is proposed based on threeclusters emerging from a correspondenceanalysis of pigment variables and variablescharacterising the anthropogenic impact andphysical forcing

Effect of Nitrogen Fertilizer on Reproductive Tiller Development in Perennial Ryegrass

The objective of this study was to compare reproductive tiller development in two ryegrass (Lolium perenne L.) cultivars, when fertilized with nitrogen. Plots of the cultivars ‘Grasslands Ruanui’ and ‘Ellett’ ryegrass were sown in April 1996. Half of each plot received nitrogen fertilizer (30 kg N/ha) after each grazing by dairy cows from September 1996 to May 1997 and from October 1997 to April 1998. Ryegrass tiller dynamics was monitored from September 1996 to March 1998. The proportion of reproductive tillers in the total tiller population was higher, on average, over the first flowering period (October 1996 to January 1997) for ‘Ellett’ (19.5%) than for ‘Grasslands Ruanui’ (13.0%) ryegrass, and there was no response to nitrogen. Over the second flowering (September 1997 to January 1998), ‘Ellett’ ryegrass slightly increased the proportion of reproductive tillers in response to nitrogen (averaging 20%) while ‘Grasslands Ruanui’ decreased (P \u3c 0.05) the number of reproductive tillers (averaging 6%). Significant cultivar x nitrogen interactions occurred in December 1997 and January 1998 when reproductive tiller number for nitrogen treated plants averaged 24.1% for ‘Ellett’ compared with 7.8% for ‘Grasslands Ruanui’ ryegrass. This work suggests current New Zealand ryegrasses (here represented by ‘Ellett’) may produce more reproductive tillers in response to spring applied nitrogen fertilizer than do older types. To encourage vegetative tillering from the bases of dying reproductive tillers and the likelihood of improved ryegrass persistence, applications of nitrogen fertilizer in early summer are recommended