Probing magnetic order in EELS of chromite spinels using both multiple scattering (FEFF8.2) and DFT (WIEN2k)

The electron energy loss near edge structure on the O K-edge from chromite spinels contains fine structure from the hybridisation of the O p-orbitals and the Cr d-orbitals. Unlike the aluminates, a non-spin polarised calculation of this fine structure differs significantly from experimental observations. This is due to the large magnetic moment on the Cr. Calculations using simplified collinear ordering of the spins and the local spin density approximation give much improved agreement. A real space multiple scattering formalism and a reciprocal space density functional formalism give results in substantial agreement. In general, the actual spin arrangement of these chromites is not known since they are typically frustrated magnetic systems with ordering temperatures in the 10–20 K range. The calculations are based on the hypothesis that dynamic short range order persists to room temperature over the time scale of the interaction with the fast electron. However, it is possible that the observed effects are due to the strong paramagnetism present at room temperatures but which it is not possible to simulate accurately at present

Record of crustal thickening and synconvergent extension from the dajiamang tso rift, southern tibet

North-trending rifts throughout south-central Tibet provide an opportunity to study the dynamics of synconvergent extension in contractional orogenic belts. In this study, we present new data from the Dajiamang Tso rift, including quantitative crustal thickness estimates calculated from trace/rare earth element zircon data, U-Pb geochronology, and zircon-He thermochronology. These data constrain the timing and rates of exhumation in the Dajiamang Tso rift and provide a basis for evaluating dynamic models of synconvergent extension. Our results also provide a semi-continuous record of Mid-Cretaceous to Miocene evolution of the Himalayan-Tibetan orogenic belt along the India-Asia suture zone. We report igneous zircon U-Pb ages of ~103 Ma and 70–42 Ma for samples collected from the Xigaze forearc basin and Gangdese Batholith/Linzizong Formation, respectively. Zircon-He cooling ages of forearc rocks in the hanging wall of the Great Counter thrust are ~28 Ma, while Gangdese arc samples in the footwalls of the Dajiamang Tso rift are 16–8 Ma. These data reveal the approximate timing of the switch from contraction to extension along the India-Asia suture zone (minimum 16 Ma). Crustal-thickness trends from zircon geochemistry reveal possible crustal thinning (to ~40 km) immediately prior to India-Eurasia collision onset (58 Ma). Following initial collision, crustal thickness increases to 50 km by 40 Ma with continued thickening until the early Miocene supported by regional data from the Tibetan Magmatism Database. Current crustal thickness estimates based on geophysical observations show no evidence for crustal thinning following the onset of E–W extension (~16 Ma), suggesting that modern crustal thickness is likely facilitated by an underthrusting Indian lithosphere balanced by upper plate extension. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.Open access journalThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

Regional Exhumation and Tectonic History of the Shanxi Rift and Taihangshan, North China

This study presents a comprehensive low-temperature thermochronometric data set from the Shanxi Rift, Taihangshan, and eastern Ordos block in North China, including new apatite fission track and apatite (U-Th-Sm)/He data and published apatite and zircon fission track and (U-Th-Sm)/He data. We use these data and new thermal history inversion models to reveal that the Shanxi Rift and Taihangshan experienced an increase in cooling rates between ca. 110–70 Ma and ca. 50–30 Ma. A preceding ca. 160–135 Ma cooling event is generally restricted to the western rift margin in the Lüliangshan and Hengshan. In contrast, the ca. 50–30 Ma cooling event was widespread and occurred coevally with the opening of the Bohai Basin and slip across the NNE-striking Eastern Taihangshan fault. In the southern rift zone, however, exhumation beginning ca. 50 Ma was likely associated with fault block uplift across the ESE–striking Qinling and Huashan faults, which accompanied the extensional opening of the Weihe Graben. Coeval fault slip along the NNE–striking Eastern Taihangshan faults and ESE–striking Qinling and Huashan faults was associated with NW-SE extension in North China related to oblique subduction of the Pacific plate under Eastern Asia and slow convergence rates. The Shanxi Rift is commonly attributed to Late Miocene and younger extension, but our new thermochronologic data do not precisely record the onset of rifting. However, our inversion models do suggest ≤∼50°C of Neogene–Quaternary cooling, consistent with ≤∼2 km of footwall uplift across most range-bounding faults. © 2021. American Geophysical Union. All Rights Reserved.6 month embargo; first published: 21 January 2021This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]