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    An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

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    The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations
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