563 research outputs found
Optical Properties of (SrMnO3)n/(LaMnO3)2n superlattices: an insulator-to-metal transition observed in the absence of disorder
We measure the optical conductivity of (SrMnO3)n/(LaMnO3)2n superlattices
(SL) for n=1,3,5, and 8 and 10 < T < 400 K. Data show a T-dependent insulator
to metal transition (IMT) for n \leq 3, driven by the softening of a polaronic
mid-infrared band. At n = 5 that softening is incomplete, while at the
largest-period n=8 compound the MIR band is independent of T and the SL remains
insulating. One can thus first observe the IMT in a manganite system in the
absence of the disorder due to chemical doping. Unsuccessful reconstruction of
the SL optical properties from those of the original bulk materials suggests
that (SrMnO3)n/(LaMnO3)2n heterostructures give rise to a novel electronic
state.Comment: Published Online in Nano Letters, November 8, 2010;
http://pubs.acs.org/doi/abs/10.1021/nl1022628; 5 pages, 3 figure
Si-compatible candidates for high-K dielectrics with the Pbnm perovskite structure
We analyze both experimentally (where possible) and theoretically from
first-principles the dielectric tensor components and crystal structure of five
classes of Pbnm perovskites. All of these materials are believed to be stable
on silicon and are therefore promising candidates for high-K dielectrics. We
also analyze the structure of these materials with various simple models,
decompose the lattice contribution to the dielectric tensor into force constant
matrix eigenmode contributions, explore a peculiar correlation between
structural and dielectric anisotropies in these compounds and give phonon
frequencies and infrared activities of those modes that are infrared-active. We
find that CaZrO_3, SrZrO_3, LaHoO_3, and LaYO_3 are among the most promising
candidates for high-K dielectrics among the compounds we considered.Comment: 17 pages, 9 figures, 4 tables. Supplementary information:
http://link.aps.org/supplemental/10.1103/PhysRevB.82.064101 or
http://www.physics.rutgers.edu/~sinisa/highk/supp.pd
Understanding the Clean Interface between Covalent Si and Ionic Al2O3
The atomic and electronic structures of the (001)-Si/(001)-gamma-Al2O3
heterointerface are investigated by first principles total energy calculations
combined with a newly developed "modified basin-hopping" method. It is found
that all interface Si atoms are fourfold coordinated due to the formation of
Si-O and unexpected covalent Si-Al bonds in the new abrupt interface model. And
the interface has perfect electronic properties in that the unpassivated
interface has a large LDA band gap and no gap levels. These results show that
it is possible to have clean semiconductor-oxide interfaces
Evolution of magnetic phases and orbital occupation in (SrMnO3)n/(LaMnO3)2n superlattices
The magnetic and electronic modifications induced at the interfaces in
(SrMnO)/(LaMnO) superlattices have been investigated
by linear and circular magnetic dichroism in the Mn L x-ray absorption
spectra. Together with theoretical calculations, our data demonstrate that the
charge redistribution across interfaces favors in-plane ferromagnetic (FM)
order and orbital occupation, in agreement with the
average strain. Far from interfaces, inside LaMnO, electron localization
and local strain favor antiferromagnetism (AFM) and
orbital occupation. For the high density of interfacial planes ultimately
leads to dominant FM order forcing the residual AFM phase to be in-plane too,
while for the FM layers are separated by AFM regions having
out-of-plane spin orientation.Comment: accepted for publication as a Rapid Communication in Physical Review
Interplay of Spin-Orbit Interactions, Dimensionality, and Octahedral Rotations in Semimetallic SrIrO
We employ reactive molecular-beam epitaxy to synthesize the metastable
perovskite SrIrO and utilize {\it in situ} angle-resolved photoemission
to reveal its electronic structure as an exotic narrow-band semimetal. We
discover remarkably narrow bands which originate from a confluence of strong
spin-orbit interactions, dimensionality, and both in- and out-of-plane IrO
octahedral rotations. The partial occupation of numerous bands with strongly
mixed orbital characters signals the breakdown of the single-band Mott picture
that characterizes its insulating two-dimensional counterpart,
SrIrO, illustrating the power of structure-property relations for
manipulating the subtle balance between spin-orbit interactions and
electron-electron interactions
IgG Responses to Tissue-Associated Antigens as Biomarkers of Immunological Treatment Efficacy
We previously demonstrated that IgG responses to a panel of 126 prostate tissue-associated antigens are common in patients with prostate cancer. In the current report we questioned whether changes in IgG responses to this panel might be used as a measure of immune response, and potentially antigen spread, following prostate cancer-directed immune-active therapies. Sera were obtained from prostate cancer patients prior to and three months following treatment with androgen deprivation therapy (n = 34), a poxviral vaccine (n = 31), and a DNA vaccine (n = 21). Changes in IgG responses to individual antigens were identified by phage immunoblot. Patterns of IgG recognition following three months of treatment were evaluated using a machine-learned Bayesian Belief Network (ML-BBN). We found that different antigens were recognized following androgen deprivation compared with vaccine therapies. While the number of clinical responders was low in the vaccine-treated populations, we demonstrate that ML-BBN can be used to develop potentially predictive models
Role of Interfaces in the Proximity Effect in Anisotropic Superconductors
We report measurements of the critical temperature of YBCO-Co doped YBCO
Superconductor-Normal bilayer films. Depending on the morphology of the S-N
interface, the coupling between S and N layers can be turned on to depress the
critical temperature of S by tens of degrees, or turned down so the layers
appear almost totally decoupled. This novel effect can be explained by the
mechanism of quasiparticle transmission into an anisotropic superconductor.Comment: 13 pages, 3 figure
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