Thermal stability and grain growth behavior of mechanically alloyed nanocrystalline Fe-Cu alloys

X-ray diffraction, transmission electron microscopy, and differential scanning calorimetry were used to study the thermal stability of highly supersaturated nanocrystalline FexCu100−x alloys (10~80. For 60<=x<=80 fcc and bcc phases coexist. Heating to elevated temperatures leads to structural relaxation, phase separation, and grain growth of the metastable nanocrystalline solid solutions. Single-phase fcc and bcc alloys undergo significant strain release but no appreciable grain growth prior to phase separation. After phase separation pronounced grain growth sets in. In contrast, samples in the two-phase region show some grain growth and significant chemical redistribution even at low temperatures. The phase separation of single-phase fcc and bcc alloys proceeds via different mechanisms: fcc solid solutions decompose by forming small Fe precipitates, while demixing in bcc alloys starts by segregation of Cu atoms to bcc grain boundaries before nucleation of Cu precipitates. These results show that the stability and grain growth behavior of nanocrystalline alloys is strongly affected by the microstructure of the material

Parameter trails

Successful communication is vital for the success of any design project. However, communication often fails, adversely affecting design process efficiency and product quality.understand the connections between different aspects of design and don–t know where to find out more information or who to talk to. This paper presents a new model, developed from current project planning techniques, which supports communication using parameter-specific data. It enables designers to question information, inform their colleagues pro-actively and assess the impact of changing parameter values on subsequent design tasks. Such interaction is critical in allowing designers to see how their own tasks fit into the overall product design

Mechanically driven alloying and grain size changes in nanocrystalline Fe-Cu powders

Highly supersaturated nanocrystalline FexCu100-x alloys (10 less-than-or-equal-to x less-than-or-equal-to 95) have been prepared by mechanical alloying of elemental crystalline powders. The development of the microstructure is investigated by x-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The results are compared with data for ball-milled elemental Fe and Cu powders, samples prepared by inert gas condensation, and sputtered films. The deformation during milling reduces the grain size of the alloys to 6-20 nm. The final grain size of the powders depends on the composition of the material. Single-phase fcc alloys with x less-than-or-equal-to 60 and single-phase bcc alloys with x greater-than-or-equal-to 80 are formed even though the Fe-Cu system exhibits vanishingly small solid solubilities under equilibrium conditions. For 60 less-than-or-equal-to x less-than-or-equal-to 80, fcc and bcc solid solutions coexist. The alloy formation is discussed with respect to the thermodynamic conditions of the material. The role of the large volume fraction of grain boundaries between the nanometer-sized crystals, as well as the influence of internal strains and stored enthalpies introduced by ball milling, is critically assessed

A functional analysis of change propagation

A thorough understanding of change propagation is fundamental to effective change management during product redesign. A new model of change propagation, as a result of the interaction of form and function is presented and used to develop an analysis method that determines how change is likely to propagate. The analysis produces a Design Structure Matrix, which clearly illustrates change propagation paths and highlights connections that could otherwise be ignored. This provides the user with an in-depth knowledge of product connectivity, which has the potential to support the design process and reduce the product's susceptibility to future change

Ultracold atomic Bose and Fermi spinor gases in optical lattices

We investigate magnetic properties of Mott-insulating phases of ultracold Bose and Fermi spinor gases in optical lattices. We consider in particular the F=2 Bose gas, and the F=3/2 and F=5/2 Fermi gases. We derive effective spin Hamiltonians for one and two atoms per site and discuss the possibilities of manipulating the magnetic properties of the system using optical Feshbach resonances. We discuss low temperature quantum phases of a 87Rb gas in the F=2 hyperfine state, as well as possible realizations of high spin Fermi gases with either 6Li or 132Cs atoms in the F=3/2 state, and with 173Yb atoms in the F=5/2 state.Comment: 15 pages, 5 figures; a completely new and substantially expanded version with several errors correcte

Comparative study of design: application to Engineering Design

A recent exploratory study examines design processes across domains and compares them. This is achieved through a series of interdisciplinary, participative workshops. A systematic framework is used to collect data from expert witnesses who are practising designers across domains from engineering through architecture to product design and fashion, including film production, pharmaceutical drugs, food, packaging, graphics and multimedia and software. Similarities and differences across domains are described which indicate the types of comparative analysis we have been able to do from our data. The paper goes further and speculates on possible lessons for selected areas of engineering design which can be drawn from comparison with processes in other domains. As such this comparative design study offers the potential for improving engineering design processes. More generally it is a first step in creating a discipline of comparative design which aims to provide a new rich picture of design processes

Role of Hemin and Growth Media on the Autofluorescence of Streptococcus mutans

poster abstractAbstract Carious lesions fluoresce under blue light. The primary cariogenic bacterium Streptococcus mutans has been shown previously to fluoresce within blue light wavelengths. In this study we wanted to determine the role of hemin and various growth media on the fluorescing properties of S. mutans under planktonic (total biomass) and biofilm (biofilm mass) growth conditions. UA159 was grown for 24 h at 37ºC in Tryptic Soy Broth (TSB), Brain Heart Infusion (BHI) and Todd Hewitt broth (THB) with and without hemin in 5% CO2. Biofilm was grown for 24 h in a 96 well sterile microplate in the above described media with and without hemin. A stock solution of Protoporphyrin –IX was prepared and diluted to concentrations ranging from 1.6-3.1×10-4 g/ml. A SpectraMax (M3) was used to determine the fluorescence from UA159. RFU of total biomass and biofilm mass was assessed by exciting at fixed wavelengths of 385 and 405 nm at a spectral band width of 10 nm. Emission spectra at 770 nm were observed with 385 nm and an emission of 800 and 810 nm with 405 nm. ANOVA on the ranks of the measurements was used, with four different factors including wavelength (770, 800 and 810 nm); total biomass or biofilm mass; various growth media (TSB, BHI, THB) and the presence/absence of hemin and interactions among the factors. The analysis allowed each media-hemin combination to have different variances. Hemin decreased the amount of fluorescence; regardless of the levels of the other factors (p≤0.0001). Without hemin, BHI had more fluorescence than THB (p≤0.0003) and TSB (p≤0.0001). However with hemin, THB had more fluorescence than BHI (p≤0.0001) and TSB (p≤0.0001). The role of hemin and porphyrin-related compounds in the metabolism of S. mutans should be elucidated

Long-range adiabatic quantum state transfer through a linear array of quantum dots

We introduce an adiabatic long-range quantum communication proposal based on a quantum dot array. By adiabatically varying the external gate voltage applied on the system, the quantum information encoded in the electron can be transported from one end dot to another. We numerically solve the Schr\"odinger equation for a system with a given number of quantum dots. It is shown that this scheme is a simple and efficient protocol to coherently manipulate the population transfer under suitable gate pulses. The dependence of the energy gap and the transfer time on system parameters is analyzed and shown numerically. We also investigate the adiabatic passage in a more realistic system in the presence of inevitable fabrication imperfections. This method provides guidance for future realizations of adiabatic quantum state transfer in experiments.Comment: 7 pages, 7 figure