348 research outputs found
Mechanism of Near-Field Raman Enhancement in One-Dimensional Systems
We develop a theory of near-field Raman enhancement in one-dimensional systems, and report supporting experimental results for carbon nanotubes. The enhancement is established by a laser-irradiated nanoplasmonic structure acting as an optical antenna. The near-field Raman intensity is inversely proportional to the 10th power of the separation between the enhancing structure and the one-dimensional system. Experimental data obtained from single-wall carbon nanotubes indicate that the Raman enhancement process is not significantly influenced by the specific phonon eigenvector, and is mainly defined by the properties of the nanoplasmonic structure
Calculation of the Raman G peak intensity in monolayer graphene: role of Ward identities
The absolute integrated intensity of the single-phonon Raman peak at 1580
cm^{-1} is calculated for a clean graphene monolayer. The resulting intensity
is determined by the trigonal warping of the electronic bands and the
anisotropy of the electron-phonon coupling, and is proportional to the second
power of the excitation frequency. The main contribution to the process comes
from the intermediate electron-hole states with typical energies of the order
of the excitation frequency, contrary to what has been reported earlier. This
occurs because of strong cancellations between different terms of the
perturbation theory, analogous to Ward identities in quantum electrodynamics
Group theory for structural analysis and lattice vibrations in phosphorene systems
Group theory analysis for two-dimensional elemental systems related to
phosphorene is presented, including (i) graphene, silicene, germanene and
stanene, (ii) dependence on the number of layers and (iii) two stacking
arrangements. Departing from the most symmetric graphene space
group, the structures are found to have a group-subgroup relation, and analysis
of the irreducible representations of their lattice vibrations makes it
possible to distinguish between the different allotropes. The analysis can be
used to study the effect of strain, to understand structural phase transitions,
to characterize the number of layers, crystallographic orientation and
nonlinear phenomena.Comment: 24 pages, 3 figure
Raman-scattering study of the phonon dispersion in twisted bi-layer graphene
Bi-layer graphene with a twist angle \theta\ between the layers generates a
superlattice structure known as Moir\'{e} pattern. This superlattice provides a
\theta-dependent q wavevector that activates phonons in the interior of the
Brillouin zone. Here we show that this superlattice-induced Raman scattering
can be used to probe the phonon dispersion in twisted bi-layer graphene (tBLG).
The effect reported here is different from the broadly studied double-resonance
in graphene-related materials in many aspects, and despite the absence of
stacking order in tBLG, layer breathing vibrations (namely ZO' phonons) are
observed.Comment: 18 pages, 4 figures, research articl
Group Theory analysis of phonons in two-dimensional Transition Metal Dichalcogenides
Transition metal dichalcogenides (TMDCs) have emerged as a new two
dimensional materials field since the monolayer and few-layer limits show
different properties when compared to each other and to their respective bulk
materials. For example, in some cases when the bulk material is exfoliated down
to a monolayer, an indirect-to-direct band gap in the visible range is
observed. The number of layers ( even or odd) drives changes in space
group symmetry that are reflected in the optical properties. The understanding
of the space group symmetry as a function of the number of layers is therefore
important for the correct interpretation of the experimental data. Here we
present a thorough group theory study of the symmetry aspects relevant to
optical and spectroscopic analysis, for the most common polytypes of TMDCs,
i.e. , and , as a function of the number of layers. Real space
symmetries, the group of the wave vectors, the relevance of inversion symmetry,
irreducible representations of the vibrational modes, optical selection rules
and Raman tensors are discussed.Comment: 32 pages, 4 figure
Comparison of a retrotransposon-based marker with microsatellite markers for discriminating accessions of Vitis vinifera.
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Análise da diversidade genética em Stylosanthes guianensis utilizando marcadores RAPD.
O conhecimento da variabilidade genética e da relação entre diferentes acessos de Stylosanthes guianensis é importante para maximizar o uso dos recursos genéticos disponíveis. Este trabalho teve como objetivo avaliar a variabilidade genética em 20 acessos dessa espécie, pertencentes ao banco de germoplasma da Embrapa Gado de Corte, usando marcadores RAPD (DNA Polimórfico Amplificado ao Acaso). Foram selecionados 40 primers randômicos, que produziram um total de 210 bandas; destas, 82 polimórficas (39,05%). Os dados obtidos foram utilizados para gerar uma matriz de similaridade genética usando o coeficiente de Jaccard. A similaridade genética variou de 0,747 a 0,945, o que indicou uma variabilidade genética pouco acentuada entre os acessos estudados. Os acessos com menor similaridade genética foram SG01 e SG14. Os resultados das análises de agrupamento com os métodos UPGMA (Agrupamento com Média Aritmética Não Ponderada) e Tocher foram similares. Apesar da baixa variabilidade genética detectada entre os 20 acessos, estes foram separados em nove grupos distintos pelo método UPGMA e seis grupos pelo método de Tocher.bitstream/CNPGC-2009-09/12415/1/BP20.pd
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