PORTUGALIAE ELECTROCHIMICA ACTA Experimental Investigation of Nickel Electrodeposits Brightness in the Presence of Surfactants: Modeling, Optimization and Polarization Studies

Abstract Nickel coatings were obtained from Watts bath containing sodium dodecyl sulfate (SDS) or polyvinylpyrrolidone (PVP) surfactants by direct current plating. The influence of electrolysis parameters, temperature, current density, concentration of surfactants and pH on the nickel deposits brightness is investigated through a multiple linear regression model with interaction. The models obtained fitted very well the experimental data. ANOVA statistical analysis shows that all design factors are significant, and the brightness of nickel deposits obtained from bath containing PVP is more sensitive to the changes in the factors levels. The electrochemical behaviour of baths was discussed; the results revealed an inhibitive effect exerted by both SDS and PVP. We have also found that the brightness and the inhibition are well linked and directly proportional. In addition, the corrosion resistance of the nickel coatings was slightly improved, especially with PVP. Finally, the optimization analysis showed that PVP could efficiently and eco-friendly substitute SDS as an additive of nickel electroplating