13 research outputs found
Persistence of instanton connections in chemical reactions with time dependent rates
The evolution of a system of chemical reactions can be studied, in the
eikonal approximation, by means of a Hamiltonian dynamical system. The fixed
points of this dynamical system represent the different states in which the
chemical system can be found, and the connections among them represent
instantons or optimal paths linking these states. We study the relation between
the phase portrait of the Hamiltonian system representing a set of chemical
reactions with constant rates and the corresponding system when these rates
vary in time. We show that the topology of the phase space is robust for small
time-dependent perturbations in concrete examples and state general results
when possible. This robustness allows us to apply some of the conclusions on
the qualitative behavior of the autonomous system to the time-dependent
situation
Infinitely Many Stochastically Stable Attractors
Let f be a diffeomorphism of a compact finite dimensional boundaryless
manifold M exhibiting infinitely many coexisting attractors. Assume that each
attractor supports a stochastically stable probability measure and that the
union of the basins of attraction of each attractor covers Lebesgue almost all
points of M. We prove that the time averages of almost all orbits under random
perturbations are given by a finite number of probability measures. Moreover
these probability measures are close to the probability measures supported by
the attractors when the perturbations are close to the original map f.Comment: 14 pages, 2 figure