Global behavior of cosmological dynamics with interacting Veneziano ghost

In this paper, we shall study the dynamical behavior of the universe accelerated by the so called Veneziano ghost dark energy component locally and globally by using the linearization and nullcline method developed in this paper. The energy density is generalized to be proportional to the Hawking temperature defined on the trapping horizon instead of Hubble horizon of the Friedmann-Robertson-Walker (FRW) universe. We also give a prediction of the fate of the universe and present the bifurcation phenomenon of the dynamical system of the universe. It seems that the universe could be dominated by dark energy at present in some region of the parameter space.Comment: 8 pages, 7 figures, accepted for publication in JHE

Progress and perspective of interface design in garnet electrolyte-based all-solid-state batteries

Inorganic solid-state electrolytes (SSEs) are nonflammable alternatives to the commercial liquid-phase electrolytes. This enables the use of lithium (Li) metal as an anode, providing high-energy density and improved stability by avoiding unwanted liquid-phase chemical reactions. Among the different types of SSEs, the garnet-type electrolytes witness a rapid development and are considered as one of the top candidates to pair with Li metal due to their high ionic conductivity, thermal, and electrochemical stability. However, the large resistances at the interface between garnet-type electrolytes and cathode/anode are the major bottlenecks for delivering desirable electrochemical performances of all-solid-state batteries (SSBs). The electrolyte/anode interface also suffers from metallic dendrite formation, leading to rapid performance degradation. This is a fundamental material challenge due to the poor contact and wettability between garnet-type electrolytes with electrode materials. Here, we summarize and analyze the recent contributions in mitigating such materials challenges at the interface. Strategies used to address these challenges are divided into different categories with regard to their working principles. On one hand, progress has been made in the anode/garnet interface, such as the successful application of Li-alloy anode and different artificial interlayers, significantly improving interfacial performance. On the other hand, the desired cathode/garnet interface is still hard to reach due to the complex chemical and physical structure at the cathode. The common methods used are nanostructured cathode host and sintering additives for increasing the contact area. On the basis of this information, we present our views on the remaining challenges and future research of electrode/garnet interface. This review not only motivates the need for further understanding of the fundamentals, stability, and modifications of the garnet/electrode interfaces but also provides guidelines for the future design of the interface for SSB

N=2 supergravity models with stable de Sitter vacua

In the present talk I shall review the construction of N=2 supergravity models exhibiting stable de Sitter vacua. These solutions represent the first instance of stable backgrounds with positive cosmological constant in the framework of extended supergravities (N >=2). After briefly reviewing the role of de Sitter space--times in inflationary cosmology, I shall describe the main ingredients which were necessary for the construction of gauged N=2 supergravity models admitting stable solutions of this kind.Comment: Prepared for Workshop on the Quantum Structure of Spacetime and the Geometric Nature of Fundamental Interactions, Leuven, Belgium, September 13-19 200

Effective Activation of Strong C−Cl Bonds for Highly Selective Photosynthesis of Bibenzyl via Homo-Coupling

Carbon-carbon (C−C) coupling of organic halides has been successfully achieved in homogeneous catalysis, while the limitation, e.g., the dependence on rare noble metals, complexity of the metal-ligand catalylst and the poor catalyst stability and recyclability, needs to be tackled for a green process. The past few years have witnessed heterogeneous photocatalysis as a green and novel method for organic synthesis processes. However, the study on C−C coupling of chloride substrates is rare due to the extremely high bond energy of C−Cl bond (327 kJ mol−1). Here, we report a robust heterogeneous photocatalyst (Cu/ZnO) to drive the homo-coupling of benzyl chloride with high efficiency, which achieves an unprecedented high selectivity of bibenzyl (93 %) and yield rate of 92 % at room temperature. Moreover, this photocatalytic process has been validated for C−C coupling of 10 benzylic chlorides all with high yields. In addition, the excellent stability has been observed for 8 cycles of reactions. With detailed characterization and DFT calculation, the high selectivity is attributed to the enhanced adsorption of reactants, stabilization of intermediates (benzyl radicals) for the selective coupling by the Cu loading and the moderate oxidation ability of the ZnO support, besides the promoted charge separation and transfer by Cu species

Geometry of lines and degeneracy loci of morphisms of vector bundles

Corrado Segre played a leading role in the foundation of line geometry. We survey some recent results on degeneracy loci of morphisms of vector bundles where he still is of profound inspiration.Comment: 10 pages. To appear in the proceedings of the conference "Homage to Corrado Segre

Generation of the Baryon Asymmetry of the Universe within the Left--Right Symmetric Model

Fermions scattering off first-order phase transition bubbles, in the framework of $SU(2)_L\otimes SU(2)_R\otimes U(1)$ models, may generate the Baryon Asymmetry of the Universe (BAU), either at the $LR$-symmetry-breaking scale, or at the weak scale. In the latter case, the baryon asymmetry of the Universe is related to CP violation in the $K_0$--$\bar K_0$ system.Comment: 17 pages, CERN--TH 6747/92, ULB--TH--07/92, UAB-FT-298/9

Advanced Li₂S/Si Full Battery Enabled by TiN Polysulfide Immobilizer

Lithium sulfide (Li2S) is a promising cathode material with high capacity, which can be paired with nonlithium metal anodes such as silicon or tin so that the safety issues caused by the Li anode can be effectively avoided. However, the Li2S full cell suffers from rapid capacity degradation due to the dissolution of intermediate polysulfides. Herein, a Li2S/Si full cell is designed with a Li2S cathode incorporated by titanium nitride (TiN) polysulfide immobilizer within parallel hollow carbon (PHC). This full cell delivers a high initial reversible capacity of 702 mAh gLi2S−1 (1007 mAh gsulfur−1) at 0.5 C rate and excellent cyclability with only 0.4% capacity fade per cycle over 200 cycles. The long cycle stability is ascribed to the strong polysulfide anchor effect of TiN and highly efficient electron/ion transport within the interconnected web‐like architecture of PHC. Theoretical calculations, self‐discharge measurements, and anode stability experiments further confirm the strong adsorption of polysulfides on the TiN surface. The present work demonstrates that the flexible Li2S cathode and paired Si anode can be used to achieve highly efficient Li‐S full cells