Properties and Performance of High-Purity Thermal Barrier Coatings

It has been found that reducing the level of impurity oxides (particularly SiO2 and Al2O3) in 7YSZ, from about 0.2 wt% to below 0.1 wt% raises the sintering resistance and the phase stability of plasma-sprayed coatings. The implications for the usage of these coatings at elevated temperatures are examined. It is concluded that using relatively high-purity powder of this type is likely to confer substantial benefits in terms of the thermomechanical stability of the coatings under service conditions

Effect of Heat Treatment on Pore Architecture and Associated Property Charges in Plasma Sprayed TBCs

Plasma sprayed TBCs exhibit many interlamellar pores, voids and microcracks. These microstructural features are primarily responsible for the low global stiffnesses and the low thermal conductivities commonly exhibited by such coatings. The pore architecture thus has an important influence on such thermophysical properties. In the present work, the effect of heat treatment (at temperatures up to 1400C, for times of up to 100 hours) and coating purity on the pore architecture in detached YSZ top coats has been characterised by Mercury Intrusion Porosimetry (MIP) and BJH Analysis. While the overall porosity level (measured by densitometry) remained relatively unaffected (at around 10-12%) after the heat treatments concerned, there were substantial changes in the pore size distribution and the (inter-connected) specific surface area, although these changes occurred less rapidly with coatings produced using high purity powders. Fine pores (<~50 nm) rapidly disappeared, while the specific surface area dropped dramatically, particularly at high treatment temperatures (>~1300C). These changes are thought to be associated with improved inter-splat bonding and increased contact area, leading to disappearance of much of the very fine inter-splat porosity. These microstructural changes are reflected in sharply increased stiffness and thermal conductivity. Measured thermal conductivity data are compared with predictions from a recently-developed analytical model [1], using the deduced inter-splat contact area results as input parameters. Good agreement is obtained, suggesting that the model captures the main geometrical effects and the porosity architecture measurements reflect the most significant microstructural changes. REF.1. Golosnoy, IO, Tsipas, SA and Clyne, TW, An Analytical Model For Simulation Of Heat Flow In Plasma Sprayed Thermal Barrier Coating, J. Thermal Spray Techn., 14 (2005) 205-214

Continuous-Variable Quantum State Transfer with Partially Disembodied Transport

We propose a new protocol of implementing continuous-variable quantum state transfer using partially disembodied transport. This protocol may improve the fidelity at the expense of the introduction of a semi-quantum channel between the parties, in comparison with quantum teleportation using the same strength of entanglement. Depending on the amount of information destroyed in the measurement, this protocol may be regarded as a teleportation protocol (complete destruction of input state), or as a $1\to M$ cloning protocol (partial destruction), or as a direct transmission (no destruction). This scheme can be straightforwardly implemented with the experimentally accessible setup at present.Comment: 4 pages, to appear in Phys. Rev. Let

Complete classification of 1D gapped quantum phases in interacting spin systems

Quantum phases with different orders exist with or without breaking the symmetry of the system. Recently, a classification of gapped quantum phases which do not break time reversal, parity or on-site unitary symmetry has been given for 1D spin systems in [X. Chen, Z.-C. Gu, and X.-G. Wen, Phys. Rev. B \textbf{83}, 035107 (2011); arXiv:1008.3745]. It was found that, such symmetry protected topological (SPT) phases are labeled by the projective representations of the symmetry group which can be viewed as a symmetry fractionalization. In this paper, we extend the classification of 1D gapped phases by considering SPT phases with combined time reversal, parity, and/or on-site unitary symmetries and also the possibility of symmetry breaking. We clarify how symmetry fractionalizes with combined symmetries and also how symmetry fractionalization coexists with symmetry breaking. In this way, we obtain a complete classification of gapped quantum phases in 1D spin systems. We find that in general, symmetry fractionalization, symmetry breaking and long range entanglement(present in 2 or higher dimensions) represent three main mechanisms to generate a very rich set of gapped quantum phases. As an application of our classification, we study the possible SPT phases in 1D fermionic systems, which can be mapped to spin systems by Jordan-Wigner transformation.Comment: 15 pages, 3 figure

Tuning and Locking the Localized Surface Plasmon Resonances of CuS (Covellite) Nanocrystals by an Amorphous CuPdxS Shell

[Image: see text] We demonstrate the stabilization of the localized surface plasmon resonance (LSPR) in a semiconductor-based core–shell heterostructure made of a plasmonic CuS core embedded in an amorphous-like alloyed CuPd(x)S shell. This heterostructure is prepared by reacting the as-synthesized CuS nanocrystals (NCs) with Pd(2+) cations at room temperature in the presence of an electron donor (ascorbic acid). The reaction starts from the surface of the CuS NCs and proceeds toward the center, causing reorganization of the initial lattice and amorphization of the covellite structure. According to density functional calculations, Pd atoms are preferentially accommodated between the bilayer formed by the S–S covalent bonds, which are therefore broken, and this can be understood as the first step leading to amorphization of the particles upon insertion of the Pd(2+) ions. The position and intensity in near-infrared LSPRs can be tuned by altering the thickness of the shell and are in agreement with the theoretical optical simulation based on the Mie–Gans theory and Drude model. Compared to the starting CuS NCs, the amorphous CuPd(x)S shell in the core–shell nanoparticles makes their plasmonic response less sensitive to a harsh oxidation environment (generated, for example, by the presence of I(2))

Metal-insulator transition in a multilayer system with a strong magnetic field

We study the Anderson localization in a weakly coupled multilayer system with a strong magnetic field perpendicular to the layers. The phase diagram of 1/3 flux quanta per plaquette is obtained. The phase diagram shows that a three-dimensional quantum Hall effect phase exists for a weak on-site disorder. For intermediate disorder, the system has insulating and normal metallic phases separated by a mobility edge. At an even larger disorder, all states are localized and the system is an insulator. The critical exponent of the localization length is found to be $\nu=1.57\pm0.10$.Comment: Latex file, 3 figure

Quantum codes give counterexamples to the unique pre-image conjecture of the N-representability problem

It is well known that the ground state energy of many-particle Hamiltonians involving only 2-body interactions can be obtained using constrained optimizations over density matrices which arise from reducing an N-particle state. While determining which 2-particle density matrices are "N- representable" is a computationally hard problem, all known extreme N-representable 2-particle reduced density matrices arise from a unique N-particle pre-image, satisfying a conjecture established in 1972. We present explicit counterexamples to this conjecture through giving Hamiltonians with 2-body interactions which have degenerate ground states that cannot be distinguished by any 2-body operator. We relate the existence of such counterexamples to quantum error correction codes and topologically ordered spin systems.Comment: 4 pages, 1 figur