54,365 research outputs found

    How does the chain extension of poly (acrylic acid) scale in aqueous solution? A combined study with light scattering and computer simulation

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    This work adresses the question of the scaling behaviour of polyelectrolytes in solution for a realistic prototype: We show results of a combined experimental (light scattering) and theoretical (computer simulations) investigation of structural properties of poly (acrylic acid) (PAA). Experimentally, we determined the molecular weight (M_W) and the hydrodynamic radius (R_H) by static light scattering for six different PAA samples in aqueous NaCl-containing solution (0.1-1 mol/L) of polydispersity D_P between 1.5 and 1.8. On the computational side, three different variants of a newly developed mesoscopic force field for PAA were employed to determine R_H for monodisperse systems of the same M_W as in the experiments. The force field effectively incorporates atomistic information and one coarse-grained bead corresponds to one PAA monomer. We find that R_H matches with the experimental data for all investigated samples. The effective scaling exponent for R_H is found to be around 0.55, which is well below its asymptotic value for good solvents. Additionally, data for the radius of gyration (R_G) are presented.Comment: 17 pages, 3 figures, submitted to Macromolecule

    Hadron annihilation into two photons and backward dVCS in the scaling regime of QCD

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    We study the scaling regime of hadron-(anti)-hadron annihilation into a deeply virtual photon and a real photon, H anti-H -> gamma^* gamma, and deep backward virtual Compton scattering, gamma^* H -> H gamma. We advocate that there is a kinematical region where the scattering amplitude factorizes into a short-distance matrix element and a long-distance dominated object: a transition distribution amplitude which describes the hadron to photon transition.Comment: 4 pages, 1 .eps figure, to be published in Phys. Rev. D Rapid Com

    h/2eh/2e--Oscillations for Correlated Electron Pairs in Disordered Mesoscopic Rings

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    The full spectrum of two interacting electrons in a disordered mesoscopic one--dimensional ring threaded by a magnetic flux is calculated numerically. For ring sizes far exceeding the one--particle localization length L1L_1 we find several h/2eh/2e--periodic states whose eigenfunctions exhibit a pairing effect. This represents the first direct observation of interaction--assisted coherent pair propagation, the pair being delocalized on the scale of the whole ring.Comment: 4 pages, uuencoded PostScript, containing 5 figures

    Unlocking the Potential of Flexible Energy Resources to Help Balance the Power Grid

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    Flexible energy resources can help balance the power grid by providing different types of ancillary services. However, the balancing potential of most types of resources is restricted by physical constraints such as the size of their energy buffer, limits on power-ramp rates, or control delays. Using the example of Secondary Frequency Regulation, this paper shows how the flexibility of various resources can be exploited more efficiently by considering multiple resources with complementary physical properties and controlling them in a coordinated way. To this end, optimal adjustable control policies are computed based on robust optimization. Our problem formulation takes into account power ramp-rate constraints explicitly, and accurately models the different timescales and lead times of the energy and reserve markets. Simulations demonstrate that aggregations of select resources can offer significantly more regulation capacity than the resources could provide individually.Comment: arXiv admin note: text overlap with arXiv:1804.0389

    Collective cyclotron motion of the relativistic plasma in graphene

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    We present a theory of the finite temperature thermo-electric response functions of graphene, in the hydrodynamic regime induced by electron-electron collisions. In moderate magnetic fields, the Dirac particles undergo a collective cyclotron motion with a temperature-dependent relativistic cyclotron frequency proportional to the net charge density of the Dirac plasma. In contrast to the undamped cyclotron pole in Galilean-invariant systems (Kohn's theorem), here there is a finite damping induced by collisions between the counter-propagating particles and holes. This cyclotron motion shows up as a damped pole in the frequency dependent conductivities, and should be readily detectable in microwave measurements at room temperature. We also discuss the large Nernst effect to be expected in graphene.Comment: 16 pages, 2 figures; calculation of giant Nernst effect in graphene adde
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