17 research outputs found

    Arabidopsis Retinoblastoma-related and Polycomb group proteins: cooperation during plant cell differentiation and development

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    Retinoblastoma-related (RBR) is the plant homologue of pRb, a tumour suppressor. This review discusses the molecular functions of RBR during plant development and in the control of the cell cycle, with emphasizing on its cooperation with chromatin-modifying factor

    A CONCISE SYNTHESIS OF SOLAMIN AND CIS-SOLAMIN, MONO-THF ACETOGENINS FROM ANNONA MURICATA

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    A concise total synthesis of solamin (1) and cis-solamin (2) was performed using an epoxy alcohol (11) as a versatile chiral building block for synthesizing the stereoisomers of the mono-THF annonaceous acetogenins.ArticleHETEROCYCLES. 78(9):2369-2376 (2009)journal articl

    Trust, Cohesion, and Cooperation After Early Versus Late Trust Violations in Two-Person Exchange

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    We examine how the timing of trust violations affects cooperation and solidarity, including trust and relational cohesion. Past studies that used repeated Prisoner’s Dilemmas suggest that trust violations are more harmful when they occur in early rather than later interactions. We argue that this effect of early trust violations depends on cultural and individual differences in generalized trust. A laboratory study from high- and low-trust cultures (the United States vs. Japan) supported our claim. First, early trust violations were more harmful than late trust violations, but only for Americans; the pattern reversed for Japanese. Second, these patterns were mediated by individual differences in generalized trust. Finally, generalized trust also moderated the effect of trust violations in the United States but not Japan. By demonstrating that generalized trust is not only lower but also less important in low-trust cultures, our research advances our understanding of how culture affects the development of solidarity in exchange relations

    Weakly Bound Dimer of a Diaryloxygermylene Derived from a tBuPh2Si-Substituted 2,2′-Methylenediphenol

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    Novel diaryloxygermylenes have been prepared by the reaction of Lappert’s germylene, Ge[N(SiMe3)2]2, with 2,2′-methylenediphenols bearing different substituents. The bulkiness of the substituents on the ortho positions of the phenolic oxygen (6 and 6′ positions) affects the structure of the products both in the solid-state and in solution. When the ortho substituents are SitBuPh2, the diaryloxygemylene crystalizes as a weakly bound dimer with intermolecular Ge…O distances of ca. 3.0 Å and exists as a monomer in solution. In contrast, the germylene with SiMePh2 groups as the ortho substituents form a tightly bound dimer featuring a Ge2O2 rhombus with cis-oriented terminal aryloxy groups in the crystalline state, which is confirmed to be maintained in solution through the VT (variable-temperature)-1H NMR studies. To the best of our knowledge, the former dimeric structure is unprecedented in the family of dioxytetrylenes
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