177 research outputs found
Nanofibrous carbon with herringbone structure as an effective catalyst of the H2S selective oxidation
Synthesis of Ni-based catalysts by hexamethylenetetramine-nitrates solution combustion method for co-production of hydrogen and nanofibrous carbon from methane
It was shown that hexamethylenetetramine (HMT)is a new effective fuel for single-step solutions combustion synthesis (SCS)of supported Ni catalysts for methane decomposition into hydrogen and nanofibrous carbon. Several generalized chemical equations reflecting different ideas about combustion of the HMT−Ni(NO 3 ) 2 −Cu(NO 3 ) 2 −Al(NO 3 ) 3 −H 2 O system have been derived. On the basis of those equations the adiabatic combustion temperature (T ad )and the amount of gaseous products (n g )have been calculated depending on the ignition temperature (T 1 ), water content (m), excess fuel coefficient (φ), and the composition of the obtained solid product. The calculations have shown that T ad , depending on m and φ, changes from hundreds to thousands of degrees Kelvin. Increase of Al 2 O 3 content in the catalyst up to 0.6 increases T ad by hundreds of degrees, and that increase of the Ni:NiO ratio up to 0.5 lowers T ad by tens of degrees. Three samples of the supported unreduced 0.97NiO/0.03Al 2 O 3 catalyst were successfully prepared with the help of the SCS method using HMT as the fuel at φ=0.7. Those samples, obtained at reaction mixture preliminary heating rates V = 1, 10, 15 K/min were characterised using XRD, TEM, and SEM, and further tested in a pure methane decomposition reaction (100 L CH4 /h/g cat , 823К, 1 bar). Nanoparticles of metal Ni were found in the SCS products, in contrast to cases when other types of fuel were used with
Fidelity of holonomic quantum computations in the case of random errors in the values of control parameters
We investigate the influence of random errors in external control parameters
on the stability of holonomic quantum computation in the case of arbitrary
loops and adiabatic connections. A simple expression is obtained for the case
of small random uncorrelated errors. Due to universality of mathematical
description our results are valid for any physical system which can be
described in terms of holonomies. Theoretical results are confirmed by
numerical simulations.Comment: 7 pages, 3 figure
Chaos assisted instanton tunneling in one dimensional perturbed periodic potential
For the system with one-dimensional spatially periodic potential we
demonstrate that small periodic in time perturbation results in appearance of
chaotic instanton solutions. We estimate parameter of local instability, width
of stochastic layer and correlator for perturbed instanton solutions.
Application of the instanton technique enables to calculate the amplitude of
the tunneling, the form of the spectrum and the lower bound for width of the
ground quasienergy zone
Velocity field distributions due to ideal line vortices
We evaluate numerically the velocity field distributions produced by a
bounded, two-dimensional fluid model consisting of a collection of parallel
ideal line vortices. We sample at many spatial points inside a rigid circular
boundary. We focus on ``nearest neighbor'' contributions that result from
vortices that fall (randomly) very close to the spatial points where the
velocity is being sampled. We confirm that these events lead to a non-Gaussian
high-velocity ``tail'' on an otherwise Gaussian distribution function for the
Eulerian velocity field. We also investigate the behavior of distributions that
do not have equilibrium mean-field probability distributions that are uniform
inside the circle, but instead correspond to both higher and lower mean-field
energies than those associated with the uniform vorticity distribution. We find
substantial differences between these and the uniform case.Comment: 21 pages, 9 figures. To be published in Physical Review E
(http://pre.aps.org/) in May 200
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