EPR study of the Jahn-Teller effect of Cu2+ in ZnTiF6·6H20

The 34-GHz EPR spectrum of Cu2+ in ZnTiF6·6H20 shows a Jahn-Teller effect with a transition from a single-line spectrum at high temperatures to a multiline anisotropic spectrum. The transition temperature on cooling varied with Cu concentration from 172 K for a sample containing 0.2 at.% Cu to roughly 90 K for a 46-at. % Cu sample. For dilute samples, the single-line spectrum was isotropic at 300 K with g =2.223±0.005, but showed axial symmetry about the trigonal axis at 180 K with gj1 =2.226±0.005 and g~ =2.223±0.005. At 4.2 K, a "static" Jahn-Teller effect was observed with six axially symmetric Cu2+ spectra, each with g 11 =2.470±0.005, g1 =2.100±0.005, I A 11 I ~ I 06 X 10- 4 em -I, and I A 1 I ~30 X 10- 4 em - I. The z axis of these spectra was found to lie along the fourfold axes of two cubes with a common [Ill] axis, rotated by 40"±2" with respect to each other about this axis. Analysis of the 4.2-K data leads to the values q~O. 50 for the Ham reduction factor and K~O. 26 for the Fenni contact parameter, with A uA 1 < 0. An activation energy of about 100 cm-1 was deduced from the gradual increase of the anisotropy of the spectrum on cooling in the low-temperature region

TMAV: Temporal Motionless Analysis of Video using CNN in MPSoC

Analyzing video for traffic categorization is an important pillar of Intelligent Transport Systems. However, it is difficult to analyze and predict traffic based on image frames because the representation of each frame may vary significantly within a short time period. This also would inaccurately represent the traffic over a longer period of time such as the case of video. We propose a novel bio-inspired methodology that integrates analysis of the previous image frames of the video to represent the analysis of the current image frame, the same way a human being analyzes the current situation based on past experience. In our proposed methodology, called IRON-MAN (Integrated Rational prediction and Motionless ANalysis), we utilize Bayesian update on top of the individual image frame analysis in the videos and this has resulted in highly accurate prediction of Temporal Motionless Analysis of the Videos (TMAV) for most of the chosen test cases. The proposed approach could be used for TMAV using Convolutional Neural Network (CNN) for applications where the number of objects in an image is the deciding factor for prediction and results also show that our proposed approach outperforms the state-of-the-art for the chosen test case. We also introduce a new metric named, Energy Consumption per Training Image (ECTI). Since, different CNN based models have different training capability and computing resource utilization, some of the models are more suitable for embedded device implementation than the others, and ECTI metric is useful to assess the suitability of using a CNN model in multi-processor systems-on-chips (MPSoCs) with a focus on energy consumption and reliability in terms of lifespan of the embedded device using these MPSoCs

Probing the CP-violating light neutral higgs in the charged higgs decay at the LHC

The CP-violating MSSM allows existence of a light neutral Higgs boson (MH150 GeV) in the CPX scenario in the low tan &#946; (5)region, which could have escaped the LEP searches due to a strongly suppressed H1ZZ coupling. This parameter space corresponds to a relatively light H+ (MH+&lt;Mt), which is predicted to decay dominantly into the WH1 channel. Thus one expects to see a striking tt- signal at the LHC, where one of the top quarks decays into the bbb-W channel, via t&#8594;bH&#177;, H&#177;&#8594;WH1 and H1&#8594;bb-. The characteristic correlation between the bb-,bb-W and bbb-W invariant mass peaks is expected to make this signal practically free of the SM background. Our parton level Monte Carlo simulation yields upto 5000 events, for L=30 fb-1, over the parameter space of interest, after taking into account the b-tagging efficiency for three or more b-tagged jets

EPR and Magnetic Studies on y:bis(N -Methyl Salicylaldimine) Copper(II)

EPR and magnetic studies on single crystals of the dimeric copper (II) compound y: his (N-methyl salicylaldimine) Cu(II) down to 1.5 K reveal that each Cu(II) dimer is ferromagnetically exchange coupled having negligible interdimer exchange interaction. The magnetic properties are best described with C4v ligand field symmetry around each Cu(II) ion. The principal axes of the susceptibility and the g-tensor are not strictly coincident at low temperature. EPR und magnetische Untersuchungen an Einkristallen der dimeren Kupfer (II)-Verbindung y: bis-(N-methylsalizylaldimin)- Cu(II) his herab zu 1,5 K zeigen, daB jedes Cu(II)-Dimer ferromagnetisch austauschgekoppelt ist und eine vernachlassigbare interdimere Austauschwechselwirkung aufweist. Die magnetischen Eigenschaften lassen sich am besten mit C4v-Ligandensymmetrie urn jedes Cu(II)-Ion beschreiben. Die Hauptachsen des Suszeptibilitats- und g-Tensoren sind nicht genau koinzident bei tiefen Temperature

Facile method for trimethylsilylation of alcohols using hexamethyldisilazane and ammonium thiocyanate under neutral conditions

A highly efficient method for trimethylsilylation of primary, secondary, tertiary, allylic, and a variety of sugar-derived alcohols using hexamethyldisilazane in the presence of a catalytic amount of ammonium thiocyanate under neutral conditions is reported

Jahn-Teller EPA spectra of Cu2 + in MgSif6.6H20

The 34 GHz EPR spectrum ofCu2+ in MgSiF6-6H20 showed a "static" Jahn-Teller effect at 4.2 K with two inequivalent Jahn- Teller sites per unit cell. The six axially symmetric sets of Cu2+ lines had their z axes parallel to the three tetragonal axes of two cubes, which were rotated by approximately 40" with respect to each other about a common (Ill) axis, which is the crystal c axis. The measured spin-Hamiltonian parameters at 4.2 K for each set of lines were g11 = 2.47 ± 0.01, g1 = 2.10 ± 0.01 , and lA 11 1 = (110 ± 3)X 10- 4 em- •. There was a gradual decrease in the anisotropy of the spectrum on warming the crystal, with a single, nearly isotropic line being observed above 220 K. At 270 K the spectrum had axial symmetry about the c axis with Kn = 2.23 ± 0.01 and g~ = 2.25 ± 0.01 . The temperature evolution of the spectrum was interpreted in terms of a Boltzmann distribution over inequivalent distorted Jahn-Teller configurations, with one potential well lowered by an amount L1:::::: I 05 em- 1 below the other two

Observation of the cubic-field splitting of an excited S = 2 manifold in a cubic copper tetramer

EPR measurements on single crystals of Cu40Cl6(triphenylphosphine oxide)4 at liquid helium temperatures in the frequency ranges 14-17 and 34-35 GHz were fitted to a simple cubicS= 2 spin Hamiltonian with g = 2.10 ± 0.01 and a zero-field splitting of(0.53 ± 0.01) em - 1 • From the decrease in intensity of the S = 2 spectrum on cooling below 4.2 K and the absence of an S = 1 spectrum, the S = 2 manifold was deduced to lie ( 14 ± 1) em- 1 above a nonmagnetic ground state. The EPR results are used as a test of the various theories developed to explain the magnetic susceptibility of copper tetramer

Association between Helicobacter pylori infection and increased risk of typhoid fever

Helicobacter pylori infection has been reported to increase the risk of cholera. This nested case-control study was conducted to determine whether H. pylori infection is associated with occurrence of typhoid fever. Eighty-three case subjects of culture-proven typhoid fever were identified through a 1-year surveillance of subjects aged 0-40 years in an urban slum. Two age- and sex-matched neighborhood control subjects were concurrently selected for each case subject. Serum anti-H. pylori immunoglobulin G antibodies were measured in case and neighborhood control subjects. For determining other risk factors, 2 additional community control subjects per case were selected. There was a significant association between the presence of serum anti-H. pylori immunoglobulin G antibodies and typhoid fever (adjusted odds ratio, 2.03; 95% confidence interval, 1.02-4.01). Illiteracy, being part of a nuclear family, nonuse of soap, and consumption of ice cream were also associated with a significantly greater risk of typhoid fever. This study provides the first empiric evidence that H. pylori infection is associated with an increased risk of typhoid fever

Prevalence and Genotypes of Mycobacterium Avium Subspecies Paratuberculosis in Large Ruminants of Eastern Uttar Pradesh, North India

Uttar Pradesh is the fourth largest, most populous and leading milk and meat producing state in India. Despite the huge livestock population, information on the status of paratuberculosis homogeneity and heterogeneity of Mycobacterium avium subspecies paratuberculosis (MAP) isolates of eastern Uttar Pradesh is non-existent. Present study was aimed to estimate the presence of MAP in large ruminants (Cattle and Buffaloes) of eastern Uttar Pradesh. A total 108 fecal samples were collected from farmer's herds of large ruminants (cattle and buffaloes) from different geographical regions (Chandauli, Mughalsarai, Gazipur, and Naugarh) of eastern Uttar Pradesh and screened for the presence of MAP infection using microscopic examination, direct IS900 PCR and culture on Herrold egg yolk (HEY) medium. The isolates recovered on HEY medium were subjected to molecular identification and genotyping using IS900 PCR and IS1311 PCR-REA method, respectively. Of the 108 fecal samples, 25 (23.14%) and 11 (10.18%) samples were positive for the presence of acid-fast bacilli and growth on HEY medium, respectively. Species-wise, 17.5, 7.5% and 26.5, 11.7% fecal samples from cattle and buffaloes were found positive for the presence of acid-fast bacilli and growth on HEY medium, respectively. Isolates recovered on HEY medium with mycobactin J were positive for IS900 sequence and genotyped as Bison Type using IS1311 PCR-REA method. Present study is the first report on the presence of MAP infection and ‘Bison Type' genotype of MAP in eastern Uttar Pradesh. These findings will be useful for the intervention of effective control measures in order to reduce the prevalence of MAP infection in domestic livestock species and prevent its spread to the human population in the regions

High-Tc superconductor YBa2Cu307-.5 studied by positron annihilation

We have measured the positron-lifetime and the Doppler-broadening spectra in the hightemperature superconductor YBa2Cu30 7 - 6 as a function of temperature between 77 and 295 K. Positron-lifetime and Doppler-broadening data show new features in the superconducting phase. These results are interpreted in terms of positron localization in lattice distortions and posi~ron surface states