Impact of Weft Yarn Density and Core-yarn Fibre Composition on Tensile Properties, Abrasion Resistance and Air Permeability of Denim Fabrics

Characteristics and serviceability of denim fabrics have undergone major changes. Nowadays denim is commonly used for casual wear. Durability and comfort are important parameters for consumers when choosing a denim garment. Therefore, in this study, abrasion resistance, tear and tensile properties of core–spun yarns and air permeability of denim fabrics with different weft yarns per centimetre and fibre content were analysed. The test results showed that weft yarns per centimetre influences fabric air permeability negatively but abrasion resistance increases. Higher weft yarns per centimetre influences fabric air permeability negatively but abrasion resistance increases. Polyester, elastane, modal, viscose and Lycra T400 were used in the core of weft yarn to analyse the impact of those fibres on the durability and comfort properties. Elastane is used to add stretchability to the fabric, which provides comfort to the wearer. The higher the elastomeric fibre content in the fabric, the greater is its elasticity; however, the tensile properties of the woven fabric decrease. The tear strength of the fabric was increased by the presence of the polyester fibre in the core

A method for producing conductive graphene biopolymer nanofibrous fabrics by exploitation of an ionic liquid dispersant in electrospinning

Owing to its high conductivity, graphene has been incorporated into polymeric nanofibers to create advanced materials for flexible electronics, sensors and tissue engineering. Typically, these graphene-based nanofibers are prepared by electrospinning synthetic polymers, whereas electrospun graphene-biopolymer nanofibers have been rarely reported due to poor compatibility of graphene with biopolymers. Herein, we report a new method for the preparation of graphene-biopolymer nanofibers using the judicious combination of an ionic liquid and electrospinning. Cellulose acetate (CA) has been used as the biopolymer, graphene oxide (GO) nanoparticles as the source of graphene and 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) as the ionic liquid (IL) to create CA-[BMIM]Cl-GO nanofibers by electrospinning for the first time. Moreover, we developed a new route to convert CA-[BMIM]Cl-GO nanofibers to reduced GO nanofibers using hydrazine vapor under ambient conditions to enhance the conductivity of the hybrid nanofibers. The graphene sheets were shown to be uniformly incorporated in the hybrid nanofibers and only 0.43 wt% of GO increase the conductivity of CA-[BMIM]Cl nanofibers by more than four orders of magnitude (from 2.71× 10−7 S/cm to 5.30 × 10−3 S/cm). This ultra-high enhancement opens up a new route for conductive enhancement of biopolymer nanofibers to be used in smart (bio) electronic devices

Thermal Analyses of Blends of Hyperbranched Linear Low-density Polyethylene (LLDPE) with High-density Polyethylene and LLDPE Prepared by Dissolving Method

Blends of high-density polyethylene (HDPE), moderate and hyper-branched LLDPEs (LLDPE and HbPE, respectively) have attained widespread commercial applications, though the understanding of the mechanical and melt-flow properties of such blends has been handicapped by the absence of a consensus concerning the degrees of mixing of the components. Moreover, usually the blends are obtained by melt blending, which may not ensure the initial homogeneity of the components. In our work the mixtures were prepared by dissolving the conventional LLDPE having branching content 7.2&nbsp;wt% with HbPE with comonomer content 17.8&nbsp;wt% in xylene at 130&nbsp;&deg;C and stirring for 2 hours. The same procedure was applied for the blending of HDPE with HbPE. After dissolving the mixtures were cooled in liquid nitrogen and after that freeze dried in vacuum line. The ratio of components in the blends was varied. Differential scanning calorimetry has been used to investigate the miscibility and thermal behavior of the blends. For this purpose isothermal and non-isothermal treatment of prepared blends were conducted. By preliminary study the double melting peaks in non-isothermal endotherms have been observed in all the studied blends. The presence of two peaks in DSC scan can be attributed to the formation of separated crystals from both the high density/linear low density and highly branched components. However, certain limited degree of co-crystallization is detected in all the LLDPE/HbPE blends and HDPE/HbPE blend rich in HbPE component.http://dx.doi.org/10.5755/j01.ms.17.3.589</p

Influence of hollow glass microspheres on the mechanical and physical properties and cost of particle reinforced polymer composites

Abstract. The goal of the study was to find a cost-effective composition of a particle reinforced composite that is light in weight but has sufficient mechanical properties. The matrix of the particulate composite is unsaturated polyester resin that is reinforced with alumina trihydrate particles. Part of the alumina trihydrate proportion was replaced with hollow glass microspheres to reduce weight and save costs. In order to find out the influence of the light filler on the physical and mechanical properties of composites, materials with different percentages of the light filler were prepared. Test specimens were cut from moulded sheets that were fabricated with vacuum assisted extruder. Tensile strength, indentation hardness measured with a Barcol impressor, and density were determined. Based on the experimental data a multi-criteria optimization problem was formulated and solved to find the optimal design of the material. Artificial neural networks and a hybrid genetic algorithm were used. The optimal solution is given as a Pareto curve to represent the distinction between the density and selected mechanical properties of the composite material. The composite material filled with 6% hollow glass microspheres showed 3% loss in the tensile strength and 26% loss in the surface hardness compared to the composition without the filler. The weight decreased by 13% compared with the initial composition. The addition of hollow glass microspheres did not lower the net value of the material, it increased 7%

Effect of Electrode Type on Electrospun Membrane Morphology Using Low-Concentration PVA Solutions

Electrospun polymer nanofiber materials have been studied as basic materials for various applications. Depending on the intended use of the fibers, their morphology can be adjusted by changing the technological parameters, the properties of the spinning solutions, and the combinations of composition. The aim of the research was to evaluate the effect of electrode type, spinning parameters, polymer molecular weight, and solution concentration on membranes morphology. The main priority was to obtain the smallest possible fiber diameters and homogeneous electrospun membranes. As a result, five electrode types were selected, the lowest PVA solution concentration for stable spinning process was detected, spinning parameters for homogenous fibers were obtained, and the morphology of electrospun fiber membranes was analyzed. Viscosity, conductivity, pH, and density were evaluated for PVA polymers with five different molecular weights (30&ndash;145 kDa) and three concentration solutions (6, 8, and 10 wt.%). The membrane defects and fiber diameters were compared as a function of molecular weight and electrode type. The minimum concentration of PVA in the solution allowed more additives to be added to the solution, resulting in thinner diameters and a higher concentration of the additive in the membranes. The molecular weight, concentration, and electrode significantly affected the fiber diameters and the overall quality of the membrane

Electrochemical Evaluation of Directly Electrospun Carbide-Derived Carbon-Based Electrodes in Different Nonaqueous Electrolytes for Energy Storage Applications

This study focuses on the electrochemical behavior of thin-layer fibrous carbide-derived carbon (CDC) electrospun electrodes in commercial and research and development stage organic-solvent and ionic liquid (IL) based electrolytes. The majority of earlier published works stated various electrolytes with asymmetric cells of powder-based pressure-rolled (PTFE), or slurry-cast electrodes, were significantly different from the presented CDC-based fibrous spun electrodes. The benefits of the fibrous structure are relatively low thickness (20 &micro;m), flexibility and mechanical durability. Thin-layered durable electrode materials are gaining more interest and importance in mechanically more demanding applications such as the space industry and in wearable devices, and need to achieve a targeted balance between mechanical, electrical and electrochemical properties. The existing commercial electrode technologies lack compatibility in such applications due to their limited mechanical properties and high cost. The test results showed that the widest potential window dU &le; 3.5 V was achieved in 1.5 M 1-ethyl-3-methylimidazoliumbis(trifluoromethyl-sulfonyl)imide (EMIm-TFSI) solution in acetonitrile (ACN). Gravimetric capacitance reached 105.6 F g&minus;1 for the positively charged electrode. Cycle-life results revealed stable material capacitance and resistance over 3000 cycles

Synthesis and Investigation of Thermo-Induced Gelation of Partially Cross-Linked Poly-2-isopropyl-2-oxazoline in Aqueous Media

Water-soluble, partially cross-linked poly-2-isopropyl-2-oxazoline combining the properties of chemical and physical gels was synthesized by a two-step procedure. Thermally induced sol-gel transition in its aqueous solution was studied by rheology, light scattering, and turbidimetry. It was demonstrated that the synthesized product is bimodal; it consists of linear and cross-linked components. The cross-linked components are responsible for the gelation, while the linear ones abate the viscosity growth. Heating the solution above the phase transition temperature leads to the self-assembly of the particles into a physical gel. The combination of chemical and physical cross-linking was found to be a prospective route for thermosensitive gel development

Antibacterial and Antiviral Effects of Ag, Cu and Zn Metals, Respective Nanoparticles and Filter Materials Thereof against Coronavirus SARS-CoV-2 and Influenza A Virus

Due to the high prevalence of infectious diseases and their concurrent outbreaks, there is a high interest in developing novel materials with antimicrobial properties. Antibacterial and antiviral properties of a range of metal-based nanoparticles (NPs) are a promising means to fight airborne diseases caused by viruses and bacteria. The aim of this study was to test antimicrobial metals and metal-based nanoparticles efficacy against three viruses, namely influenza A virus (H1N1; A/WSN/1933) and coronaviruses TGEV and SARS-CoV-2; and two bacteria, Escherichia coli and Staphylococcus aureus. The efficacy of ZnO, CuO, and Ag NPs and their respective metal salts, i.e., ZnSO4, CuSO4, and AgNO3, was evaluated in suspensions, and the compounds with the highest antiviral efficacy were chosen for incorporation into fibers of cellulose acetate (CA), using electrospinning to produce filter materials for face masks. Among the tested compounds, CuSO4 demonstrated the highest efficacy against influenza A virus and SARS-CoV-2 (1 h IC50 1.395 mg/L and 0.45 mg/L, respectively), followed by Zn salt and Ag salt. Therefore, Cu compounds were selected for incorporation into CA fibers to produce antiviral and antibacterial filter materials for face masks. CA fibers comprising CuSO4 decreased SARS-CoV-2 titer by 0.38 logarithms and influenza A virus titer by 1.08 logarithms after 5 min of contact; after 1 h of contact, SARS-COV-2 virus was completely inactivated. Developed CuO- and CuSO4-based filter materials also efficiently inactivated the bacteria Escherichia coli and Staphylococcus aureus. The metal NPs and respective metal salts were potent antibacterial and antiviral compounds that were successfully incorporated into the filter materials of face masks. New antibacterial and antiviral materials developed and characterized in this study are crucial in the context of the ongoing SARS-CoV-2 pandemic and beyond