Theory of Broensted acidity in zeolites

The nature of the chem. bond of protons in a zeolite is analyzed from theor. and spectroscopic results. Of interest is the dependence on zeolite structure as well as compn. The zeolitic OH bond is mainly covalent. Proton attachment to the zeolite lattice causes a weakening of neighboring Si-O and Al-O bonds. The effective increase in vol. of the bridging O atom causes a local deformation, that changes the strength of the lattice-chem. bonds over a few bond distances. Proton concn. effects as well as lattice-compn. effects can be understood from the lattice-relaxation model. The energetics of proton transfer is controlled by the need to stabilize the resulting Zwitter-ion. The pos. charge on the cation becomes stabilized by contact with basic lattice-O atom

From the exclusive photoproduction of heavy quarkonia at HERA to the EDDE at TeVatron and LHC

Exclusive photoproduction of heavy quarkonia at HERA is analyzed in the framework of the Regge-eikonal approach together with the nonrelativistic bound state formalism. Total and differential cross-sections for the process $\gamma+p\to (Q\bar{Q})_{1S}+p$ are calculated. The model predicts cross-sections of Exclusive Double Diffractive Events (EDDE) at TeVatron and LHC.Comment: 14 pages, 6 figures, reference is adde

Lattice-relaxation of zeolites

Quantum-chemical cluster calculations as well as solid-state chemical lattice-calculations indicate that zeolitic SiO2- and AlPO4-structures are flexible structures. The structures reflect the subtle balance of electrostatic and covalent interactions. The different electrostatic interactions lower the symmetry of layered AlPO4-structures compared to that of the corresponding SiO2-compounds. The result is a smaller zeolite-channel dimension for the AlPO4-structure compared to that of the corresponding SiO2-network. Deprotonation of the zeolite-lattice leads to large local changes in geometry that changes acidity compared to that predicted for a non-flexible lattice. Changes in lattice vibrational frequencies are consistent with the theoretically predicted relaxation of the zeolite-lattic

Properties of the Ideal Ginzburg-Landau Vortex Lattice

The magnetization curves M(H) for ideal type-II superconductors and the maximum, minimum, and saddle point magnetic fields of the vortex lattice are calculated from Ginzburg-Landau theory for the entire ranges of applied magnetic fields Hc1 <= H < Hc2 or inductions 0 <= B < Hc2 and Ginzburg-Landau parameters sqrt(1/2) <= kappa <= 1000. Results for the triangular and square flux-line lattices are compared with the results of the circular cell approximation. The exact magnetic field B(x,y) and magnetization M(H, kappa) are compared with often used approximate expressions, some of which deviate considerably or have limited validity. Useful limiting expressions and analytical interpolation formulas are presented.Comment: 11 pages, 8 figure

On the statistical significance of the conductance quantization

Recent experiments on atomic-scale metallic contacts have shown that the quantization of the conductance appears clearly only after the average of the experimental results. Motivated by these results we have analyzed a simplified model system in which a narrow neck is randomly coupled to wide ideal leads, both in absence and presence of time reversal invariance. Based on Random Matrix Theory we study analytically the probability distribution for the conductance of such system. As the width of the leads increases the distribution for the conductance becomes sharply peaked close to an integer multiple of the quantum of conductance. Our results suggest a possible statistical origin of conductance quantization in atomic-scale metallic contacts.Comment: 4 pages, Tex and 3 figures. To be published in PR

The random phase property and the Lyapunov Spectrum for disordered multi-channel systems

A random phase property establishing in the weak coupling limit a link between quasi-one-dimensional random Schrödinger operators and full random matrix theory is advocated. Briefly summarized it states that the random transfer matrices placed into a normal system of coordinates act on the isotropic frames and lead to a Markov process with a unique invariant measure which is of geometric nature. On the elliptic part of the transfer matrices, this measure is invariant under the unitaries in the hermitian symplectic group of the universality class under study. While the random phase property can up to now only be proved in special models or in a restricted sense, we provide strong numerical evidence that it holds in the Anderson model of localization. A main outcome of the random phase property is a perturbative calculation of the Lyapunov exponents which shows that the Lyapunov spectrum is equidistant and that the localization lengths for large systems in the unitary, orthogonal and symplectic ensemble differ by a factor 2 each. In an Anderson-Ando model on a tubular geometry with magnetic field and spin-orbit coupling, the normal system of coordinates is calculated and this is used to derive explicit energy dependent formulas for the Lyapunov spectrum

Decay rate and renormalized frequency shift of a quantum wire Wannier exciton in a planar microcavity

The superradiant decay rate and frequency shift of a Wannier exciton in a one-dimensional quantum wire are studied. It is shown that the dark mode exciton can be examined experimentally when the quantum wire is embedded in a planar microcavity. It is also found that the decay rate is greatly enhanced as the cavity length $L_{c}$ is equal to the multiple wavelength of the emitted photon. Similar to its decay rate counterpart, the frequency shift also shows discontinuities at resonant modes.Comment: 12 pages, 2 figures. To appear in P. R. B. September 200

Emergent global oscillations in heterogeneous excitable media: The example of pancreatic beta cells

Using the standard van der Pol-FitzHugh-Nagumo excitable medium model I demonstrate a novel generic mechanism, diversity, that provokes the emergence of global oscillations from individually quiescent elements in heterogeneous excitable media. This mechanism may be operating in the mammalian pancreas, where excitable beta cells, quiescent when isolated, are found to oscillate when coupled despite the absence of a pacemaker region.Comment: See home page http://lec.ugr.es/~julya

Proton-proton scattering above 3 GeV/c

A large set of data on proton-proton differential cross sections, analyzing powers and the double polarization parameter A_NN is analyzed employing the Regge formalism. We find that the data available at proton beam momenta from 3 GeV/c to 50 GeV/c exhibit features that are very well in line with the general characteristics of Regge phenomenology and can be described with a model that includes the rho, omega, f_2, and a_2 trajectories and single Pomeron exchange. Additional data, specifically for spin-dependent observables at forward angles, would be very helpful for testing and refining our Regge model.Comment: 16 pages, 19 figures; revised version accepted for publication in EPJ