1,372 research outputs found
Theory of Broensted acidity in zeolites
The nature of the chem. bond of protons in a zeolite is analyzed from theor. and spectroscopic results. Of interest is the dependence on zeolite structure as well as compn. The zeolitic OH bond is mainly covalent. Proton attachment to the zeolite lattice causes a weakening of neighboring Si-O and Al-O bonds. The effective increase in vol. of the bridging O atom causes a local deformation, that changes the strength of the lattice-chem. bonds over a few bond distances. Proton concn. effects as well as lattice-compn. effects can be understood from the lattice-relaxation model. The energetics of proton transfer is controlled by the need to stabilize the resulting Zwitter-ion. The pos. charge on the cation becomes stabilized by contact with basic lattice-O atom
Effectiveness of an Online Group Course for Depression in Adolescents and Young Adults: A Randomized Trial
From the exclusive photoproduction of heavy quarkonia at HERA to the EDDE at TeVatron and LHC
Exclusive photoproduction of heavy quarkonia at HERA is analyzed in the
framework of the Regge-eikonal approach together with the nonrelativistic bound
state formalism. Total and differential cross-sections for the process
are calculated. The model predicts
cross-sections of Exclusive Double Diffractive Events (EDDE) at TeVatron and
LHC.Comment: 14 pages, 6 figures, reference is adde
Lattice-relaxation of zeolites
Quantum-chemical cluster calculations as well as solid-state chemical lattice-calculations indicate that zeolitic SiO2- and AlPO4-structures are flexible structures. The structures reflect the subtle balance of electrostatic and covalent interactions. The different electrostatic interactions lower the symmetry of layered AlPO4-structures compared to that of the corresponding SiO2-compounds. The result is a smaller zeolite-channel dimension for the AlPO4-structure compared to that of the corresponding SiO2-network. Deprotonation of the zeolite-lattice leads to large local changes in geometry that changes acidity compared to that predicted for a non-flexible lattice. Changes in lattice vibrational frequencies are consistent with the theoretically predicted relaxation of the zeolite-lattic
Properties of the Ideal Ginzburg-Landau Vortex Lattice
The magnetization curves M(H) for ideal type-II superconductors and the
maximum, minimum, and saddle point magnetic fields of the vortex lattice are
calculated from Ginzburg-Landau theory for the entire ranges of applied
magnetic fields Hc1 <= H < Hc2 or inductions 0 <= B < Hc2 and Ginzburg-Landau
parameters sqrt(1/2) <= kappa <= 1000. Results for the triangular and square
flux-line lattices are compared with the results of the circular cell
approximation. The exact magnetic field B(x,y) and magnetization M(H, kappa)
are compared with often used approximate expressions, some of which deviate
considerably or have limited validity. Useful limiting expressions and
analytical interpolation formulas are presented.Comment: 11 pages, 8 figure
On the statistical significance of the conductance quantization
Recent experiments on atomic-scale metallic contacts have shown that the
quantization of the conductance appears clearly only after the average of the
experimental results. Motivated by these results we have analyzed a simplified
model system in which a narrow neck is randomly coupled to wide ideal leads,
both in absence and presence of time reversal invariance. Based on Random
Matrix Theory we study analytically the probability distribution for the
conductance of such system. As the width of the leads increases the
distribution for the conductance becomes sharply peaked close to an integer
multiple of the quantum of conductance. Our results suggest a possible
statistical origin of conductance quantization in atomic-scale metallic
contacts.Comment: 4 pages, Tex and 3 figures. To be published in PR
The random phase property and the Lyapunov Spectrum for disordered multi-channel systems
A random phase property establishing in the weak coupling limit a link between quasi-one-dimensional random Schrödinger operators and full random matrix theory is advocated. Briefly summarized it states that the random transfer matrices placed into a normal system of coordinates act on the isotropic frames and lead to a Markov process with a unique invariant measure which is of geometric nature. On the elliptic part of the transfer matrices, this measure is invariant under the unitaries in the hermitian symplectic group of the universality class under study. While the random phase property can up to now only be proved in special models or in a restricted sense, we provide strong numerical evidence that it holds in the Anderson model of localization. A main outcome of the random phase property is a perturbative calculation of the Lyapunov exponents which shows that the Lyapunov spectrum is equidistant and that the localization lengths for large systems in the unitary, orthogonal and symplectic ensemble differ by a factor 2 each. In an Anderson-Ando model on a tubular geometry with magnetic field and spin-orbit coupling, the normal system of coordinates is calculated and this is used to derive explicit energy dependent formulas for the Lyapunov spectrum
Decay rate and renormalized frequency shift of a quantum wire Wannier exciton in a planar microcavity
The superradiant decay rate and frequency shift of a Wannier exciton in a
one-dimensional quantum wire are studied. It is shown that the dark mode
exciton can be examined experimentally when the quantum wire is embedded in a
planar microcavity. It is also found that the decay rate is greatly enhanced as
the cavity length is equal to the multiple wavelength of the emitted
photon. Similar to its decay rate counterpart, the frequency shift also shows
discontinuities at resonant modes.Comment: 12 pages, 2 figures. To appear in P. R. B. September 200
Emergent global oscillations in heterogeneous excitable media: The example of pancreatic beta cells
Using the standard van der Pol-FitzHugh-Nagumo excitable medium model I
demonstrate a novel generic mechanism, diversity, that provokes the emergence
of global oscillations from individually quiescent elements in heterogeneous
excitable media. This mechanism may be operating in the mammalian pancreas,
where excitable beta cells, quiescent when isolated, are found to oscillate
when coupled despite the absence of a pacemaker region.Comment: See home page http://lec.ugr.es/~julya
Proton-proton scattering above 3 GeV/c
A large set of data on proton-proton differential cross sections, analyzing
powers and the double polarization parameter A_NN is analyzed employing the
Regge formalism. We find that the data available at proton beam momenta from 3
GeV/c to 50 GeV/c exhibit features that are very well in line with the general
characteristics of Regge phenomenology and can be described with a model that
includes the rho, omega, f_2, and a_2 trajectories and single Pomeron exchange.
Additional data, specifically for spin-dependent observables at forward angles,
would be very helpful for testing and refining our Regge model.Comment: 16 pages, 19 figures; revised version accepted for publication in
EPJ
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