Theoretical Framework for Microscopic Osmotic Phenomena

The basic ingredients of osmotic pressure are a solvent fluid with a soluble molecular species which is restricted to a chamber by a boundary which is permeable to the solvent fluid but impermeable to the solute molecules. For macroscopic systems at equilibrium, the osmotic pressure is given by the classical van't Hoff Law, which states that the pressure is proportional to the product of the temperature and the difference of the solute concentrations inside and outside the chamber. For microscopic systems the diameter of the chamber may be comparable to the length-scale associated with the solute-wall interactions or solute molecular interactions. In each of these cases, the assumptions underlying the classical van't Hoff Law may no longer hold. In this paper we develop a general theoretical framework which captures corrections to the classical theory for the osmotic pressure under more general relationships between the size of the chamber and the interaction length scales. We also show that notions of osmotic pressure based on the hydrostatic pressure of the fluid and the mechanical pressure on the bounding walls of the chamber must be distinguished for microscopic systems. To demonstrate how the theoretical framework can be applied, numerical results are presented for the osmotic pressure associated with a polymer of N monomers confined in a spherical chamber as the bond strength is varied

An electronic system for measuring thermophysical properties of wind tunnel models

An electronic system is described which measures the surface temperature of a small portion of the surface of the model or sample at high speeds using an infrared radiometer. This data is processed along with heating rate data from the reference heat gauge in a small computer and prints out the desired thermophysical properties, time, surface temperature, and reference heat rate. This system allows fast and accurate property measurements over thirty temperature increments. The technique, the details of the apparatus, the procedure for making these measurements, and the results of some preliminary tests are presented

Spherical Orbifolds for Cosmic Topology

Harmonic analysis is a tool to infer cosmic topology from the measured astrophysical cosmic microwave background CMB radiation. For overall positive curvature, Platonic spherical manifolds are candidates for this analysis. We combine the specific point symmetry of the Platonic manifolds with their deck transformations. This analysis in topology leads from manifolds to orbifolds. We discuss the deck transformations of the orbifolds and give eigenmodes for the harmonic analysis as linear combinations of Wigner polynomials on the 3-sphere. These provide new tools for detecting cosmic topology from the CMB radiation.Comment: 17 pages, 9 figures. arXiv admin note: substantial text overlap with arXiv:1011.427