Non-Equilibrium relation between mobility and diffusivity of interacting Brownian particles under shear

We investigate the relation between mobility and diffusivity for Brownian particles under steady shear near the glass transition, using mode coupling approximations. For the two directions perpendicular to the shear direction, the particle motion is diffusive at long times and the mobility reaches a finite constant. Nevertheless, the Einstein relation holds only for the short-time in-cage motion and is violated for long times. In order to get the relation between diffusivity and mobility, we perform the limit of small wavevector for the relations derived previously [Phys. Rev. Lett. 102 (2009), 135701], without further approximation. We find good agreement to simulation results. Furthermore, we split the extra term in the mobility in an exact way into three terms. Two of them are expressed in terms of mean squared displacements. The third is given in terms of the (less handy) force-force correlation function.Comment: 14 pages, 4 figures, accepted for Prog. Theor. Phys. Suppl., issue for the workshop "Frontiers in Nonequilibrium Physics", Kyoto, 200

Heat radiation and transfer in confinement

Near-field heat radiation and transfer are rich in various exciting effects, in particular, regarding the amplification due to the geometrical configuration of the system. In this paper, we study heat exchange in situations where the objects are confined by additional objects so that the dimensionality of heat flow is reduced. In particular, we compute the heat transfer for spherical point particles placed between two parallel plates. The presence of the plates can enhance or reduce the transfer compared to the free case and provides a slower power-law decay for large distance. We also compute the heat radiation of a sphere placed inside a spherical cavity, finding that it can be larger or smaller compared to the radiation of a free sphere. This radiation shows strong resonances as a function of the cavity's size. For example, the cooling rate of a nanosphere placed in a cavity varies by a factor of $10^5$ between cavity radii $2 \ \mu {\rm m}$ and $5 \ \mu {\rm m}$.Comment: 8 pages, 7 figures (v2: discussion about different heat flow contributions was added, temperatures were added to the figures describing configurations; Fig. 3 was added; discussions related to validity of the point particle approximation were updated; meters were replaced with micrometers in figures and text; minor changes in text

Anisotropic particles near surfaces: Self-propulsion and friction

We theoretically study the phenomenon of self-propulsion through Casimir forces in thermal non-equilibrium. Using fluctuational electrodynamics, we derive a formula for the self-propulsion force for an arbitrary small object in two scenarios, i) for the object being isolated, and ii) for the object being close to a planar surface. In the latter case, the self-propulsion force (i.e., the force parallel to the surface) increases with decreasing distance, i.e., it couples to the near-field. We numerically calculate the lateral force acting on a hot spheroid near a surface and show that it can be as large as the gravitational force, thus being potentially measurable in fly-by experiments. We close by linking our results to well-known relations of linear response theory in fluctuational electrodynamics: Looking at the friction of the anisotropic object for constant velocity, we identify a correction term that is additional to the typically used approach.Comment: 13 pages, 8 figures (v2: References updated

Driven colloidal suspensions in confinement and density functional theory: Microstructure and wall-slip

We theoretically investigate general properties of driven (sheared) colloidal suspensions in confinement, based on methods of classical density functional theory. In the absence of an exact closed (Smoluchowski-) equation for the one-particle density under shear, we formulate a set of general conditions for approximations, and show that a simple closure fulfills them. The exact microscopic stress tensor is identified. Exemplifying the situation near a wall (oriented parallel to the direction of shear), we note that the microscopic shear stress is not necessarily homogeneous. Formulating a second equation additional to the Smoluchowski equation, we achieve a homogeneous shear stress, and thereby compute the local flow velocity near the wall. This finally leads to a slip length of the complex fluid at the wall.Comment: 11 pages, 8 figure

Extrapolation to nonequilibrium from coarse grained response theory

Nonlinear response theory, in contrast to linear cases, involves (dynamical) details, and this makes application to many body systems challenging. From the microscopic starting point we obtain an exact response theory for a small number of coarse grained degrees of freedom. With it, an extrapolation scheme uses near-equilibrium measurements to predict far from equilibrium properties (here, second order responses). Because it does not involve system details, this approach can be applied to many body systems. It is illustrated in a four state model and in the near critical Ising model.Comment: Accepted for publication in Phys. Rev. Let

Heat radiation and transfer for point particles in arbitrary geometries

We study heat radiation and heat transfer for pointlike particles in a system of other objects. Starting from exact many-body expressions found from scattering theory and fluctuational electrodynamics, we find that transfer and radiation for point particles are given in terms of the Green's function of the system in the absence of the point particles. These general expressions contain no approximation for the surrounding objects. As an application, we compute the heat transfer between two point particles in the presence of a sphere of arbitrary size and show that the transfer is enhanced by several orders of magnitude through the presence of the sphere, depending on the materials. Furthermore, we compute the heat emission of a point particle in front of a planar mirror. Finally, we show that a particle placed inside a spherical mirror cavity does not radiate energy.Comment: 14 pages, 9 figures (v2: Sec. IIIE was added; explanation of Eq. (29) was added; sentence in Acknowledgments was added; Ref. [69] was added; minor changes in text

Overshoots in stress strain curves: Colloid experiments and schematic mode coupling theory

The stress versus strain curves in dense colloidal dispersions under start-up shear flow are investigated combining experiments on model core-shell microgels, computer simulations of hard disk mixtures, and mode coupling theory. In dense fluid and glassy states, the transient stresses exhibit first a linear increase with the accumulated strain, then a maximum ('stress overshoot') for strain values around 5%, before finally approaching the stationary value, which makes up the flow curve. These phenomena arise in well-equilibrated systems and for homogeneous flows, indicating that they are generic phenomena of the shear-driven transient structural relaxation. Microscopic mode coupling theory (generalized to flowing states by integration through the transients) derives them from the transient stress correlations, which first exhibit a plateau (corresponding to the solid-like elastic shear modulus) at intermediate times, and then negative stress correlations during the final decay. We introduce and validate a schematic model within mode coupling theory which captures all of these phenomena and handily can be used to jointly analyse linear and large-amplitude moduli, flow curves, and stress-strain curves. This is done by introducing a new strain- and time-dependent vertex into the relation between the the generalized shear modulus and the transient density correlator.Comment: 21 pages, 13 figure