Defect distribution in a-plane GaN on Al2O3

The authors studied the structural and point defect distributions of hydride vapor phase epitaxial GaN film grown in the [11−20] a direction on (1−102) r-plane sapphire with metal-organic vapor phase deposited a-GaN template using transmission electron microscopy, secondary ion mass spectrometry, and positron annihilation spectroscopy. Grown-in extended and point defects show constant behavior as a function of thickness, contrary to the strong nonuniform defect distribution observed in GaN grown along the [0001] direction. The observed differences are explained by orientation-dependent and kinetics related defect incorporation.Peer reviewe

Chemical Self-Enrichment of HII Regions by the Wolf-Rayet Phase of an 85 Msun star

It is clear from stellar evolution and from observations of WR stars that massive stars are releasing metal-enriched gas through their stellar winds in the Wolf-Rayet phase. Although HII region spectra serve as diagnostics to determine the present-day chemical composition of the interstellar medium, it is far from being understood to what extent the HII gas is already contaminated by chemically processed stellar wind. Therefore, we analyzed our models of radiative and wind bubbles of an isolated 85 Msun star with solar metallicity (Kr\"oger et al. 2006) with respect to the chemical enrichment of the circumstellar HII region. Plausibly, the hot stellar wind bubble (SWB) is enriched with 14N during the WN phase and even much higher with 12C and 16O during the WC phase of the star. During the short period that the 85 Msun star spends in the WC stage enriched SWB material mixes with warm HII gas of solar abundances and thus enhances the metallicity in the HII region. However, at the end of the stellar lifetime the mass ratios of the traced elements N and O in the warm ionized gas are insignificantly higher than solar, whereas an enrichment of 22 % above solar is found for C. Important issues from the presented study comprise a steeper radial gradient of C than O and a decreasing effect of self-enrichment for metal-poor galaxies.Comment: 5 pages, 3 figures, accepted for publication in A&A Letter

Adsorption structure of glycine on TiO2(1 1 0): a photoelectron diffraction determination

High-resolution core-level photoemission and scanned-energy mode photoelectron diffraction (PhD) of the O 1s and N 1s states have been used to investigate the interaction of glycine with the rutile TiO2(1 1 0) surface. Whilst there is clear evidence for the presence of the zwitterion View the MathML sourceCH2COO− with multilayer deposition, at low coverage only the deprotonated glycinate species, NH2CH2COO is present. Multiple-scattering simulations of the O 1s PhD data show the glycinate is bonded to the surface through the two carboxylate O atoms which occupy near-atop sites above the five-fold-coordinated surface Ti atoms, with a Ti–O bondlength of 2.12 ± 0.06 Å. Atomic hydrogen arising from the deprotonation is coadsorbed to form hydroxyl species at the bridging oxygen sites with an associated Ti–O bondlength of 2.01 ± 0.03 Å. Absence of any significant PhD modulations of the N 1s emission is consistent with the amino N atom not being involved in the surface bonding, unlike the case of glycinate on Cu(1 1 0) and Cu(1 0 0)

Role of elastic scattering in electron dynamics at ordered alkali overlayers on Cu(111)

Scanning tunneling spectroscopy of p(2x2) Cs and Na ordered overlayers on Cu(111) reveals similar line widths of quasi two-dimensional quantum well states despite largely different binding energies. Detailed calculations show that 50% of the line widths are due to electron-phonon scattering while inelastic electron-electron scattering is negligible. A frequently ignored mechanism for ordered structures, i.e., enhanced elastic scattering due to Brillouin zone back folding, contributes the remaining width.Comment: 4 pages, 2 figures, 1 tabl

Tuning the properties of complex transparent conducting oxides: role of crystal symmetry, chemical composition and carrier generation

The electronic properties of single- and multi-cation transparent conducting oxides (TCOs) are investigated using first-principles density functional approach. A detailed comparison of the electronic band structure of stoichiometric and oxygen deficient In$_2$O$_3$, $\alpha$- and $\beta$-Ga$_2$O$_3$, rock salt and wurtzite ZnO, and layered InGaZnO$_4$ reveals the role of the following factors which govern the transport and optical properties of these TCO materials: (i) the crystal symmetry of the oxides, including both the oxygen coordination and the long-range structural anisotropy; (ii) the electronic configuration of the cation(s), specifically, the type of orbital(s) -- $s$, $p$ or $d$ -- which form the conduction band; and (iii) the strength of the hybridization between the cation's states and the p-states of the neighboring oxygen atoms. The results not only explain the experimentally observed trends in the electrical conductivity in the single-cation TCO, but also demonstrate that multicomponent oxides may offer a way to overcome the electron localization bottleneck which limits the charge transport in wide-bandgap main-group metal oxides. Further, the advantages of aliovalent substitutional doping -- an alternative route to generate carriers in a TCO host -- are outlined based on the electronic band structure calculations of Sn, Ga, Ti and Zr-doped InGaZnO$_4$. We show that the transition metal dopants offer a possibility to improve conductivity without compromising the optical transmittance

Estimation and Validation of Codephase Center Correction Using the Empirical Mode Decomposition

In high precision Global Navigation Satellite Systems (GNSS) applications, it is necessary to take phase center corrections (PCC) into account. Beside these corrections for carrier phase measurements, also corrections for the codephase are necessary, so called codephase center corrections (CPC). The CPC, also known as group delay variations, are antenna dependent delays of the received codephase, which are varying with azimuth and elevation of the incoming GNSS signal. A concept for estimating absolute CPC and PCC for multi GNSS signals has been established by the Institut für Erdmessung. In this paper, the standard calibration approach with a sampling rate of 1 Hz is briefly described, which works well for PCC estimation. The main challenge of this approach for estimating repeatable CPC patterns is the significantly higher noise to pattern ratio in the observations compared to PCC determination. Therefore, an alternative processing strategy is presented in this contribution. By increasing the sampling rate to 10 Hz, the empirical mode decomposition can be used to reduce the noise of the input observations by maintaining all pattern information. With this method, the calibration repeatability is improved by 46% to 60% for GPS and Galileo C1C signals for a geodetic antenna. Moreover, the estimated pattern is validated in the positioning domain with a single point positioning approach. By considering the estimated CPC the accuracy of the height component can be improved

Pattern formation from consistent dynamical closures of uniaxial nematic liquid crystals

Pattern formation in uniaxial polymeric liquid crystals is studied for different dynamic closure approximations. Using the principles of mesoscopic non-equilibrium thermodynamics in a mean-field approach, we derive a Fokker-Planck equation for the single-particle non-homogeneous distribution function of particle orientations and the evolution equations for the second and fourth order orientational tensor parameters. Afterwards, two dynamic closure approximations are discussed, one of them considering the relaxation of the fourth order orientational parameter and leading to a novel expression for the free-energy like function in terms of the scalar order parameter. Considering the evolution equation of the density of the system and values of the interaction parameter for which isotropic and nematic phases coexist, our analysis predicts that patterns and traveling waves can be produced in lyotropic uniaxial nematics even in the absence of external driving.Comment: 34 pages, 7 figure