The link between lithospheric scale deformations and deep fluid emanations: Inferences from the Southeastern Carpathians, Romania

Understanding the formation, migration and emanation of deep CO2, H2O and noble gases (He–Ne) in deep-seated deformation settings is crucial to understand the complex relationship between deep-originated fluids and lithospheric deformation. To gain a better insight into these phenomena, we studied the origin of H2O, CO2 and noble gases of gas-rich springs found in the Târgu Secuiesc Basin located in the southeasternmost part of the Carpathian-Pannonian region of Europe. This study area is one of the best natural examples to understand the connection between the deep sources of gas emanations and deep-seated deformation zones, providing an excellent analogue for regions worldwide with similar tectonic settings and fluid emanation properties. We studied the δ2H and δ18O stable isotopic ratios of the spring waters, and the δ13C, He and Ne stable isotopic ratio of the emanating CO2-rich gases dissolved in the mineral spring waters in Covasna town and its vicinity. Based on the δ2H, δ13C, δ18O stable isotopic ratios, the spring waters and the majority of the gases are released through two consecutive fluid infiltration events. The preservation of the metamorphic signal of the upwelling H2O is linked to the local groundwater flow and fault abundancy. Furthermore, the noble gas isotopic ratios show a high degree of atmospheric contamination in the dissolved water gasses that is most likely related to the local hydrogeology. Nevertheless, the elevated corrected helium stable isotopic ratios (Rc/Ra) of our filtered data suggest that part of the emanating gases have a potential upper mantle source component. Beneath the Southeastern Carpathians, mantle fluids can have multiple origin including the dehydration of the sinking slab hosting the Vrancea seismogenic zone, the local asthenospheric upwelling and the lithospheric mantle itself. The flux of the mantle fluids is enhanced by lithospheric scale deformation zones that also support the fluid inflow from the upper mantle into the lower crust. The upwelling CO2–H2O mantle fluids may induce the release of crustal fluids by shifting the pore fluid composition (X(CO2)) and, consequently, initiating decarbonisation and devolatilization metamorphic reactions as a result of carbonate and hydrous mineral destabilisation in the crust. Based on the p-T-X(CO2) conditions of calc-silicates and the local low geotherm, we emphasise the importance of the upwelling fluids in the release and upward migration of further H2O and CO2 in the shallower lower and upper crust. Our observations in the Southeastern Carpathians show a strong similarity to other deep-seated deformation zones worldwide (e.g., Himalayas, Alps, San Andreas Fault). We infer that migration of deep fluids may also play an important role in addition to temperature control on the generation of crustal fluids in deep-seated deformation zones

Lower Cretaceous Provenance and Sedimentary Deposition in the Eastern Carpathians: Inferences for the Evolution of the Subducted Oceanic Domain and its European Passive Continental Margin

Abstract Reconstructing orogenic systems made up dominantly by sediments accreted in trenches is challenging because of the incomplete lithological record of the subducted oceanic domain and its attached passive continental margin thrusted by collisional processes. In this respect, the remarkable ~600 km long continuity of sediments exposed in the Eastern Carpathian thin-skinned thrust and fold belt and the availability of quantitative reconstructions for adjacent continental units provide excellent conditions for a paleogeographical study by provenance and sedimentological techniques constraining sediment routing and depositional systems. These sediments were deposited in the Ceahl?u-Severin branch of the Alpine Tethys Ocean and over its European passive continental margin. We report sedimentological, paleomagnetic, petrographic, and detrital zircon U-Pb data of Lower Cretaceous sediments from several thin-skinned tectonic units presumably deposited in the Moldavides domain of the Eastern Carpathians. Sedimentological observations in the innermost studied unit demonstrate that deposition took place in a deepwater basin floor sheets to sandy turbidite system. Detrital zircon age data demonstrate sourcing from internal Carpathian basement units. The sediment routing changes in more external units, where black shales basin floor sheets to sandy mud turbidites were sourced from an external, European continental area. Although some degree of mixing between sources located on both margins of the ocean occurred, constraining a relatively narrow width of the deep oceanic basin, these results demonstrate that the internal-most studied unit was deposited near an Early Cretaceous accretionary wedge, located on the opposite internal side relative to the passive continental margin domain of other Moldavides units

Lower Cretaceous Provenance and Sedimentary Deposition in the Eastern Carpathians: Inferences for the Evolution of the Subducted Oceanic Domain and its European Passive Continental Margin

Reconstructing orogenic systems made up dominantly by sediments accreted in trenches is challenging because of the incomplete lithological record of the subducted oceanic domain and its attached passive continental margin thrusted by collisional processes. In this respect, the remarkable similar to 600 km long continuity of sediments exposed in the Eastern Carpathian thin-skinned thrust and fold belt and the availability of quantitative reconstructions for adjacent continental units provide excellent conditions for a paleogeographical study by provenance and sedimentological techniques constraining sediment routing and depositional systems. These sediments were deposited in the Ceahlau-Severin branch of the Alpine Tethys Ocean and over its European passive continental margin. We report sedimentological, paleomagnetic, petrographic, and detrital zircon U-Pb data of Lower Cretaceous sediments from several thin-skinned tectonic units presumably deposited in the Moldavides domain of the Eastern Carpathians. Sedimentological observations in the innermost studied unit demonstrate that deposition took place in a deepwater basin floor sheets to sandy turbidite system. Detrital zircon age data demonstrate sourcing from internal Carpathian basement units. The sediment routing changes in more external units, where black shales basin floor sheets to sandy mud turbidites were sourced from an external, European continental area. Although some degree of mixing between sources located on both margins of the ocean occurred, constraining a relatively narrow width of the deep oceanic basin, these results demonstrate that the internal-most studied unit was deposited near an Early Cretaceous accretionary wedge, located on the opposite internal side relative to the passive continental margin domain of other Moldavides units.6 month embargo; first published: 20 April 2020This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

Lower Cretaceous Provenance and Sedimentary Deposition in the Eastern Carpathians: Inferences for the Evolution of the Subducted Oceanic Domain and its European Passive Continental Margin

Reconstructing orogenic systems made up dominantly by sediments accreted in trenches is challenging because of the incomplete lithological record of the subducted oceanic domain and its attached passive continental margin thrusted by collisional processes. In this respect, the remarkable similar to 600 km long continuity of sediments exposed in the Eastern Carpathian thin-skinned thrust and fold belt and the availability of quantitative reconstructions for adjacent continental units provide excellent conditions for a paleogeographical study by provenance and sedimentological techniques constraining sediment routing and depositional systems. These sediments were deposited in the Ceahlau-Severin branch of the Alpine Tethys Ocean and over its European passive continental margin. We report sedimentological, paleomagnetic, petrographic, and detrital zircon U-Pb data of Lower Cretaceous sediments from several thin-skinned tectonic units presumably deposited in the Moldavides domain of the Eastern Carpathians. Sedimentological observations in the innermost studied unit demonstrate that deposition took place in a deepwater basin floor sheets to sandy turbidite system. Detrital zircon age data demonstrate sourcing from internal Carpathian basement units. The sediment routing changes in more external units, where black shales basin floor sheets to sandy mud turbidites were sourced from an external, European continental area. Although some degree of mixing between sources located on both margins of the ocean occurred, constraining a relatively narrow width of the deep oceanic basin, these results demonstrate that the internal-most studied unit was deposited near an Early Cretaceous accretionary wedge, located on the opposite internal side relative to the passive continental margin domain of other Moldavides units.6 month embargo; first published: 20 April 2020This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

New data on the Vrancea Nappe (Moldavidian Basin, Outer Carpathian Domain, Romania): paleogeographic and geodynamic reconstructions

A study has been performed on the Cretaceous to Early Miocene succession of the Vrancea Nappe (Outer Carpathians, Romania), based on field reconstruction of the stratigraphic record, mineralogical-petrographic and geochemical analyses. Extra-basinal clastic supply and intra-basinal autochthonous deposits have been differentiated, appearing laterally inter-fingered and/or interbedded. The main clastic petrofacies consist of calcarenites, sub-litharenites, quartzarenites, sub-arkoses, and polygenic conglomerates derived from extra-basinal margins. An alternate internal and external provenance of the different supplies is the result of the paleogeographic re-organization of the basin/margins system due to tectonic activation and exhumation of rising areas. The intra-basinal deposits consist of black shales and siliceous sediments (silexites and cherty beds), evidencing major environmental changes in the Moldavidian Basin. Organic-matter-rich black shales were deposited during anoxic episodes related to sediment starvation and high nutrient influx due to paleogeographic isolation of the basin caused by plate drifting. The black shales display relatively high contents in sub-mature to mature, Type II lipidic organic matter (good oil and gas-prone source rocks) constituting a potentially active petroleum system. The intra-basinal siliceous sediments are related to oxic pelagic or hemipelagic environments under tectonic quiescence conditions although its increase in the Oligocene part of the succession can be correlated with volcanic supplies. The integration of all the data in the “progressive reorientation of convergence direction” Carpathian model, and their consideration in the framework of a foreland basin, led to propose some constrains on the paleogeographic-geodynamic evolutionary model of the Moldavidian Basin from the Late Cretaceous to the Burdigalian.This research was supported by Urbino University grant (responsible F. Guerrera), Italy; CGL2009-09249 and CGL2011-30153-CO2-02 research projects (Spanish Ministry of Education and Science), Research Groups and projects of the Generalitat Valenciana and from Alicante University (CTMA-IGA Spain); Research Contr. IDEI 436/01.10.2007 (CNCSIS-Romania)